Synthesis and characterization of phosphorus-based flame retardant containing rigid polyurethane foam

Author(s):  
Esra Çalışkan ◽  
Tuba Çakır Çanak ◽  
Müfide Karahasanoğlu ◽  
I. Ersin Serhatlı
2019 ◽  
Vol 803 ◽  
pp. 346-350
Author(s):  
Jessalyn C. Grumo ◽  
Lady Jaharah Y. Jabber ◽  
Arnold A. Lubguban ◽  
Rey Y. Capangpangan ◽  
Arnold C. Alguno

We report on the rigid polyurethane foam (RPUF) with varying amount of blowing agent. The effects of blowing agent in the formation of polyurethane will be characterized using scanning electron microscopy (SEM) and fourier transform infrared (FTIR) spectroscopy. SEM images revealed that varying the amount of blowing agent will significantly change the surface morphology of the resulting RPUF. The average cell size of the RPUF increases with increasing amount of blowing agent. Moreover, FTIR results revealed the presence of functional group related to formation of urethane bonds such as N-H, C=O, C=N and C-O-C stretching suggesting that polyurethane foam was successfully synthesized. This simple and straightforward process of RPUF using water as blowing agent will be economical.


2018 ◽  
Vol 76 (7) ◽  
pp. 3753-3768 ◽  
Author(s):  
Rong Yang ◽  
Bo Wang ◽  
Liang Xu ◽  
Caixia Zhao ◽  
Xin Zhang ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 2756-2766
Author(s):  
Yi Zhang ◽  
Weiwei Yang

In this study, a highly effective flame retardant agent, called polybicyclopentaerythritol phosphate-O-4-imino-p-phenylmethane-4-imino-2-chloro-1,3,5-s-triazine (PEDMCD), has been prepared through a direct polycondensation reaction.


2018 ◽  
Vol 6 (2) ◽  
pp. 025312 ◽  
Author(s):  
Sherif M A S Keshk ◽  
Adel A El-Zahhar ◽  
Abdullah G Al-Sehemi ◽  
Ahmad Irfan ◽  
Samir Bondock

2014 ◽  
Vol 1030-1032 ◽  
pp. 241-245 ◽  
Author(s):  
Yan Wei Li

In this paper, the effect of C3H6N6modified by imidazolium based Ionic Liquid 1-butyl-methylimidazolium hexafluorophosphate ([BMIM]PF6) on polyurethane rigid foam flame retardant properties was conducted.The results show that the flame retardant properties of C3H6N6 modified with Ionic Liquid significantly increased and the LOI increased form 22.3 to 24.5. In the modification process, the ionic liquid mass have a very noticeable effect to the flame retardant property and when [BMIM]PF6 and C3H6N6 in quality was 4:6, Fire-retardant effect was best.Compared with the prior to the modification, C3H6N6 modified can increase effective Flame resistance of materials, horizontal burning speed from 67.6mm/min down to 33.4mm/min.Thermal degradation data show that C3H6N6 modified could improve initial decomposition temperature and reminder yield of rigid polyurethane foam,and then heat release reduced, the decomposition controlled,thermal stability increased.


2012 ◽  
Vol 012 (9) ◽  
pp. 1042-1046 ◽  
Author(s):  
De-ming Guo ◽  
Xin-ke Jing ◽  
Jia-ning Wu ◽  
Ying-qing Ou ◽  
Fei-yu Zhai ◽  
...  

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