Speciation of rare earth elements in soil by sequential extraction then HPLC coupled with visible and ICP-MS detection

2001 ◽  
Vol 370 (8) ◽  
pp. 1041-1047 ◽  
Author(s):  
Qiuquan Wang ◽  
B. Huang ◽  
Zhenwei Guan ◽  
Limin Yang ◽  
Bin Li
2018 ◽  
Vol 410 (29) ◽  
pp. 7635-7643 ◽  
Author(s):  
Federica Maraschi ◽  
Andrea Speltini ◽  
Tiziana Tavani ◽  
Maria Grazia Gulotta ◽  
Daniele Dondi ◽  
...  

2021 ◽  
Vol 882 (1) ◽  
pp. 012020
Author(s):  
I Setiawan

Abstract Indonesia needs a proven technology for REE extraction to build a national REE industry. Monazite that has been recovered from placer deposits at Bangka-Belitung areas is the most potential REE source. In the future, ion adsorption type will be another potential source of REE deposits. This paper describes the sequential REE extraction of the weathered crusts of granitoids from Sibolga using sequential extraction ICP-MS analysis is applied to determine bulk samples mineralogical compositions and REE content. The total REE (∑REE) content of weathered crusts of granitoids from Sibuluhan Sihaporas A ranges from 265 to 479 ppm, while the amount of ∑REE leached by sequential extraction range from 151 to 263 ppm, and the percentage of adsorbed ∑REE ranges from 55 to 74%. In comparison, Sibuluhan Sihaporas B ranges from 302 to 634 ppm, 82 to 198 ppm, and 28 to 44%, respectively. ∑REE content of weathered granitoids crusts from Sarudik ranges from 135 to 219 ppm, while that SREE leached by sequential extraction range from 21 to 82 ppm, and percentage of adsorbed ∑REE range from 11 to 50 %, while that Sibolga Julu ranges from 191 to 304 ppm, 111 to 138 ppm, and 27 to 44%.


2021 ◽  
pp. 1-41
Author(s):  
Lianfu Hai ◽  
Qinghai Xu ◽  
Caixia Mu ◽  
Rui Tao ◽  
Lei Wang ◽  
...  

In the Tanshan area, which is at the Liupanshui Basin, abundant oil shale resources are associated with coals. We analyzed the cores, geochemistry of rare earth elements (REE) and trace element of oil shale with ICP-MS technology to define the palaeo-sedimentary environment, material source and geological significance of oil shale in this area. The results of the summed compositions of REE, and the total REE contents (SREE), in the Yan'an Formation oil shale are slightly higher than the global average of the composition of the upper continental crustal (UCC) and are lower than that of North American shales. The REE distribution pattern is characterized by right-inclined enrichment of light rare earth elements (LREE) and relative loss of heavy rare earth elements (HREE), which reflects the characteristics of crustal source deposition. There is a moderate degree of differentiation among LREE, while the differences among HREE are not obvious. The dEu values show a weak negative anomaly and the dCe values show no anomaly, which are generally consistent with the distribution of REE in the upper crust. The characteristics of REE and trace elements indicate that the oil shale formed in an oxygen-poor reducing environment and that the paleoclimatic conditions were relatively warm and humid. The degree of differentiation of REE indicates that the sedimentation rate in the study area was low, which reflected the characteristics of relatively deep sedimentary water bodies and distant source areas. The results also proved that the source rock mainly consisted of calcareous mudstone, and a small amount of granite was also mixed in.


2018 ◽  
Vol 10 (33) ◽  
pp. 4094-4103 ◽  
Author(s):  
Fernanda Pollo Paniz ◽  
Tatiana Pedron ◽  
Bruna Moreira Freire ◽  
Daiane Placido Torres ◽  
Fábio Ferreira Silva ◽  
...  

There are several international regulations regarding trace elements. The use of ICP-MS for their determination is usually a difficult task, especially when Hg is one of the target elements.


Biology ◽  
2021 ◽  
Vol 10 (10) ◽  
pp. 1058
Author(s):  
Stefano Loppi ◽  
Riccardo Fedeli ◽  
Giulia Canali ◽  
Massimo Guarnieri ◽  
Stefano Biagiotti ◽  
...  

In the Valdichiana area (Tuscany, Italy) an ancient native landrace of elephant garlic (Allium ampeloprasum L.), locally known as “Aglione della Valdichiana”, has long been cultivated. The aim of this study was to check whether there are differences in the mineral and nutraceutical profiles of the Aglione della Valdichiana cultivated conventionally and organically. Based on the analysis by ICP-MS of a wide array of major, minor, essential, and non-essential trace elements as well as rare earth elements, and the evaluation of the content of polyphenols, flavonoids, antioxidants, soluble proteins, soluble sugars, and starch, as well as the weight and water content, it was concluded that differences in the mineral and nutraceutical profiles of organically and conventionally grown bulbs were very limited. Only a statistically (p < 0.05) higher concentration of Cd (+2620%), Co (+113%), Mn (+55%), Rb (+180%), and Sb (+180%), as well as glucose (+37%) in conventionally cultivated bulbs emerged. Cadmium was the only element slightly higher than in the “reference plant,” but with a negligible risk (three orders of magnitude lower) for human health based on consumption. It is concluded that we failed to find evidence of healthier food or a higher nutraceutical quality for organically cultivated elephant garlic.


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