Determination of Mass Transfer Rates in an Aquifer Sand of Low Organic Carbon Content — Laboratory Experiments

Author(s):  
P. Merkel ◽  
Ch. Schüth ◽  
P. Grathwohl
1987 ◽  
Vol 59 (2) ◽  
pp. 63-65
Author(s):  
Raina Niskanen ◽  
Väinö Mäntylahti

Drying of three mineral soil samples (clay content 4—58 %, organic carbon content 1—5 %) equilibrated at 75.5 % relative humidity was studied. The soils were dried in an oven at +50°C, +70°C and + 105°C for 4 and 8 hours and in a desiccator over pure concentrated H2SO4 and P2O5. Drying over desiccants for 8 hours removed less water than drying at + 50°C. Drying over desiccants for 3—7 days was as efficient as drying at +70°C, for 14—24 days as efficient as 4 hours of drying at + 105°C. Eight hours of drying at + 105°C seemed to be too drastic, because it caused a greater weight loss in the clay sample of 5 % organic carbon content than did prolonged desiccant-drying. Drying at + 70°Cremoved as much water from fine sand which contained 4 % clay as prolonged desiccant-drying.


1983 ◽  
Vol 55 (2) ◽  
pp. 109-117
Author(s):  
Raili Jokinen

A total of 430 topsoil samples were collected from ten fields of the Viikki Experimental Farm, University of Helsinki. Particle size distribution, organic carbon content, pH(CaCl2), exchangeable Ca, Mg, K contents, plant available P (Bray 1), 1 M KCI extractable (Al+H) content and effective cation exhange capacity of the soils were determined. The coefficient of variation was used as indicator of the variability of soil properties with in each field. The lowest coefficients of variation were observed for pH(CaCl2) and the highest for exchangeable Mg 1 M KCI extractable (Al+H) and effective cation exchange capasity. The results indicate that from 1 (pH(CaCl2)) to 33 (exchangeable Mg) samples per hectare are needed from individual fields for strict level of accuracy in estimation of the soil properties. For determination of soil type (according to clay content) and organic carbon content on average 8 samples, and for the plant available P (Bray 1) and exchangeable Mg and K contents 10 to 16 samples per hectare appear sufficient. Four samples suffice for a less stringent, lax accurate determination of all properties. The variability of soil properties is discussed from the viewpoint of agricultural advisory work and field experiments for agricultural research.


2019 ◽  
Vol 51 (3) ◽  
pp. 342-347 ◽  
Author(s):  
V. R. Angelova ◽  
V. I. Akova ◽  
K. I. Ivanov

The aim of this study was to compare the most commonly used methods for the determination of organic carbon (OC) and organic matter (SOM), and evaluate the capability of LOI (loss on ignition method) to estimate OC, using reference soils, compost and sludge as standards. The use of a titrimetric endpoint (adding phosphoric acid prior to titration) is more suitable for assessing the level of organic carbon in soils with low, medium, high and very high content. The use of a photometric endpoint is more appropriate for samples of medium and high carbon content. LOI 400 and LOI 450 may also be used for the determination of samples with a high organic content whereas LOI 450 - in the determination of samples with an average organic content. LOI 450 can be used to evaluate SOC in a wide range of organic matter concentrations (3-55%). Indirect assessment of the organic carbon content or organic matter using a correction coefficient is not very accurate for samples with average organic carbon content. Keywords: methods, organic carbon, organic matter, certified samples


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