Pursuit of electroconducting thermoplastic vulcanizates: activated charcoal-filled polypropylene/ethylene–propylene–diene monomer blends with upgraded electrical, mechanical and thermal properties

2018 ◽  
Vol 76 (4) ◽  
pp. 2005-2020 ◽  
Author(s):  
Muhammad Sarfraz ◽  
Zia ur Rehman ◽  
M. Ba-Shammakh
2017 ◽  
Vol 52 (15) ◽  
pp. 1989-1995 ◽  
Author(s):  
AM El-Dakhakhny ◽  
AF Ahmed ◽  
M Rutkevičius ◽  
S El-Marsafy ◽  
E Abadeer

In this study, we develop and characterize an asbestos-free rubber composite for potential use as a rocket motor insulator. The insulator is based on ethylene propylene diene monomer blended with aramid fiber (Kevlar) in the pulp form (KP), together with alumina and/or silica as reinforcement. Different formulations based on these fillers were prepared. The fillers were dispersed in the ethylene propylene diene monomer polymeric matrix to obtain a homogenous master batch for curing. We analyzed and compared physical, mechanical and thermal properties of different compositions (density, hardness, tensile strength, elongation, ablation resistance and mass loss on heating). Reinforcement of ethylene propylene diene monomer with Kevlar improves the performance of the material with respect to mechanical and thermal properties, while not improving well the performance with respect to ablation resistance. Using hybrid reinforcement (KP + alumina + silica) within ethylene propylene diene monomer improves the performance of ethylene propylene diene monomer with respect to mechanical properties, thermal properties, ablation resistance and thermal decomposition resistance. The optimum performance of the insulation material was achieved when the formulation consisted of 10 part per hundred ratio KP with even amounts of alumina and silica. A novel composite engineered for improved insulation of solid rocket motors using the hybrid reinforcements was developed for the first time, which can be applied in future space missions.


2019 ◽  
Vol 956 ◽  
pp. 192-200
Author(s):  
Yu Feng Bai ◽  
Xin Xin Cao ◽  
Ming Lu Xu ◽  
Xiao Fang He ◽  
Guo Hui Cai

For the better mechanical and thermal properties of polypropylene (PP), PP sea-island structured composites with elastomer ethylene-propylene-diene monomer (EPDM) and coal powder were prepared by melt-blending method. Coupling agent γ-methacryloxypropyltrimethoxysilane (KH-570) was used as modifier to improve the superficial capacity of coal powder. The structural changes and properties of modified coal powder and composites were characterized and analyzed by Fourier Transform Infrared Spectroscopy (FTIR), surface contact angle analysis, scanning electron microscope (SEM), thermogravimetric analysis (TGA) and mechanical testing. Results show that the modified coal powder has good hydrophobicity and sea-island structure is beneficial in improving the comprehensive performance of composites. The contact angle increases from 33.8° to 91.6° after modification. The initial decomposition temperature (T0) and largest weight loss temperature (Tmd) both have an increase with coal powder content and the maximum are 431.02 °C and 465.33 °C. The mechanical properties tend to go up first and then down with the addition of coal powder. PP/26EPDM/4coal composite has best mechanical properties as well as the impact strength and elongation at break are 60.9 MPa, 615.0%, respectively.


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