Optimization of Coagulation Flocculation Process for the Removal of Heavy Metals from Real Textile Wastewater

Author(s):  
Dalila Sakhi ◽  
Younes Rakhila ◽  
Abedellah Elmchaouri ◽  
Meriem Abouri ◽  
Salah Souabi ◽  
...  
Water ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 352 ◽  
Author(s):  
Lorena Lugo ◽  
Alison Martín ◽  
John Diaz ◽  
Alejandro Pérez-Flórez ◽  
Crispin Celis

The modified tannin by Mannich reaction was investigated for wastewater treatment. The removal of heavy metals, such as copper, chromium and mercury, in industrial wastewater was evaluated through the coagulation–flocculation technique, using modified Acacia tannin (MAT) as a coagulant agent. The successful tannin modification was evaluated by infrared spectopometry (FTIR), nuclear magnetic resonance (NMR); monitoring the removal of heavy metals was performed by atomic absorption (AA) and a direct mercury analyzer (DMA). Additionally, the parameters of water quality, total suspended solids (TSS), turbidity and chemical oxygen demand (COD) were assessed. Different doses of MAT were evaluated (375 ppm, 750 ppm, 1250 ppm and 1625 ppm) and three different levels of pH (4, 7 and 10). The highest percentages of removal obtained were copper 60%, chromium 87%, mercury 50%–80%, COD 88%, TSS 86% and turbidity 94%, which were achieved with the dose of 375 ppm of MAT at pH 10. The coagulation–flocculation process with the modified Acacia tannin is efficient for the removal of conventional parameters and for a significant removal of the metals studied.


Water ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 3034
Author(s):  
Muhammad Mubashar ◽  
Muhammad Naveed ◽  
Adnan Mustafa ◽  
Sobia Ashraf ◽  
Khurram Shehzad Baig ◽  
...  

The present study evaluated the performance of microalgae Chlorella vulgaris in an Enterobacter sp. MN17-assisted textile industry wastewater treatment system for decolorization, removal of heavy metals (Cu, Cr, Pb, and Cd), and chemical oxygen demand (COD). Different dilutions (5, 10, and 20%) of wastewater were prepared to decrease the pollutant toxicity for culturing microalgae and bacteria. Reduction of color, COD, and metal contents by microalgal treatment of wastewater varied greatly, while removal efficiency (RE) was significantly enhanced when endophytic bacterial strain MN17 inoculum was applied. Most notable, results were found at a 5% dilution level by Enterobacter sp. MN17-inoculated C. vulgaris medium, as chromium (Cr), cadmium (Cd), copper (Cu), and lead (Pb) concentrations were decreased from 1.32 to 0.27 mg L−1 (79% decrease), 0.79–0.14 mg L−1 (93% decrease), 1.33–0.36 mg L−1 (72% decrease), and 1.2–0.25 mg L−1 (79% decrease), respectively. The values of COD and color were also significantly decreased by 74% and 70%, respectively, by a C. vulgaris–Enterobacter sp. MN17 consortium. The present investigation revealed that bacterial inoculation of microalgae significantly enhanced the removal of coloring agents and heavy metals from textile wastewater by stimulating the growth of algal biomass. This study manifested the usefulness of microalgae–bacterial mutualism for the remediation of heavy metals, COD, and color in industrial effluents. Microalgae consortia with growth promoting bacteria could be a breakthrough for better bioremediation and bioprocess economy. Thus, further studies are needed for successful integration of microalgae–plant growth promoting bacterial (PGPB) consortium for wastewater treatments.


Author(s):  
Ahmed M. AZZAM ◽  
Ahmed TAWFIK

Bio-flocculants produced by Bacillus sp. and Pseudomonas sp. were evaluated as flocculating agents for the removal of Cu (II), Pb (II) and Cd (II) from chemical and textile wastewater industries. Both bio-flocculants were very effective for removal of heavy metals at a dosage not exceeding 0.1 mg/ml. However, the removal efficiency of heavy metals was dependant on initial concentration and type of bio-flocculants. 84.0% of Cu2+ and 99.5% of Pb2+ were removed from industrial wastewater using Bacillus sp. Bio-flocculant resulting residual values of 28.5 and 1.13μg/l respectively in the treated effluent. Lower removal efficiencies of 70.4% for Cu2+ and 97.8% for Pb2+ occurred using Pseudomonas sp. bioflocculant. Nevertheless, Pseudomonas sp. bio-flocculant achieved a substantially higher removal efficiency of Cd2+ (93.5%) as compared to 72.9% using Bacillus sp. Based on these results bio-flocculants are considered as a viable alternative for the treatment of industrial wastewater containing heavy metals.


Desalination ◽  
2008 ◽  
Vol 228 (1-3) ◽  
pp. 245-254 ◽  
Author(s):  
Merzouk Belkacem ◽  
Madani Khodir ◽  
Sekki Abdelkrim

2011 ◽  
Vol 2 (3) ◽  
pp. 1-8 ◽  
Author(s):  
Sasmita Sabat ◽  
◽  
R V Kavitha R V Kavitha ◽  
Shantha S L Shantha S L ◽  
Gopika Nair ◽  
...  

2013 ◽  
Vol 12 (3) ◽  
pp. 239-247

The removal of heavy metals from wastewaters is a matter of paramount importance due to the fact that their high toxicity causes major environmental pollution problems. One of the most efficient, applicable and low cost methods for the removal of toxic metals from aqueous solutions is that of their adsorption on an inorganic adsorbent. In order to achieve high efficiency, it is important to understand the influence of the solution parameters on the extent of the adsorption, as well as the kinetics of the adsorption. In the present work, the adsorption of Cu(II) species onto TiO2 surface was studied. It was found that the adsorption is a rapid process and it is not affected by the value of ionic strength. In addition, it was found that by increasing the pH, the adsorbed amount of Cu2+ ions and the value of the adsorption constant increase, whereas the value of the lateral interaction energy decreases.


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