Comment on the matrix effect on photochromism of spiropyrans in bulk polymers

1980 ◽  
Vol 2 (3) ◽  
pp. 169-176 ◽  
Author(s):  
Claus D. Eisenbach
Keyword(s):  
Matrix Effect ◽  
The Matrix ◽  
Bulk Polymers

A Modified QuEChERS Extraction and LC-MS/MS Method for the Determination of Pesticide Residues in Curry Leaves (Murraya koenigii)

2019 ◽  
Vol 6 (1) ◽  
pp. 30-41
Author(s):  
Ranjith Arimboor ◽  
Karunkara Ramakrishna Menon ◽  
Natarajan Ramesh Babu ◽  
Haneesh Chandran
Keyword(s):  
Sample Preparation ◽  
Matrix Effect ◽  
Retention Time ◽  
Pesticide Residues ◽  
Mobile Phase ◽  
Preparation Technique ◽  
Modified Quechers ◽  
Curry Leaves ◽  
Ms Analysis ◽  
The Matrix

Background:Increased consumer demand for curry leaves free from pesticides demands fast and reliable analytical methods for the analysis of pesticide residues.Objective:The optimization of a QuEChERS based sample preparation technique with improved analytical accuracy by removing interfering matrix components for LC-MS/MS analysis of pesticide residues from curry leaves.Methods:A modified QuEChERS solid phase extraction method was developed and validated for the analysis of 26 pesticides in fresh and dried curry leaves. The effects of the sample preparation steps and column retention time on the matrix suppression of analyte ions were also evaluated.Results:Validation parameters were found within an acceptable range. The matrix effect evaluation studies showed that the QuEChERS sample preparation was able to minimize the ion suppression of analytes due to co-eluting matrix of components and that a d-SPE clean up step had major role in reducing matrix effect. The gradient mobile phase with longer retention time for analytes resulted in comparatively lesser matrix effects than the isocratic mobile phase of non-polar nature. Even after the clean up, a considerable number of compounds had more than 20% reduction in their MS response in the gradient mobile phase.Conclusion:This study emphasized the need of proper sample clean up before a LC-MS/MS analysis and the usage of matrix matched standards and mobile phase that ultimately results in an appropriate analyte separation in reasonable retention times.

On the matrix-effect in the excitation of the atomic emission spectra of magnesites

1965 ◽  
Vol 30 (4) ◽  
pp. 1303-1310 ◽  
Author(s):  
M. Matherny ◽  
N. Pliešovská ◽  
Ž. Rybárová
Keyword(s):  
Matrix Effect ◽  
Emission Spectra ◽  
Atomic Emission ◽  
The Matrix

Evaluation of the matrix effect in the quantitative bio-oil analysis by gas chromatography

Fuel ◽  
2021 ◽  
Vol 290 ◽  
pp. 119866
Author(s):  
Eliane Lazzari ◽  
Érica A. Souza Silva ◽  
Thiago R. Bjerk ◽  
Jaderson K. Schneider ◽  
Elina Bastos Caramão
Keyword(s):  
Gas Chromatography ◽  
Matrix Effect ◽  
Oil Analysis ◽  
Bio Oil ◽  
The Matrix

scholarly journals Dilution of QuEChERS Extracts Without Cleanup Improves Results in the UHPLC-MS/MS Multiresidue Analysis of Pesticides in Tomato

2021 ◽  
Author(s):  
Fabiane M. Stringhini ◽  
Lucila C. Ribeiro ◽  
Graziela I. Rocha ◽  
Juliana D. de B. Kuntz ◽  
Renato Zanella ◽  
...  
Keyword(s):  
Matrix Effect ◽  
Practical Method ◽  
Analysis Method ◽  
Multiresidue Analysis ◽  
Limit Of Quantification ◽  
Chromatography Tandem Mass Spectrometry ◽  
The Matrix ◽  
Liquid Chromatography Tandem Mass ◽  
Ultrahigh Performance Liquid Chromatography ◽  
Positive Results

AbstractTomato is well-known to be one of the most cultivated and consumed vegetables worldwide and frequently contain pesticide residues. Therefore, a simple multiresidue method was established and validated to determine 129 pesticides and metabolites in tomato samples using a modified acetate QuEChERS without cleanup for sample preparation and determination by ultrahigh-performance liquid chromatography tandem mass spectrometry (UHPLC-MS/MS). Dilution of the raw extract in different proportions of mobile phase was evaluated and a dilution of 10 times presented adequate results improving analysis performance while minimizing the matrix effect. Validation performed according to SANTE guideline presented satisfactory results. Practical method limit of quantification was 0.01 mg kg−1 for most compounds. Recoveries between 70 and 120% with precision ≤ 20% were found for most compounds and spike levels evaluated. Matrix effect results were not significant for most part of compounds. Method proved to be simple, robust, and effective to be applied in routine analysis. Method applicability was performed by analysis of samples commercialized in Brazil and positive results were found demonstrating the importance of the proposed method.

ChemInform Abstract: Matrix Effect. Dimerization of Silylenes at 77 K in the Matrix.

ChemInform ◽  
1987 ◽  
Vol 18 (37) ◽  
Author(s):  
A. SEKIGUCHI ◽  
K. HAGIWARA ◽  
W. ANDO
Keyword(s):  
Matrix Effect ◽  
The Matrix

Creatine kinase 2 mass measurement: methods comparison and study of the matrix effect

1999 ◽  
Vol 288 (1-2) ◽  
pp. 111-119 ◽  
Author(s):  
Maribel Sánchez ◽  
Francesca Canalias ◽  
Teresa Palencia ◽  
F.-Javier Gella
Keyword(s):  
Creatine Kinase ◽  
Matrix Effect ◽  
Mass Measurement ◽  
Measurement Methods ◽  
Methods Comparison ◽  
The Matrix ◽  
Comparison And Study

scholarly journals Polyphenols: From Theory to Practice

Foods ◽  
2021 ◽  
Vol 10 (11) ◽  
pp. 2595
Author(s):  
Alberto Bertelli ◽  
Marco Biagi ◽  
Maddalena Corsini ◽  
Giulia Baini ◽  
Giorgio Cappellucci ◽  
...  
Keyword(s):  
Matrix Effect ◽  
Virgin Olive Oil ◽  
Extra Virgin Olive Oil ◽  
Biological Properties ◽  
Health Claims ◽  
In Vitro Tests ◽  
The Matrix ◽  
Gender Characteristics

Background: The importance of polyphenols in human health is well known; these compounds are common in foods, such as fruits, vegetables, spices, extra virgin olive oil and wine. On the other hand, the different factors that modulate the biological activity of these compounds are less well known. Conceptualization of the work: In this review we took into account about 200 relevant and recent papers on the following topics: “polyphenols bioavailability”, “polyphenols matrix effect”, “food matrix effect”, “polyphenols-cytochromes interaction”, after having reviewed and updated information on chemical classification and main biological properties of polyphenols, such as the antioxidant, anti-radical and anti-inflammatory activity, together with the tricky link between in vitro tests and clinical trials. Key findings: the issue of polyphenols bioavailability and matrix effect should be better taken into account when health claims are referred to polyphenols, thus considering the matrix effect, enzymatic interactions, reactions with other foods or genetic or gender characteristics that could interfere. We also discovered that in vitro studies often underrate the role of phytocomplexes and thus we provided practical hints to describe a clearer way to approach an investigation on polyphenols for a more resounding transfer to their use in medicine.

scholarly journals A Systematic Approach to Overcome the Matrix Effect during LC-ESI-MS/ MS Analysis by different Sample Extraction Techniques

2011 ◽  
Vol 03 (06) ◽  
Author(s):  
Chinmoy Ghosh ◽  
Shashank Gaur ◽  
Chandrakant P. Shinde ◽  
Bhaswat Chakraborty
Keyword(s):  
Matrix Effect ◽  
Systematic Approach ◽  
Extraction Techniques ◽  
Esi Ms ◽  
Ms Analysis ◽  
Sample Extraction ◽  
The Matrix

Comparison of the matrix effect in laser induced breakdown spectroscopy analysis of coal particle flow and coal pellets

2021 ◽  
Author(s):  
Ziyu Yu ◽  
Shunchun Yao ◽  
Yuan Jiang ◽  
Weize Chen ◽  
Shuixiu Xu ◽  
...  
Keyword(s):  
Matrix Effect ◽  
Coal Particle ◽  
Particle Flow ◽  
Laser Induced Breakdown Spectroscopy ◽  
Spectroscopy Analysis ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown ◽  
The Matrix

Laser-induced breakdown spectroscopy analysis of coal particle flow presents milder matrix effect compared with coal pellet.

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