scholarly journals Biodegradation of cellulose fibers functionalized with CuO/Cu2O nanoparticles in combination with polycarboxylic acids

Cellulose ◽  
2021 ◽  
Author(s):  
Brigita Tomšič ◽  
Darka Marković ◽  
Vukašin Janković ◽  
Barbara Simončič ◽  
Jasmina Nikodinovic-Runic ◽  
...  

AbstractSustainable biodegradation of cellulose fibers is critical for composting after the end of a product’s life. In this study, we aimed at investigating the effect of in situ synthesized CuO/Cu2O nanoparticles (NPs) with biocidal concentration on the biodegradation behavior of cotton fibers pretreated with 1,2,3,4-butanetetracarboxylic acid (BTCA) and succinic acid (SUC). Biodegradation of the fibers was evaluated by soil burial tests in garden soil and in model compost after different soil burial times. The results showed that the application of BTCA, SUC, and CuO/Cu2O NPs did not affect the hydrophilicity of the samples and allowed a smooth biodegradation process. The morphological and chemical changes during biodegradation, evaluated by FESEM and FTIR analyses, showed that the presence of CuO/Cu2O NPs slightly hindered biodegradation of the fibers after 18 days in soil. However, biodegradation was much faster in the model compost, where all samples, regardless of their chemical modification, almost completely degraded after only 11 days. Intense microbial growth on the surface of all samples after nine days of burial in garden soil and model compost was confirmed by the presence of proteins produced by the microorganisms. The total number of microorganisms in the garden soil remained almost unchanged and increased in the model compost after the burial test. The only exception was the sample with the highest concentration of CuO/Cu2O NPs, which caused a reduction in microbial growth but not complete growth inhibition. These results clearly showed that during material degradation, the cellulosic material supporting microbial growth prevailed over the suppression of microbial growth by CuO/Cu2O NPs.

2015 ◽  
Vol 28 (1) ◽  
pp. 43-48 ◽  
Author(s):  
Stéphanie Degoutin ◽  
Camille Saffre ◽  
Delphine Ruffin ◽  
Maryse Bacquet ◽  
Bernard Martel

The aim of this study was to prepare ion exchange textiles (IET) by grafting carboxylic functions onto the surface of polyethylene terephthalate (PET) nonwoven fabrics in order to capture metals in leachates extracted from dredged sediment samples, taken from Dunkerque seaport. A pad/dry/cure coating process, based on the in situ polymerization of a mixture consisting of maltodextrin and a polycarboxylic acid on the textile structure, was applied. We used either citric acid (CTR) or 1,2,3,4-butanetetracarboxylic acid (BTCA) as polycarboxylic acids. The amount of ion exchange functions on the geotextiles was first measured and we evaluated their adsorption capacities towards metal cations. To reach that purpose, a first test was carried out on solutions prepared with lead (Pb) in the absence or presence of NaCl, to mimic seawater saline conditions. The presence of NaCl led to a moderate reduction of 25% in lead removal by the IET. The second test was carried out on a sediment leachate. This leachate being weakly contaminated, we artificially doped it with cadmium, copper, lead and zinc in order to evaluate the potential utility of the geotextile treatment. The functionalized textiles adsorbed more than 60% of the lead and zinc. A complete removal of copper was reached for CTR-based IET and the textiles showed less efficiency towards cadmium in the considered mixture.


2014 ◽  
Vol 9 (3) ◽  
pp. 155892501400900
Author(s):  
Kristoffer Lund ◽  
Harald Brelid

Cross-linked fluff pulp fibers for use in, for example, acquisition layers in absorption products can be found in the patent literature. Cross-linking improves properties such as the wet resilience of fluff pulp fiber networks. Among the more commonly seen cross-linkers are polycarboxylic acids, such as 1,2,3,4-butanetetracarboxylic acid (BTCA). These acids form ester bonds with the hydroxyl groups in the fiber wall. In this study, softwood kraft pulp fibers were cross-linked with BTCA. The swelling behavior of the fibers and properties related to acquisition in absorption products were studied. It was found that the water retention value (WRV) decreased as a consequence of the introduced cross-linker. After deprotonization of a large part of the introduced carboxylic acids, the WRV increased, but the cross-linker was still able to limit significant swelling of the fiber wall. The wet bulk under load of fiber networks, composed of cross-linked fibers, generally increased with a decrease in WRV. Furthermore, it was found that the property development obtained after a cross-linking reaction with BTCA may be predicted by introducing a relative reaction intensity, RIrel, that takes into account both time and temperature in the curing step. This shows that the time and temperature in the curing step are interchangeable.


Cellulose ◽  
2017 ◽  
Vol 25 (1) ◽  
pp. 829-841 ◽  
Author(s):  
Darka Marković ◽  
Matea Korica ◽  
Mirjana Kostić ◽  
Željko Radovanović ◽  
Zoran Šaponjić ◽  
...  

2013 ◽  
Vol 127 (5) ◽  
pp. 509-510 ◽  
Author(s):  
H Mohammed ◽  
P Martinez-Devesa

AbstractObjective:To demonstrate that ventilation tubes can remain in situ much longer than expected, and that the materials used in the manufacturing of these tubes can degrade and cause complications. Long-term follow up and replacement of the tube is recommended.Method:Case report and review of the literature concerning the use of long-term ventilation tubes.Results:In the case reported, the ventilation tube was in place for 19 years, which resulted in chronic ear discharge. When it was removed, it was noted that the tube itself had degraded and had caused a chronic inflammatory reaction.Conclusion:We recommend that the long-term use of ventilation tubes is followed up and that the tube is replaced before material degradation takes place.


1984 ◽  
Vol 24 (01) ◽  
pp. 33-37 ◽  
Author(s):  
Gary E. Jenneman ◽  
Roy M. Knapp ◽  
Michael J. McInerney ◽  
D.E. Menzie ◽  
D.E. Revus

Abstract Experiments were conducted to study the feasibility of using microorganisms in EOR, particularly for the correction of permeability variation. The use of microorganisms requires the ability to transport viable cells as well as the nutrients required for cellular growth through reservoir formations. Nutrients such is glucose, peptone-protein, and phosphate and ammonium ions were transported through brine-saturated Berea sand-stone cores in amounts sufficient to suppose microbial growth. Viable bacterial cells were transported to through sandstone cores of 170-md permeability. Less than1% of the influent cell concentration was recovered in the effluent, indicating a high degree of cell retention inside the core. The addition of nutrients to these cores and subsequent incubation to allow for microbial growth resulted in permeability reductions of 60 to 80%. These data show that the growth of microorganisms significantly reduces the permeability of porous rock. permeability of porous rock. Introduction The major objective of this study is to investigate experimentally thepotential use of microorganisms in oil recovery. In this investigation, potential use of microorganisms in oil recovery. In this investigation, petroleum engineering and microbiology are used to understand the physical petroleum engineering and microbiology are used to understand the physical mechanisms of oil recovery by bacterial processes. One process under study is permeability reduction by the in-situ growth of bacteria as a proposed solution to reservoir heterogeneity problems, specifically permeability variation, that detrimentally affect the performance of waterflood and EOR projects. Numerous investigation have experimentally studied the plugging projects. Numerous investigation have experimentally studied the plugging effect of bacteria on Berea sandstone cores. However, their work dealt with injectivity problems resulting from wellbore plugging caused by bacteria. Theory Reservoir heterogeneity has a significant effect on the oil recovery efficiency of a waterflood or EOR process. The recovery efficiency ( )may be defined as a combination of a microscopic oil-displacement efficiency ( ) and volumetric sweep efficiency ( ). ............................(1) Permeability variation greatly influences the volumetric sweep efficiency Permeability variation greatly influences the volumetric sweep efficiency and its two-dimensional components of areal and vertical sweep efficiency. Reservoir selective plugging techniques developed in the past to modify permeability variations included a wide variety of plugging agents. The permeability variations included a wide variety of plugging agents. The application and success of these methods were limited. Meehan et al. demonstrated that additional oil recovery is possible if the channeling water in a waterflood can be immobilized. The residual oil saturation (ROS) remaining after waterflooding is apotential target for the application of a reservoir selective plugging potential target for the application of a reservoir selective plugging process using the in-situ growth of bacteria. The theoretical concept of process using the in-situ growth of bacteria. The theoretical concept of this process involves the introduction of viable bacteria in the aqueous displacing fluid to be injected into the high- permeability water-sweptzones. The selectivity is based on the experimental evidence that bacteria more readily, plug high-permeability zones since these zones receive a greater proportion of the fluid flow. Once the bacteria are in place, a designed volume of nutrients may be injected into the reservoir to support in-situ metabolism of the bacteria. The result of this metabolism is the production of cellular mass capable of initiating physical plugging. The production of cellular mass capable of initiating physical plugging. The physical plugging results in a reduction of original permeability mid can physical plugging results in a reduction of original permeability mid can be expressed as the ratio of impaired to original permeability. The resumption of injection will result in a diversion of the displacing fluid from plugged high-permeability zones to unswept zones and, thus, improvesweep efficiency. This reduces the ROS, decreases WOR, and increases theultimate recovery of oil in place. The success of an in-situ microbial plugging process depends on the ability to (1) transport the microorganisms plugging process depends on the ability to (1) transport the microorganisms throughout the reservoir rock stratum, (2) transport nutrients required for microbial growth and metabolism and (3) reduce the apparent permeability of the reservoir rock stratum as a result of microbial growth and metabolism. Description of Equipment and Processes Berea sandstone cores obtained from Cleveland Quarrics (Amherst, OH) werecut into cylinders 2 × 8 in. [5 × 20 cm] with a coring device. Cores were either steamcleaned for 2 weeks and then dried or used as received. Each core was coated with epoxy, cast in a resin mold (Evercoat Fiberglassresin), and cut into specified lengths. SPEJ p. 33


Holzforschung ◽  
2006 ◽  
Vol 60 (4) ◽  
pp. 439-444 ◽  
Author(s):  
Sandra Bischof Vukusic ◽  
Drago Katovic ◽  
Christian Schramm ◽  
Jelena Trajkovic ◽  
Bogoslav Sefc

Abstract Wood specimens of fir (Abies alba Mill) and beech (Fagus sylvatica L.) were chemically modified using polycarboxylic acids (PCA), cured by convection heating or microwave treatment and analyzed by HPLC. A new non-formaldehyde cross-linking system was composed of citric acid (CA) and 1,2,3,4-butanetetracarboxylic acid (BTCA), which are representative polycarboxylic acids (PCAs). These reagents require phosphono-based catalysts, so a sodium hypophosphite (SHP) catalyst was used in this study. The effects of PCA treatment were compared with a previously introduced 1,3-dimethylol 4,5-dihydroxy ethylene urea (DMDHEU) treatment. The dimensional stability of the modified wood was determined in terms of the anti-swelling efficiency (ASE) using the water soak/oven dry method. The results revealed an improvement in ASE for wood modified with PCA compared to modification with DMDHEU. Qualitative and quantitative determinations of bound acids were performed by HPLC. Further intensification of the wood modification process and an increase in the quality of wood-based materials were achieved using microwave treatment. Among other benefits, the formation of cross-links between the wood and the reagent components led to an improvement in the tensile strength retention, particularly in combination with the microwave treatment.


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