Chloride-Induced Depassivation of Steel in Concrete—Influence of Electrochemical Potential and Anodic Polarization Level

Author(s):  
Marc Kosalla ◽  
Michael Raupach
Author(s):  
Ann Chidester Van Orden ◽  
John L. Chidester ◽  
Anna C. Fraker ◽  
Pei Sung

The influence of small variations in the composition on the corrosion behavior of Co-Cr-Mo alloys has been studied using scanning electron microscopy (SEM), energy dispersive x-ray analysis (EDX), and electrochemical measurements. SEM and EDX data were correlated with data from in vitro corrosion measurements involving repassivation and also potentiostatic anodic polarization measurements. Specimens studied included the four alloys shown in Table 1. Corrosion tests were conducted in Hanks' physiological saline solution which has a pH of 7.4 and was held at a temperature of 37°C. Specimens were mechanically polished to a surface finish with 0.05 µm A1203, then exposed to the solution and anodically polarized at a rate of 0.006 v/min. All voltages were measured vs. the saturated calomel electrode (s.c.e.).. Specimens had breakdown potentials near 0.47V vs. s.c.e.


1995 ◽  
Vol 44 (506) ◽  
pp. 1326-1331 ◽  
Author(s):  
Yasuyuki TAKATANI ◽  
Tomoki TOMITA ◽  
Kazumi TANI ◽  
Mitsuharu INABA ◽  
Yoshio HARADA

1980 ◽  
Vol 45 (8) ◽  
pp. 2272-2282 ◽  
Author(s):  
Jan Balej ◽  
Martin Kadeřávek

Preparation of peroxodisulphates by electrolysis of mixed solutions of sulphuric acid and various sulphates was studied at low degree of conversion; the partial polarization curves of peroxodisulphate formation and of oxygen evolution obtained from the overall anodic polarization curves and current yields of the principal anodic processes were examined. The mechanism of the effect of various cations on the rate of anodic formation of peroxodisulfates is discussed.


Author(s):  
K. Ando ◽  
E. Saitoh

This chapter introduces the concept of incoherent spin current. A diffusive spin current can be driven by spatial inhomogeneous spin density. Such spin flow is formulated using the spin diffusion equation with spin-dependent electrochemical potential. The chapter also proposes a solution to the problem known as the conductivity mismatch problem of spin injection into a semiconductor. A way to overcome the problem is by using a ferromagnetic semiconductor as a spin source; another is to insert a spin-dependent interface resistance at a metal–semiconductor interface.


1984 ◽  
Vol 81 (2) ◽  
pp. 128-142 ◽  
Author(s):  
C. Biscari ◽  
J. Buon ◽  
B. W. Montague

Author(s):  
Shin Nakamura ◽  
Matteo Capone ◽  
Giuseppe Mattioli ◽  
Leonardo Guidoni

Water-oxidizing metal-(hydr)oxo catalyst films can be generally deposited and activated by applying a positive electrochemical potential to suitable starting aqueous solutions. Here, we used ab initio simulations based on density...


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