Theoretical treatment of first-order reversible reactions occurring in a chromatographic reactor, on the basis of consecutive reactions

1997 ◽  
Vol 45 (1) ◽  
pp. 149-154 ◽  
Author(s):  
R. Thede ◽  
E. Below ◽  
D. Haberland ◽  
S. H. Langer
Keyword(s):  
Theoretical Treatment ◽  
First Order ◽  
Consecutive Reactions ◽  
Reversible Reactions ◽  
Chromatographic Reactor

Consecutive reactions in the thermal decomposition of phenylalkyldiazirines

1977 ◽  
Vol 55 (20) ◽  
pp. 3596-3601 ◽  
Author(s):  
Michael T. H. Liu ◽  
Barry M. Jennings
Keyword(s):  
Thermal Decomposition ◽  
Kinetic Parameters ◽  
Diazo Compounds ◽  
First Order ◽  
Temperature Range ◽  
Decomposition Reactions ◽  
Consecutive Reactions ◽  
Rate Processes ◽  
Subsequent Decomposition

The thermal decomposition of phenyl-n-butyldiazirine and of phenylmethyldiazirine in DMSO and in HOAc have been investigated over the temperature range 80–130 °C. The intermediate diazo compounds, 1-phenyl-1-diazopentane and 1-phenyldiazoethane respectively have been detected and isolated. The decomposition of phenyl-n-butyldiazirine and the subsequent decomposition of its product, 1-phenyl-1-diazopentane, are an illustration of consecutive reactions. The kinetic parameters for the isomerization and decomposition reactions have been determined. The isomerization of phenylmethyldiazirine to 1-phenyldiazoethane is first order and probably unimolecular but the kinetics for the subsequent reactions of 1-phenyldiazoethane are complicated by several competing rate processes.

Selectivity Analysis for Networks Comprising Consecutive Reactions of Second and First Order

2018 ◽  
Vol 17 (5) ◽  
Author(s):  
Dmitry Yu. Murzin ◽  
Irina L. Simakova ◽  
Johan Wärnå
Keyword(s):  
Cascade Process ◽  
Reaction Parameters ◽  
One Pot ◽  
First Order ◽  
Consecutive Reactions

Abstract Coupling of second and first order reactions in one pot fashion through a cascade process is an often encountered process. Consecutive reactions of this type are considered and selectivity analysis is performed demonstrating dependence of selectivity pattern on reaction parameters.

Kinetics of Methylation of Methyl 5-Deoxy-α/β-D-xylofuranosides

2004 ◽  
Vol 69 (10) ◽  
pp. 1877-1888
Author(s):  
Mária Oščendová ◽  
Jitka Moravcová
Keyword(s):  
Sodium Hydroxide ◽  
Methyl Iodide ◽  
Rate Constants ◽  
Reaction Rate ◽  
Steric Effect ◽  
Order Reaction ◽  
Half Time ◽  
First Order ◽  
Consecutive Reactions ◽  
Kinetics Of

The kinetics of methylation of methyl 5-deoxy-α-D-xylofuranoside (1), methyl 5-deoxy-β-D-xylofuranoside (2) and their partly methylated derivatives with methyl iodide in the presence of sodium hydroxide in acetonitrile was studied. The reaction rate was independent of the base concentration during the first half-time only and the methylation proceeded as a first-order reaction. The rate constants of all side and consecutive reactions were calculated and the influence of both polar and steric effect is discussed. The methylation of 1 was highly regioselective giving almost exclusively 5-deoxy-2-O-methyl-α-D-xylofuranoside.

Kinetics of Oxidation of Columbium And Other Refractory Metals★

CORROSION ◽  
1962 ◽  
Vol 18 (10) ◽  
pp. 382t-389t ◽  
Author(s):  
J. N. ONG ◽  
W. M. FASSELL
Keyword(s):  
Phase Boundary ◽  
Nucleation And Growth ◽  
Rate Equations ◽  
Order Complex ◽  
Two Phase ◽  
Kinetics Of Oxidation ◽  
Chain Reactions ◽  
First Order ◽  
Consecutive Reactions ◽  
Kinetics Of

Abstract The oxidation of tungsten and molybdenum occurs by two consecutive reactions, forming first a suboxide then the trioxide. Tantalum and columbium oxidize by four simultaneous reactions: solution of oxygen in the metal, nucleation and growth of a suboxide phase at the metal surface and two phase boundary processes giving rise to two different modifications of the pentoxide. By assuming that all reactions are first order complex chain reactions, rate equations are formulated giving the rate of oxidation as a function of pressure, temperature and time. Regression rate expressions for the metals tungsten, tantalum and columbium above 700 C are given as;; and, respectively. The rate is expressed in cm/hr, T is in degrees K and Po2 in atmospheres pressure of oxygen. 3.8.4, 2.1,1, 6.3.5, 6.3.16, 6.3.13

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