Bioactive Molecules Coated Silver Oxide Nanoparticle Synthesis from Curcuma zanthorrhiza and HR-LCMS Monitored Validation of Its Photocatalytic Potency Towards Malachite Green Degradation

Author(s):  
K. S. Aiswariya ◽  
Vimala Jose
2017 ◽  
Vol 16 (05n06) ◽  
pp. 1750018 ◽  
Author(s):  
Vithiya Karunagaran ◽  
Kumar Rajendran ◽  
Shampa Sen

Silver oxide nanoparticle can be synthesized by chemical and biological methods. Biological synthesis has emerged as an exciting, ecofriendly approach. However, the process tends to be slow when we consider its industrial applicability. The development of reliable method for rapid synthesis of nanoparticles is one of the significant zones of interests in current nanotechnological research. In this paper, optimization of physiochemical parameters for rapid silver oxide nanoparticle synthesis using Bacillus thuringiensis SSV1 culture supernatant has been elucidated. Spherical-shaped silver oxide nanoparticles with an average particle size of 30[Formula: see text]nm were obtained. The cytotoxic effect of silver oxide nanoparticles was studied against HepG2 and Chang liver cell lines by MTT assay. These nanoparticles showed dose-dependent response on HepG2 (IC[Formula: see text]g/mL) and Chang liver cells (IC[Formula: see text]g/mL).


2020 ◽  
Vol 7 (1) ◽  
pp. 23-39 ◽  
Author(s):  
Kantharaju Kamanna ◽  
Santosh Y. Khatavi

Multi-Component Reactions (MCRs) have emerged as an excellent tool in organic chemistry for the synthesis of various bioactive molecules. Among these, one-pot MCRs are included, in which organic reactants react with domino in a single-step process. This has become an alternative platform for the organic chemists, because of their simple operation, less purification methods, no side product and faster reaction time. One of the important applications of the MCRs can be drawn in carbon- carbon (C-C) and carbon-heteroatom (C-X; X = N, O, S) bond formation, which is extensively used by the organic chemists to generate bioactive or useful material synthesis. Some of the key carbon- carbon bond forming reactions are Grignard, Wittig, Enolate alkylation, Aldol, Claisen condensation, Michael and more organic reactions. Alternatively, carbon-heteroatoms containing C-N, C-O, and C-S bond are also found more important and present in various heterocyclic compounds, which are of biological, pharmaceutical, and material interest. Thus, there is a clear scope for the discovery and development of cleaner reaction, faster reaction rate, atom economy and efficient one-pot synthesis for sustainable production of diverse and structurally complex organic molecules. Reactions that required hours to run completely in a conventional method can now be carried out within minutes. Thus, the application of microwave (MW) radiation in organic synthesis has become more promising considerable amount in resource-friendly and eco-friendly processes. The technique of microwaveassisted organic synthesis (MAOS) has successfully been employed in various material syntheses, such as transition metal-catalyzed cross-coupling, dipolar cycloaddition reaction, biomolecule synthesis, polymer formation, and the nanoparticle synthesis. The application of the microwave-technique in carbon-carbon and carbon-heteroatom bond formations via MCRs with major reported literature examples are discussed in this review.


2018 ◽  
Vol 278 ◽  
pp. 112-120 ◽  
Author(s):  
Ishaq Yusuf Habib ◽  
N.T.R.N. Kumara ◽  
Chee Ming Lim ◽  
Abdul Hanif Mahadi

A Cerium (IV) oxide nanoparticle (nanoceria) is widely used in different applications such as biomedicine and catalysis due to its unique structural, morphological and catalytic properties. In this report, the dispersion of nanoceria in both aqueous and non-aqueous (methanol and ethanol) media were studied. Adsorption-desorption processes were observed upon addition of different classes of surfactants such as citric acid (CA), cetrimonium bromide (CTAB) and diethanolamine (DEA). Stable dispersions were obtained in both aqueous, non-aqueous and electrolyte assisted media with the overall mechanism being hydrolysis, dissolution and adsorption. XRD, FE-SEM, FTIR and DLS have been used in the present study to characterize the nanoceria and to quantitatively analyze their average particle size distributions in a unique electrolyte mixture of (0.1 M NaOH/ 65% HNO3:H2O, 1:1 v/v) which has not been reported previously. The surface charge study was carried out across a wide pH range between 1.4 – 9.6 and the isoelectric points (IEP) with respect to 15 ml H2O and 50 ml H2O dispersed phases occurred at a pH of about 6.5 and 6.7 respectively. The present study could be useful in a wide range of applications including nanoparticle synthesis, stabilization, and adsorption of toxic materials, biomedical and pharmaceutical.


2012 ◽  
Vol 14 (5) ◽  
Author(s):  
Minghui Gui ◽  
Vasile Smuleac ◽  
Lindell E. Ormsbee ◽  
David L. Sedlak ◽  
Dibakar Bhattacharyya

RSC Advances ◽  
2019 ◽  
Vol 9 (67) ◽  
pp. 39381-39393 ◽  
Author(s):  
Jiacheng Yu ◽  
Tongwei Zhang ◽  
Huangtao Xu ◽  
Xiaoli Dong ◽  
Yao Cai ◽  
...  

A novel thermostable ferritin from Pyrococcus yayanosii CH1 directs the synthesis of thermostable magnetoferritins (M-PcFn5000) in one step.


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