material degradation
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2021 ◽  
Vol 8 (6) ◽  
pp. 871-880
Author(s):  
Dmitry Zheldakov ◽  
Radik Mustafin ◽  
Vladimir Kozlov ◽  
Askar Gaysin ◽  
Dmitriy Sinitsin ◽  
...  

This paper aims to develop a method to determine material durability based on physicochemical laws that describe chemical corrosion in building enclosures. The subject of this research is studying the chemical corrosion in the material in building constructions. The object of this research is the material of building ceramics. Methods that the authors used for reaching this goal include developing a multi-staged process of material degradation of building ceramics, conduction of thermodynamic calculations, and conducting laboratory research on process kinetics. The results of kinetic researches are generalized based on a developed mathematical model. This comprehensive approach to solving the goal task allowed obtaining the following results: research methods of chemical processes in brick material and its plaster on humidification were developed. A mathematical model for evaluating material degradation in time with the changing climatic influence on enclosure was developed.


Author(s):  
Kevin Woeppel ◽  
Christopher Hughes ◽  
Angelica J. Herrera ◽  
James R. Eles ◽  
Elizabeth C. Tyler-Kabara ◽  
...  

Brain-computer interfaces are being developed to restore movement for people living with paralysis due to injury or disease. Although the therapeutic potential is great, long-term stability of the interface is critical for widespread clinical implementation. While many factors can affect recording and stimulation performance including electrode material stability and host tissue reaction, these factors have not been investigated in human implants. In this clinical study, we sought to characterize the material integrity and biological tissue encapsulation via explant analysis in an effort to identify factors that influence electrophysiological performance. We examined a total of six Utah arrays explanted from two human participants involved in intracortical BCI studies. Two platinum (Pt) arrays were implanted for 980 days in one participant (P1) and two Pt and two iridium oxide (IrOx) arrays were implanted for 182 days in the second participant (P2). We observed that the recording quality followed a similar trend in all six arrays with an initial increase in peak-to-peak voltage during the first 30–40 days and gradual decline thereafter in P1. Using optical and two-photon microscopy we observed a higher degree of tissue encapsulation on both arrays implanted for longer durations in participant P1. We then used scanning electron microscopy and energy dispersive X-ray spectroscopy to assess material degradation. All measures of material degradation for the Pt arrays were found to be more prominent in the participant with a longer implantation time. Two IrOx arrays were subjected to brief survey stimulations, and one of these arrays showed loss of iridium from most of the stimulated sites. Recording performance appeared to be unaffected by this loss of iridium, suggesting that the adhesion of IrOx coating may have been compromised by the stimulation, but the metal layer did not detach until or after array removal. In summary, both tissue encapsulation and material degradation were more pronounced in the arrays that were implanted for a longer duration. Additionally, these arrays also had lower signal amplitude and impedance. New biomaterial strategies that minimize fibrotic encapsulation and enhance material stability should be developed to achieve high quality recording and stimulation for longer implantation periods.


Cellulose ◽  
2021 ◽  
Author(s):  
Brigita Tomšič ◽  
Darka Marković ◽  
Vukašin Janković ◽  
Barbara Simončič ◽  
Jasmina Nikodinovic-Runic ◽  
...  

AbstractSustainable biodegradation of cellulose fibers is critical for composting after the end of a product’s life. In this study, we aimed at investigating the effect of in situ synthesized CuO/Cu2O nanoparticles (NPs) with biocidal concentration on the biodegradation behavior of cotton fibers pretreated with 1,2,3,4-butanetetracarboxylic acid (BTCA) and succinic acid (SUC). Biodegradation of the fibers was evaluated by soil burial tests in garden soil and in model compost after different soil burial times. The results showed that the application of BTCA, SUC, and CuO/Cu2O NPs did not affect the hydrophilicity of the samples and allowed a smooth biodegradation process. The morphological and chemical changes during biodegradation, evaluated by FESEM and FTIR analyses, showed that the presence of CuO/Cu2O NPs slightly hindered biodegradation of the fibers after 18 days in soil. However, biodegradation was much faster in the model compost, where all samples, regardless of their chemical modification, almost completely degraded after only 11 days. Intense microbial growth on the surface of all samples after nine days of burial in garden soil and model compost was confirmed by the presence of proteins produced by the microorganisms. The total number of microorganisms in the garden soil remained almost unchanged and increased in the model compost after the burial test. The only exception was the sample with the highest concentration of CuO/Cu2O NPs, which caused a reduction in microbial growth but not complete growth inhibition. These results clearly showed that during material degradation, the cellulosic material supporting microbial growth prevailed over the suppression of microbial growth by CuO/Cu2O NPs.


Materials ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6686
Author(s):  
Bartosz Miller ◽  
Leonard Ziemiański

This paper presents a numerical study of the feasibility of using vibration mode shapes to identify material degradation in composite structures. The considered structure is a multilayer composite cylinder, while the material degradation zone is, for simplicity, considered a square section of the lateral surface of the cylinder. The material degradation zone size and location along the cylinder axis are identified using a deep learning approach (convolutional neural networks, CNNs, are applied) on the basis of previously identified vibration mode shapes. The different numbers and combinations of identified mode shapes used to assess the damaged zone size and location were analyzed in detail. The final selection of mode shapes considered in the identification procedure yielded high accuracy in the identification of the degradation zone.


2021 ◽  
Vol 325 ◽  
pp. 162-167
Author(s):  
Jaroslava Zatloukalová ◽  
Jiří Pazderka ◽  
Petr Lukáš ◽  
Pavel Reiterman

Quantification of water transport properties of concrete is crucial for prediction of the material degradation processes. In case of 80 years ́ old concrete of fortification structures of former Czechoslovakia, its permeability is the determining factor of the scale of degradation. Mercury intrusion porosimetry was used to characterize the porous system of seven existing bunkers from the defence line ”Pražská čára” and to calculate the permeability using model of Bágel and Živica. Results showed the altered structure of the old concrete, characterized by no notable peaks, which mark the critical pore radius most responsible for water intake. The majority of pores are small micropores, which does not contribute much in the water transport. However, calculated permeability is high enough to be the cause of several degradation processes. The performed program also confirmed high variability of permeability properties between individual structures.


Author(s):  
Shaista Manzoor ◽  
Nafiaah Naqash ◽  
Gowhar Rashid ◽  
Rahul Singh

Polymers ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 3245
Author(s):  
Lixin Song ◽  
Yongchao Li ◽  
Xiangyu Meng ◽  
Ting Wang ◽  
Ying Shi ◽  
...  

Poly (lactic acid) (PLA)-Poly (propylene carbonate) (PPC) block copolymer compatibilizers are produced in incompatible 70wt%PLA/PPC blend by initiating transesterification with addition of 1% of tetra butyl titanate (TBT) or by chain extension with addition of 2% of 2,4-toluene diisocyanate (TDI). The above blends can have much better mechanical properties than the blend without TBT and TDI. The elongation at break is dramatically larger (114% with 2% of TDI and 60% with 1% of TBT) than the blend without TDI and TBT, with a slightly lower mechanical strength. A small fraction of the copolymer is likely formed in the PLA/PPC blend with addition of TBT, and a significant amount of the copolymer can be made with addition of TDI. The copolymer produced with TDI has PPC as a major content (~70 wt%) and forms a miscible interphase with its own Tg. The crystallinity of the blend with TDI is significantly lower than the blend without TDI, as the PLA blocks of the copolymer in the interphase is hardly to crystallize. The average molecular weight increases significantly with addition of TDI, likely compensating the lower mechanical strength due to lower crystallinity. Material degradation can occur with addition of TBT, but it is very limited with 1% of TBT. However, compared with the blends without TBT, the PLA crystallinity of the blend with 1%TBT increases sharply during the cooling process, which likely compensates the loss of mechanical strength due to the slightly material degradation. The added TDI does not have any significant impact on PLA lamellar packing, but the addition of TBT can make PLA lamellar packing much less ordered, presumably resulted from much smaller PPC domains formed in the blend due to better compatibility.


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