Novel segregated-structure phase change materials composed of paraffin@graphene microencapsules with high latent heat and thermal conductivity

2017 ◽  
Vol 53 (4) ◽  
pp. 2566-2575 ◽  
Author(s):  
Wenbin Yang ◽  
Li Zhang ◽  
Yongli Guo ◽  
Zhuoni Jiang ◽  
Fangfang He ◽  
...  
Author(s):  
Xiaobo Li ◽  
Hengzhi Wang ◽  
Hui Wang ◽  
Sohae Kim ◽  
Keivan Esfarjani ◽  
...  

Inorganic materials and organic salts are usually used as phase change materials (PCMs) for thermal energy storage. Some of these materials have high latent heat of fusion; however one major drawback of these materials is the low thermal conductivity, which limits the rate of charging and discharging process. In this paper, we studied metallic alloys (eutectic alloys or alloys with a narrow melting temperature range) as phase-change materials, which have both high thermal conductivity and high latent heat of fusion. A formula was presented from entropy change to predict the latent heat of fusion of metallic alloys. We found that the latent heat of fusion of alloys can be expressed from three different contributions: the latent heat from each element, the sensible heat, and the mixing entropy. From the theory we also showed that latent heat of fusion could be greatly increased by maximizing the entropy of mixing, which can be realized by introduce more elements in the alloys, i.e., form ternary alloys by adding elements to binary alloys. This idea is demonstrated by the synthesis and measurement of the binary alloy 87.8Al-12.2Si (at%) and ternary alloy 45Al-40Si-15Fe (at%). The metallic alloy is synthesized by hot pressing method. The latent heat of fusion of 45Al-40Si-15Fe (at%) is about 865 kJ/kg with melting temperature from 830 °C to 890 °C from the differential scanning calorimetry (DSC) measurement, comparing with 554.9 kJ/kg and 578.3 °C for the binary alloy 87.8Al-12.2Si (at%). From the binary to the ternary alloy, the contribution to the latent heat from mixing entropy increases by 17%.


2019 ◽  
Vol 141 (5) ◽  
Author(s):  
S. Arunachalam

Energy storage helps in waste management, environmental protection, saving of fossil fuels, cost effectiveness, and sustainable growth. Phase change material (PCM) is a substance which undergoes simultaneous melting and solidification at certain temperature and pressure and can thereby absorb and release thermal energy. Phase change materials are also called thermal batteries which have the ability to store large amount of heat at fixed temperature. Effective integration of the latent heat thermal energy storage system with solar thermal collectors depends on heat storage materials and heat exchangers. The practical limitation of the latent heat thermal energy system for successful implementation in various applications is mainly from its low thermal conductivity. Low thermal conductivity leads to low heat transfer coefficient, and thereby, the phase change process is prolonged which signifies the requirement of heat transfer enhancement techniques. Typically, for salt hydrates and organic PCMs, the thermal conductivity range varies between 0.4–0.7 W/m K and 0.15–0.3 W/m K which increases the thermal resistance within phase change materials during operation, seriously affecting efficiency and thermal response. This paper reviews the different geometry of commercial heat exchangers that can be used to address the problem of low thermal conductivity, like use of fins, additives with high thermal conductivity materials like metal strips, microencapsulated PCM, composite PCM, porous metals, porous metal foam matrix, carbon nanofibers and nanotubes, etc. Finally, different solar thermal applications and potential PCMs for low-temperature thermal energy storage were also discussed.


2020 ◽  
Vol 396 ◽  
pp. 125265 ◽  
Author(s):  
Yunzhi Tan ◽  
Yu Xiao ◽  
Rui Chen ◽  
Changlin Zhou ◽  
Lei Wang ◽  
...  

2020 ◽  
pp. 004051752097561
Author(s):  
Wei Zhang ◽  
Shang Hao ◽  
Jiali Weng ◽  
Yibo Zhang ◽  
Jiming Yao ◽  
...  

We report on the impregnation-based preparation of composite phase change materials (CPCMs) with thermal storage properties, using paraffin wax and multi-walled carbon nanotubes (MWCNTs). We coated the CPCMs on the fabric by scraper coating, then evaluated their shape stability, latent heat, thermal conductivity, thermal storage stability and photo-thermal effects. Results show that CPCMs with 10% acid-oxidized MWCNTs introduce only a small phase leakage when heated at 50℃ for 900 s; their latent heat energy reduces by 16.5%, while their thermal conductivity increases by 131.9% compared to pure paraffin. When exposed to sunlight at an ambient temperature of 12.5℃, the cotton fabrics coated with CPCMs record a 12.8℃ higher surface temperature than the pristine fabric, while their heat dissipation is delayed by 120–180 s. The fabric surface temperature increases to twice the ambient temperature during daytime. Overall, these findings indicate that the coated fabric has excellent thermal stability, affirming its potential as photo-thermal functional material.


Author(s):  
Bofeng Shang ◽  
Jinyan Hu ◽  
Xingjian Yu ◽  
Bin Xie ◽  
Ruikang Wu ◽  
...  

Phase Change Materials (PCMs) have been widely investigated as a cooling solution due to their significant latent heat capacity. However, the current PCMs generally suffer a low thermal conductivity, thus hindering the application of PCMs. Composite Phase Change Materials (CPCMs) filling with high thermal conductivity materials have been proposed to solve this issue. Nevertheless, the latent heat of the CPCMs decreases with the mass fraction of fillings, thus leading to a lower allowable working time under safe operating temperature. Therefore, an optimal filling mass fraction of CPCMs is in urgent needed to improve the application of CPCMs. In this study, we developed a one-dimensional conduction heat transfer model of CPCMs to predict the optimal filling mass fraction of CPCMs to realize the maximum allowable working time. The filling mass fraction was introduced into the model and the relationship between the thermal conductivity and latent heat was built. We adopted paraffin as the matrix material and Expanded Graphite (EG) as the thermal conductivity enhancer. The allowable working time of the CPCMs as the function of filling mass fraction was obtained. Based on the principle of the maximum allowable working time, the optimal filling mass fraction was calculated. Comparative experiments were also conducted to validate the accuracy of the prediction model. The parameters which affect the maximum allowable working temperature were also investigated, including input heat flux, safe temperature, and height of CPCMs. The results show that a higher heat flux and height requires a larger filling mass fraction, and it’s opposite for the safe temperature.


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