Synthesis and surface activity of maleic anhydride-polyethylene glycol-phthalic anhydride polymeric surfactants

1988 ◽  
Vol 65 (8) ◽  
pp. 1346-1349 ◽  
Author(s):  
K. M. Chen ◽  
C. C. Tsai
Keyword(s):  
Polyethylene Glycol ◽  
Maleic Anhydride ◽  
Surface Activity ◽  
Phthalic Anhydride ◽  
Polymeric Surfactants

scholarly journals Preparation and Characterization of Some Hyperbranched Polyesteramides/Montmorillonite Nanocomposites

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Amal Amin ◽  
Moshera Samy
Keyword(s):  
Maleic Anhydride ◽  
Phthalic Anhydride ◽  
Succinic Anhydride ◽  
Thermal Analyses ◽  
Hyperbranched Polymers ◽  
H Nmr ◽  
Tga And Dsc ◽  
Montmorillonite Nanocomposites

Different polyesteramides hyperbranched polymers (HPEA1-6)/montomorillonite clay (MMT) nanocomposites were prepared with three different loading contents of clay (4, 10, and 15 wt%). The obtained nanocomposites were characterized via XRD, thermal analyses, and TEM. Generally, intercalation behavior was observed. The hyperbranched polyesteramides (HPEA1-6) were originally prepared by the bulky reaction between maleic anhydride (MAn), succinic anhydride (ScAn), and phthalic anhydride (PhAn) with either diethanolamine (DEA) or diisopropanolamine (DiPA). The resulting hyperbranched polyesteramides (HPEA1-6) were characterized by GPC, IR,1H-NMR, TGA, and DSC.

The Development of Thermostatically Biodegradable Composite

2021 ◽  
Vol 889 ◽  
pp. 44-49
Author(s):  
Yeng Fong Shih ◽  
Zheng Ting Chen ◽  
Wei Lun Lin ◽  
Po Chun Chiu ◽  
Chin Hsien Chiang ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Polyethylene Glycol ◽  
Maleic Anhydride ◽  
Impact Strength ◽  
Polylactic Acid ◽  
Deformation Temperature ◽  
Thermal Deformation ◽  
Biodegradable Composite ◽  
New Type ◽  
Polybutylene Succinate

The purpose of this research is to develop a new type of environmentally friendly container which has thermostatic effect and is biodegradable. This study is based on polylactic acid (PLA) and maleic anhydride grafted polybutylene succinate (MAPBS). Subsequently, the diatomite which adsorbed polyethylene glycol (PEG) was added to prepare a thermostatic biodegradable composite. The addition of MAPBS is to improve the compatibility between PLA and diatomite. In addition, the thermostatic effect, tensile strength, thermal deformation temperature and impact strength of the composite were investigated.

Synthesis and Evaluation of Nonionic Polymeric Surfactants Based on Acrylated Polyethylene Glycol

2012 ◽  
Vol 16 (2) ◽  
pp. 161-171 ◽  
Author(s):  
Abd El Monem Eissa ◽  
Manal El Hefnawy ◽  
Mohamed Deef Allah
Keyword(s):  
Polyethylene Glycol ◽  
Polymeric Surfactants

PRODUCTION AND PROPERTIES OF 2,3-BUTANEDIOL XXXVI. LINEAR POLYESTERS OF 2,3-BUTANEDIOL

1950 ◽  
Vol 28b (10) ◽  
pp. 652-659 ◽  
Author(s):  
R. W. Watson ◽  
N. H. Grace ◽  
J. L. Barnwell
Keyword(s):  
Molecular Weight ◽  
Maleic Anhydride ◽  
Phthalic Anhydride ◽  
Dibasic Acid ◽  
Side Reaction ◽  
Methyl Ethyl ◽  
Cyclic Monomer ◽  
Dimethyl Terephthalate ◽  
Ethyl Malonate ◽  
Methylene Groups

New polyesters with basic units containing 6, 7, 8, 9, 10, 13, and 14 chain atoms have been prepared from levo-2,3-butanediol and ethyl oxalate, ethyl malonate, dimethyl terephthalate, maleic anhydride, succinic, glutaric, adipic, azelaic, and sebacic acids, and from meso-2,3-butanediol and o-phthalic anhydride. Esterification of 2,3-butanediol with a dibasic acid, or its anhydride, is accompanied by a side reaction, in which butanone-2 and the cyclic methyl ethyl ketal are formed. The purified polyesters, with the exception of the poly-malonate, appear to be composed of regularly recurring acid and diol segments over the molecular weight ranges investigated. Without exception they are amorphous resins or balsams. Polyesters formed from saturated aliphatic dibasic acids become progressively softer as the number of methylene groups in the acid segment increases. The polymeric oxalate, on distillation in vacuo, is converted to a macrocrystalline cyclic monomer.

Synthesis and Characterization of Alkyd Resin Based on Soybean Oil Polyols

2011 ◽  
Vol 239-242 ◽  
pp. 1721-1724 ◽  
Author(s):  
Xiao Qing Zheng ◽  
Li Ting Yang ◽  
Kun Peng Wang
Keyword(s):  
Maleic Anhydride ◽  
Soybean Oil ◽  
Phthalic Anhydride ◽  
Alkyd Resin ◽  
Ring Opening ◽  
Molar Ratio ◽  
Synthesis And Characterization ◽  
Hydroxyl Value

Soybean oil-based alkyd resin was prepared using soy-based polyol, maleic anhydride and phthalic anhydride. The soy-based polyol was obtained through the epoxidization of soybean oil, followed by ring-opening with methanol and, the hydroxyl values of soybean oil-based polyols used in this reaction is 169.93 mgKOH/g. In the reactions of soy-based polyol, maleic anhydride and phthalic anhydride, the molar ratio of hydroxyl value is equal to carboxyl value and the molar ratio of maleic anhydride to phthalic anhydride is 2:1, 1:1 and 1:2, respectively. 1% hydroquinone based on total reactants was used as inhibitor of polymerization, 1% dibutyltin oxide was used as catalyst.

Novel polymeric surfactants and their applications in miniemulsions

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Lucretiu Cismaru ◽  
Thierry Hamaide ◽  
Marcel Popa
Keyword(s):  
Maleic Anhydride ◽  
Radical Polymerization ◽  
Vinyl Acetate ◽  
Miniemulsion Polymerization ◽  
Static Mixer ◽  
Polymeric Surfactants ◽  
Molecular Weights ◽  
Methoxypolyethylene Glycol ◽  
Mean Diameter ◽  
Evaporation Technique

AbstractN-Vinyl-2-pyrrolidone (NVP) and maleic anhydride (MA) copolymers were synthesized via radical polymerization. The synthesized copolymers were grafted with methoxypolyethylene glycol (MPEG) chains of different average molecular weights (350, 550, 750 Da). The grafted copolymers were used as surfactants in the synthesis of poly(ε-caprolactone) (PCL) nanoparticles in water by solvent evaporation technique. In order to further test the synthesized surfactants, the miniemulsion polymerization of vinyl acetate was performed. Two methods of obtaining miniemulsion were employed: a sonicator and a static mixer. The synthesized surfactants performed well in both type of experiments while in the case of static mixer nanoparticles with a lower polydispersity were obtained. Droplets with a mean diameter of 250 nm were obtained when using the sonicator while the static mixer led to formation of droplets with a mean diameter of 600 nm.

Synthesis and Characterization of Palm Oil and Polyethylene Glycol Based Polymeric Surfactants

2017 ◽  
Vol 23 (12) ◽  
pp. 11819-11823
Author(s):  
Yan Irawan ◽  
Ika Juliana ◽  
Indri Badria Adilina
Keyword(s):  
Polyethylene Glycol ◽  
Palm Oil ◽  
Synthesis And Characterization ◽  
Polymeric Surfactants
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