scholarly journals Effects of post cure treatment in the glass transformation range on the structure and fire behavior of in situ generated silica/epoxy hybrids

2018 ◽  
Vol 87 (1) ◽  
pp. 156-169 ◽  
Author(s):  
Aurelio Bifulco ◽  
Fabiana Tescione ◽  
Agostino Capasso ◽  
Pierluigi Mazzei ◽  
Alessandro Piccolo ◽  
...  
2009 ◽  
Vol 18 (3) ◽  
pp. 315 ◽  
Author(s):  
J. Kevin Hiers ◽  
Joseph J. O'Brien ◽  
R. J. Mitchell ◽  
John M. Grego ◽  
E. Louise Loudermilk

In ecosystems with frequent surface fire regimes, fire and fuel heterogeneity has been largely overlooked owing to the lack of unburned patches and the difficulty in measuring fire behavior at fine scales (0.1–10 m). The diverse vegetation in these ecosystems varies at these fine scales. This diversity could be driven by the influences of local interactions among patches of understorey vegetation and canopy-supplied fine fuels on fire behavior, yet no method we know of can capture fine-scale fuel and fire measurements such that these relationships could be rigorously tested. We present here an original method for inventorying of fine-scale fuels and in situ measures of fire intensity within longleaf pine forests of the south-eastern USA. Using ground-based LIDAR (Light Detection and Ranging) with traditional fuel inventory approaches, we characterized within-fuel bed variation into discrete patches, termed wildland fuel cells, which had distinct fuel composition, characteristics, and architecture that became spatially independent beyond 0.5 m2. Spatially explicit fire behavior was measured in situ through digital infrared thermography. We found that fire temperatures and residence times varied at similar scales to those observed for wildland fuel cells. The wildland fuels cell concept could seamlessly connect empirical studies with numerical models or cellular automata models of fire behavior, representing a promising means to better predict within-burn heterogeneity and fire effects.


2016 ◽  
Vol 16 (2) ◽  
pp. 403-415 ◽  
Author(s):  
C. Schunk ◽  
B. Ruth ◽  
M. Leuchner ◽  
C. Wastl ◽  
A. Menzel

Abstract. Dead fine fuel (e.g., litter) moisture content is an important parameter for both forest fire and ecological applications as it is related to ignitability, fire behavior and soil respiration. Real-time availability of this value would thus be a great benefit to fire risk management and prevention. However, the comprehensive literature review in this paper shows that there is no easy-to-use method for automated measurements available. This study investigates the applicability of four different sensor types (permittivity and electrical resistance measuring principles) for this measurement. Comparisons were made to manual gravimetric reference measurements carried out almost daily for one fire season and overall agreement was good (highly significant correlations with 0.792 <  =  r <  =  0.947, p  <  0.001). Standard deviations within sensor types were linearly correlated to daily sensor mean values; however, above a certain threshold they became irregular, which may be linked to exceedance of the working ranges. Thus, measurements with irregular standard deviations were considered unusable and relationships between gravimetric and automatic measurements of all individual sensors were compared only for useable periods. A large drift in these relationships became obvious from drought to drought period. This drift may be related to installation effects or settling and decomposition of the litter layer throughout the fire season. Because of the drift and the in situ calibration necessary, it cannot be recommended to use the methods presented here for monitoring purposes and thus operational hazard management. However, they may be interesting for scientific studies when some manual fuel moisture measurements are made anyway. Additionally, a number of potential methodological improvements are suggested.


2009 ◽  
Vol 18 (7) ◽  
pp. 775 ◽  
Author(s):  
François Pimont ◽  
Jean-Luc Dupuy ◽  
Rodman R. Linn ◽  
Sylvain Dupont

The wildfire model FIRETEC simulates the large coherent eddies of the wind-flows induced by the canopy. It has been qualitatively validated in its ability to simulate fire behavior, but there is still a need to validate physical submodels separately. In the present study, the dynamics and turbulence of the flow simulated by FIRETEC are validated in a manner similar to other air-flow models without fire, through comparison with measurements associated with flows within continuous and discontinuous forests captured through in situ and wind-tunnel experiments with neutral thermal stratification. The model is shown to be able to reproduce accurately all essential features of turbulent flow over both forests. Moreover, a short sensitivity study shows that the model is not very sensitive to uncertain parameters such as vegetation drag coefficient. Finally, it is shown in the discontinuous forest case that wind gusts on fuel-breaks can be very strong and significantly higher than in surrounding canopies, even if their directions are more stable. These results and others briefly reviewed in the present paper allow better understanding of wind-flow perturbations induced by fuel-breaks. This new validation added to previous ones confirms the ability of FIRETEC for investigating effects of fuel-break design on fire propagation.


2015 ◽  
Vol 3 (6) ◽  
pp. 3733-3760 ◽  
Author(s):  
C. Schunk ◽  
B. Ruth ◽  
M. Leuchner ◽  
C. Wastl ◽  
A. Menzel

Abstract. Dead fine fuel (e.g. litter) moisture content is an important parameter for both forest fire and ecological applications as it is related to ignitability, fire behavior as well as soil respiration. However, the comprehensive literature review in this paper shows that there is no easy-to-use method for automated measurements available. This study investigates the applicability of four different sensor types (permittivity and electrical resistance measuring principles) for this measurement. Comparisons were made to manual gravimetric reference measurements carried out almost daily for one fire season and overall agreement was good (highly significant correlations with 0.792 &amp;leqq; r &amp;leqq; 0.947). Standard deviations within sensor types were linearly correlated to daily sensor mean values; however, above a certain threshold they became irregular, which may be linked to exceedance of the working ranges. Thus, measurements with irregular standard deviations were considered unusable and calibrations of all individual sensors were compared for useable periods. A large drift in the sensor raw value-litter moisture-relationship became obvious from drought to drought period. This drift may be related to installation effects or settling and decomposition of the litter layer throughout the fire season. Because of the drift and the in situ calibration necessary, it cannot be recommended to use the methods presented here for monitoring purposes. However, they may be interesting for scientific studies when some manual fuel moisture measurements are made anyway. Additionally, a number of potential methodological improvements are suggested.


Author(s):  
P. R. Okamoto

Many ordered intermetallic compounds become amorphous when irradiated at low temperatures with energetic particles. There is still no fundamental understanding of why some compounds but not others are susceptible to amorphization. However, recent studies indicate that a progressive loss of chemical long-range order (LRO) is a necessary, though not a sufficient condition for the crystal-to-glass transformation. To shed further light on the role of chemical disordering, our work has focused on correlating the structural effects of chemical disorder on the shear modulus of a number of LI2, B2, and A-15 type intermetallic compounds under irradiation conditions where some become amorphous and others remain crystalline.The Brillouin scattering technique was used to measure the change in the velocity of sound (Vs) relative to that of the unirradiated state (Vos) in Zr3Al, FeAl, FeTi, NiAl, and Nb3Ir during irradiation at 298 K with 1-MeV Kr+ ions. The corresponding changes in the Bragg-Williams LRO parameter (S/So), and lattice expansion (Δa/ao) were measured by means of electron diffracting during in-situ irradiation with 1-MeV Kr in the ANL high voltage electron microscope.


Atmosphere ◽  
2020 ◽  
Vol 11 (8) ◽  
pp. 796
Author(s):  
Tirtha Banerjee ◽  
Troy Holland ◽  
Kurt Solander ◽  
Marlin Holmes ◽  
Rodman Linn

Wildfire behavior is dictated by the complex interaction of numerous physical phenomena including dynamic ambient and fire-induced winds, heat transfer, aerodynamic drag on the wind by the fuel and combustion. These phenomena create complex feedback effects between the fire and its surroundings. In this study, we aim to study the mechanisms by which buoyant flame dynamics along with vortical motions and instabilities control wildfire propagation. Specifically, this study employs a suite of simulations conducted with the physics-based coupled fire-atmosphere behavior model (FIRETEC). The simulations are initialized with a fire line and the fires are allowed to propagate on a grass bed, where the fuel heights and wind conditions are varied systematically. Flow variables are extracted to identify the characteristics of the alternating counter-rotational vortices, called towers and troughs, that drive convective heat transfer and fire spread. These vortices have previously been observed in wildfires and laboratory fires, and have also been observed to arise spontaneously in FIRETEC due to the fundamental physics incorporated in the model. However, these past observations have been qualitative in nature and no quantitative studies can be found in the literature which connected these coherent structures fundamental to fire behavior with the constitutive flow variables. To that end, a variety of state variables are examined in the context of these coherent structures under various wind profile and grass height conditions. Identification of various correlated signatures and fire-atmosphere feedbacks in simulations provides a hypothesis that can be tested in future observational or experimental efforts, potentially assisting experimental design, and can aid in the interpretation of data from in situ detectors.


Clay Minerals ◽  
2013 ◽  
Vol 48 (3) ◽  
pp. 423-445 ◽  
Author(s):  
J. Cuadros ◽  
B. Afsin ◽  
P. Jadubansa ◽  
M. Ardakani ◽  
C. Ascaso ◽  
...  

AbstractRhyolitic obsidian was reacted with natural waters to study the effect of water chemistry and biological activity on the composition and formation mechanisms of clay. Two sets of experiments (18 months, 6 years) used fresh, hypersaline water (Mg-Na-SO4-Cl- and NaCl-rich) and seawater. The 6-year experiments produced the transformation of obsidian into quartz, apparently by in situ re-crystallization (Cuadros et al., 2012). The most abundant neoformed clay was dioctahedral (typically montmorillonite), indicating chemical control by the glass (where Al > Mg). Altered glass morphology and chemistry in the 18-months experiments indicated in situ transformation to clay. Magnesium-rich (saponite) clay formed under water-chemistry control in the bulk and within biofilms with elevated Mg concentration (Cuadros et al., 2013). The contact between microbial structures and glass was very intimate. Glass transformation into quartz may be due to some characteristic of the obsidian and/or alteration conditions. Such combination needs not to be uncommon in nature and opens new possibilities of quartz origin.


2012 ◽  
Vol 29 (3) ◽  
pp. 309-315 ◽  
Author(s):  
Caroline M. Kiefer ◽  
Craig B. Clements ◽  
Brian E. Potter

Abstract Direct measurements of wildland fire plume properties are rare because of difficult access to regions near the fire front and plume. Moisture released from combustion, in addition to added heat, can enhance buoyancy and convection, influencing fire behavior. In this study, a mini unmanned aircraft system (miniUAS) was used to obtain in situ measurements of temperature and relative humidity during a prescribed fire. The miniUAS was successfully maneuvered through the plume and its associated turbulence and provided observations of temperature and humidity profiles from near the centerline of the plume. Within the plume, the water vapor mixing ratio increased by 0.5–3.5 g kg−1 above ambient and was caused by the combustion of fuels. Potential temperature perturbations were on the order of 2–5 K. These results indicate that significant moisture and temperature enhancement can occur and may potentially modify convection dynamics of fire plumes.


1984 ◽  
Vol 75 ◽  
pp. 743-759 ◽  
Author(s):  
Kerry T. Nock

ABSTRACTA mission to rendezvous with the rings of Saturn is studied with regard to science rationale and instrumentation and engineering feasibility and design. Future detailedin situexploration of the rings of Saturn will require spacecraft systems with enormous propulsive capability. NASA is currently studying the critical technologies for just such a system, called Nuclear Electric Propulsion (NEP). Electric propulsion is the only technology which can effectively provide the required total impulse for this demanding mission. Furthermore, the power source must be nuclear because the solar energy reaching Saturn is only 1% of that at the Earth. An important aspect of this mission is the ability of the low thrust propulsion system to continuously boost the spacecraft above the ring plane as it spirals in toward Saturn, thus enabling scientific measurements of ring particles from only a few kilometers.


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