Microthermometry and noble gas isotope analysis of magmatic fluid inclusions in the Kerman porphyry Cu deposits, Iran: constraints on the source of ore-forming fluids

2021 ◽  
Author(s):  
Behnam Shafiei Bafti ◽  
Samuel Niedermann ◽  
Marta Sośnicka ◽  
Sarah A. Gleeson
Keyword(s):  
Fluid Inclusions ◽  
Noble Gas ◽  
Isotope Analysis ◽  
Magmatic Fluid ◽  
Porphyry Cu ◽  
Noble Gas Isotope

Fluid inclusions, H-O, S, Pb, and noble gas isotope studies of the Baiyun gold deposit in the Qingchengzi orefield, NE China

2019 ◽  
Vol 200 ◽  
pp. 37-53 ◽  
Author(s):  
Peng Zhang ◽  
Lin-Lin Kou ◽  
Yan Zhao ◽  
Zhong-Wei Bi ◽  
De-Ming Sha ◽  
...  
Keyword(s):  
Gold Deposit ◽  
Fluid Inclusions ◽  
Noble Gas ◽  
Ne China ◽  
Noble Gas Isotope ◽  
Isotope Studies

A preliminary assessment of the application of Sr, Nd, Pb, He and N isotope analysis to fluid inclusions in kimberlite olivine: A new approach to trace deep-mantle sources

2020 ◽  
Author(s):  
Andrea Giuliani ◽  
Janne M. Koornneef ◽  
Peter Barry ◽  
Patrizia Will ◽  
Henner Busemann ◽  
...  
Keyword(s):  
Isotopic Composition ◽  
Trace Element ◽  
Mass Spectrometer ◽  
Fluid Inclusions ◽  
Noble Gas ◽  
Isotope Analysis ◽  
Helium Isotope ◽  
New Approach ◽  
Deep Mantle ◽  
Mantle Sources

<p>Kimberlites are the deepest melts that reach Earth’s surface and, therefore, can provide unique insights into the composition and evolution of the convective mantle through time. Application of isotope geochemistry to trace the composition of kimberlite sources has thus far been hindered by the ubiquitous alteration and incorporation of xenocrystic material in kimberlite rocks. Bulk-kimberlite analyses are typically considered reliable for Nd and Hf isotopes due to their overwhelmingly higher concentrations in kimberlite melts compared to common mantle and crustal contaminants. Conversely, Sr and Pb isotope compositions of bulk kimberlite samples are seldom considered representative of their parental melts thus requiring analysis of robust magmatic phases, primarily perovskite. Addressing the primary (i.e. magmatic) isotopic composition of volatile elements, such as N and noble gases, requires analyses of volatile-rich phases, and fluid inclusions in olivine represent a typical primary target in mantle-derived magmas. However, fluid inclusions in kimberlitic olivine are dominantly secondary in origin. Secondary inclusions can form at any time after crystallisation of their mineral host, which requires assessment of the origin of trapped fluids (i.e. pristine magmatic fluids, crustal fluids of external derivation, or combination thereof) before their isotopic composition can be used to make inferences about kimberlite mantle sources.</p><p>Here we present trace-element and Sr-Nd-Pb-He-N isotopic compositions of multiple olivine aliquots representing two different magmatic units of the ~88 Ma Wesselton kimberlite (Kimberley, South Africa). The Sr and Nd isotopic composition of olivine analysed by isotope-dilution (ID) TIMS are within the narrow range of perovskite <sup>87</sup>Sr/<sup>86</sup>Sr (0.7043-0.7046) and whole-rock <sup>143</sup>Nd/<sup>144</sup>Nd (eNd<sub>i</sub> = 0.4–2.2) for the Kimberley kimberlites. These results indicate that the secondary fluid inclusions, which dominate the incompatible trace-element budget of olivine separates, have a pristine magmatic origin devoid of crustal contribution.</p><p>Helium isotope compositions were measured by laser heating of 1.6 to 9.8 mg of olivine using an ultrahigh-sensitivity compressor-source noble gas mass spectrometer. <sup>3</sup>He/<sup>4</sup>He ratios are between 1.6 R<sub>A</sub> and 3.7 R<sub>A</sub> (where R<sub>A</sub> indicates the atmospheric <sup>3</sup>He/<sup>4</sup>He ratio), values more radiogenic than MORBs but comparable to HIMU OIBs. These results indicate a high time-integrated (U+Th)/He ratio in the source of the Kimberley kimberlites, which is consistent with the moderately high (i.e. HIMU-like) time-integrated U/Pb ratio implied by elevated initial <sup>206</sup>Pb/<sup>204</sup>Pb in Wesselton olivine (19.1-19.5), Kimberley kimberlites (up to 19.9) and megacrysts in southern African Cretaceous kimberlites (up to 20.5). The combination of low <sup>3</sup>He/<sup>4</sup>He, moderately radiogenic <sup>87</sup>Sr/<sup>86</sup>Sr, and negative d<sup>34</sup>S values (-2.6‰ to -5.7‰) require a contribution from subducted recycled material in the source of the Kimberley kimberlites. Conversely, a preliminary N isotope analysis of Wesselton olivine by in-vacuo crushing using a noble gas mass spectrometer returned a mantle-like d<sup>15</sup>N of -2.9‰, which might suggest limited recycling of surface N (d<sup>15</sup>N >0‰) in the source of these kimberlites. We conclude that the combination of Sr-Nd-Pb and He-N isotope tracing of fluid inclusions in olivine can provide a robust new approach to address the composition of kimberlite sources and, therefore, the evolution of the deep mantle through time.</p>

scholarly journals Technical Note: Noble gas extraction procedure and performance of the Cologne Helix MC Plus multi-collector noble gas mass spectrometer for cosmogenic neon isotope analysis

2021 ◽  
Author(s):  
Benedikt Ritter ◽  
Andreas Vogt ◽  
Tibor J. Dunai
Keyword(s):  
Mass Spectrometer ◽  
Noble Gas ◽  
Primary Standard ◽  
Isotope Analysis ◽  
Extraction Procedure ◽  
Technical Note ◽  
High Mass ◽  
Experimental Setup ◽  
And Performance ◽  
The University

Abstract. We established a new laboratory for noble gas mass spectrometry that is dedicated for the development and application to cosmogenic nuclides at the University of Cologne (Germany). At the core of the laboratory are a state-of-the-art high mass resolution multicollector Helix MCPlus (Thermo-Fisher) noble gas mass spectrometer and a novel custom-designed automated extraction line. The Mass-spectrometer is equipped with five combined Faraday Multiplier collectors, with 1012 Ω and 1013 Ω pre-amplifiers for faraday collectors. We describe the extraction line and the automized operation procedure for cosmogenic neon and the current performance of the experimental setup. Performance tests were conducted using gas of atmospheric isotopic composition (our primary standard gas); as well as CREU-1 intercomparison material, containing a mixture of neon of atmospheric and cosmogenic composition. We use the results from repeated analysis of CREU-1 to assess the performance of the current experimental setup at Cologne. The precision in determining the abundance of cosmogenic 21Ne is equal or better than those reported for other laboratories. The absolute value we obtain for the concentration of cosmogenic 21Ne in CREU is indistinguishable from the published value.

First noble gas results from fluid inclusions of the Late Miocene-Pleistocene Macedonian volcanics

2021 ◽  
Author(s):  
Kata Molnár ◽  
Marjan Temovski ◽  
László Palcsu
Keyword(s):  
Fluid Inclusions ◽  
Late Miocene ◽  
Lithospheric Mantle ◽  
Noble Gas ◽  
Mantle Xenoliths ◽  
Gas Composition ◽  
The European Union ◽  
Large Area ◽  
Development Fund ◽  
Wide Range

<p>Late Miocene to Pleistocene volcanism within the Vardar zone (N. Macedonia) covers a large area, has a wide range in composition and it is largely connected to the tectonic evolution of the South Balkan extensional system, the northern part of the Aegean extensional regime. A recent study indicated an increasing rate of mantle metasomatism towards the younger centers in the region [1]. During the last stage of activity, ultrapotassic (UK) centers that formed between ca. 3.2 and 1.5 Ma originated from the lithospheric mantle beneath the region [2]. Although there are no reported mantle xenoliths from these centers, the erupted mafic rocks contain abundant olivine as phenocrysts [3]. Noble gas isotopic characteristics of fluid inclusions in olivine can reveal important information about the origin of the fluid and the metasomatic state of the lithospheric mantle. We analyzed for the first time the noble gas composition of fluid inclusions of olivine phenocrysts from the Mlado Nagoričane volcanic center, the northernmost member of the UK centers with an eruption age of 1.8 ± 0.1 Ma [2]. The R/R<sub>A</sub> ratios give a range of 3.1-4.5 with <sup>4</sup>He/<sup>20</sup>Ne values of 11.7-14.6. These R/R<sub>A</sub> values are lower than the MORB and the averaged subcontinental lithospheric values, and considering the negligible amount of atmospheric contribution, imply a more metasomatized character for the underlying lithospheric mantle beneath the region. Mantle-derived noble gases were detected in a recent geochemical study on the thermal springs and gas exhalations in the region, with up to 20% of mantle contribution calculated based on their noble gas composition using the MORB R/R<sub>A</sub> value [4]. These new Mlado Nagoričane fluid inclusion noble gas values indicate that the mantle contribution in the recent gas emissions in the region could be higher than what was thought.</p><p>This research was supported by the European Union and the State of Hungary, financed by the European Regional and Development Fund in the project of GINOP-2.3.2-15-2016-00009 ‘ICER’ project</p><p>[1] Molnár et al. 2020 – EGU2020-13101.</p><p>[2] Yanev et al., 2008 – Mineralogy and Petrology, 94(1-2), 45-60.</p><p>[3] Yanev et al., 2008 – Geochemistry, Mineralogy and Petrology, Sofia, 46, 35-67.</p><p>[4] Temovski et al. 2020 – EGU2020-2763.</p>

scholarly journals Origin of the Shangfang Tungsten Deposit in the Fujian Province of Southeast China: Evidence from Scheelite Sm–Nd Geochronology, H–O Isotopes and Fluid Inclusions Studies

Minerals ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 713 ◽  
Author(s):  
Lü-Yun Zhu ◽  
Shao-Yong Jiang ◽  
Run-Sheng Chen ◽  
Ying Ma
Keyword(s):  
Fluid Inclusions ◽  
Large Scale ◽  
Tectonic Setting ◽  
Critical Role ◽  
Isotope Analysis ◽  
Western Boundary ◽  
Ionization Mass ◽  
Tungsten Deposit ◽  
Nanling Range ◽  
Metallogenic Belt

The Shangfang deposit is a recently discovered large-scale tungsten deposit (66,500 t at 0.23% WO3), which is located near the western boundary of the Southeastern Coastal Metallogenic Belt (i.e., Zhenghe–Dafu fault), and adjacent to the northeast of the Nanling Range Metallogenic Belt. Unlike many other W–Sn deposits in this region that occur within or near the granites, the orebodies in the Sangfang deposit all occur within the amphibolite of Palaeoproterozoic Dajinshan Formation and have no direct contact to the granite. In this study, we carry out a thermal ionization mass spectrometer (TIMS) Sm-Nd isotope analysis for the scheelites from the orebody, which yields a Sm–Nd isochron age of 157.9 ± 6.7 Ma (MSWD = 0.96). This age is in good agreement with the previously published zircon U–Pb age (158.8 ± 1.6 Ma) for the granite and the molybdenite Re–Os age (158.1 ± 5.4 Ma) in the deposit. Previous studies demonstrated that the W–Sn deposits occurring between Southeastern Nanling Range and Coastal Metallogenic Belt mainly formed in the two periods of 160–150 Ma and 140–135 Ma, respectively. The microthermometry results of fluid inclusions in scheelite and quartz are suggestive of a near-isothermal (possibly poly-baric) mixing between two fluids of differing salinities. The H–O isotope results illustrate that the ore-forming fluids are derived from magma and might be equilibrated with metamorphic rocks at high temperature. The Jurassic granite pluton should play a critical role for the large hydrothermal system producing the Shangfang W deposit. Furthermore, the negative εNd(t) of −14.6 obtained in the Shanfang scheelite suggests for the involvement of the deep crustal materials. In general, subduction of the paleo-Pacific plate caused an extensional tectonic setting with formation of the Shangfang granites and related W mineralization, the geological background of which is similar to other W deposits in the Nanling Range Metallogenic Belt.

Sign in / Sign up

Export Citation Format

Share Document