Adsorption Isotherms, Thermodynamics, and Kinetic Modeling of Methylene Blue onto Novel Carbonaceous Adsorbent Derived from Bitter Orange Peels

2021 ◽  
Vol 232 (4) ◽  
Author(s):  
Ayse Gunay Gurer ◽  
Kemal Aktas ◽  
Merve Ozkaleli Akcetin ◽  
Ayca Erdem Unsar ◽  
Meltem Asilturk
Keyword(s):  
Methylene Blue ◽  
Kinetic Modeling ◽  
Adsorption Isotherms ◽  
Bitter Orange ◽  
Orange Peels ◽  
Carbonaceous Adsorbent

Adsorption isotherms and kinetic modeling of methylene blue dye onto a carbonaceous hydrochar adsorbent derived from coffee husk waste

2020 ◽  
Vol 725 ◽  
pp. 138325 ◽  
Author(s):  
Thi Hien Tran ◽  
Anh Hoang Le ◽  
Thien Huu Pham ◽  
Dinh Thanh Nguyen ◽  
Soon Woong Chang ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Kinetic Modeling ◽  
Adsorption Isotherms ◽  
Blue Dye ◽  
Methylene Blue Dye ◽  
Coffee Husk

scholarly journals Bioremediation of organic dyes using combination of plants ash

2019 ◽  
Vol 7 (2) ◽  
pp. 240-246
Author(s):  
Kaur Harpreet ◽  
Kaur Harpreet ◽  
Vandana Kamboj ◽  
Vandana Kamboj
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Methyl Orange ◽  
Crystal Violet ◽  
Congo Red ◽  
Organic Dyes ◽  
Low Cost ◽  
Sem Image ◽  
Orange Peels

Water is the most crucial thing to mankind and so its contamination by various agencies is posing a threat to the natural balance. So, in the present work, the efficiency of various adsorbents derived from plant waste, to remove different dyes from aqueous solution was evaluated. Parameters for study were contact time, concentration and pH. Various combinations of plant ashes were used for the study. It was found that adsorbent prepared from the combination of orange peels, pomegranate and banana peels ashes, exhibited good adsorption capacity for methylene blue, congo red and crystal violet. All these dyes were completely removed from the aqueous solution while methyl orange was not removed. Congo red was removed completely within 40 min of contact with the adsorbent while methyl orange took 3 hrs to be removed to the extent of 48% only. The adsorption coefficient of congo red was found to be 2.33 while value for methylene blue and crystal violet was 1 and 1.66 respectively. The characterization of adsorbent was done by Scanning Electron Microscopy and IR spectroscopy. SEM image revealed the surface of adsorbent to be made of differential pores. From the results it became evident that the low-cost adsorbent could be used as a replacement for costly traditional methods of removing colorants from water.

Adsorption of Methylene Blue and Congo Red on Bentonite Modified with CaCO3

2017 ◽  
Vol 727 ◽  
pp. 853-858 ◽  
Author(s):  
Han Bing Zhang ◽  
Ning Hua Chen ◽  
Zhang Fa Tong ◽  
Qi Feng Liu ◽  
Yan Kui Tang ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Adsorption Isotherms ◽  
Adsorption Kinetics ◽  
Congo Red ◽  
Phosphate Adsorption ◽  
Adsorption Effect ◽  
Adsorption Performance ◽  
Initial Ph ◽  
Removal Efficiencies ◽  
Ph Range

Both bentonite and CaCO3 are cheap and abundant superior regional non-metal ores in Guangxi province, so it is very meaningful to jointly exploit bentonite and CaCO3 for real applications. In this study, bentonite modified with CaCO3 (CCB) was prepared and its adsorption performance of Congo Red (CR) and Methylene Blue (MB) was evaluated by investigating the adsorption influencing effects of initial pH, SDBS and phosphate. Adsorption isotherms and adsorption kinetics models were also fitted to analysis the corresponding kinetic characteristics of CCB. The results show that CCB exhibited superior adsorption performance with the respective > 90% MB and CR removal within the initial pH range 2 ~ 10. To a certain extent, MB removal efficiencies by CCB can be increased with the addition of SDBS. On the other hand, CR adsorption on CCB was inhibited slightly in presence of SDBS. But as a whole, removal efficiencies of MB and CR by CCB were kept constant when SDBS co-existed. MB and CR adsorption on CCB decreased to some extent because of competitive adsorption effect when phosphate co-existed. It also demonstrated that CCB can remove phosphate at the same time with dyes. Adsorption models including adsorption isotherms adsorption kinetics indicated that MB and CR adsorption on CCB was a monolayer process, and the adsorption rate depended on both adsorbent and adsorbate. In summary, CCB is a promising adsorbent for dyes removal with many advantages such as simple preparation technology, excellent adsorption performance for anionic and cationic dyes, broad fitting pH range and SDBS resistance. Besides, it can remove dyes together with phosphate at the same time. Therefore, this study is very useful for the dyeing wastewater treatment and exploiting the resources of bentonite and CaCO3.

Removal of Methylene Blue from Aqueous Solution by Powdered Expanded Graphite: Adsorption Isotherms and Thermodynamics

2012 ◽  
Vol 424-425 ◽  
pp. 1313-1317 ◽  
Author(s):  
Shui Cheng Tan ◽  
Peng Hui Shi ◽  
Rui Jing Su ◽  
Min Cong Zhu
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Adsorption Isotherms ◽  
Dye Adsorption ◽  
Expanded Graphite ◽  
Solution Ph ◽  
Adsorption Behaviors ◽  
Different Temperatures ◽  
Isotherms And Thermodynamics ◽  
Langmuir And Freundlich Equations

The powdered expanded graphite (EG) was used as a porous adsorbent for the removal of the cationic dye, methylene blue (MB), from aqueous solution. The dye adsorption experiments were carried out with the bath procedure. Adsorption isotherms at different temperatures were determined and modeled with Langmuir and Freundlich equations. Thermodynamic parameters were calculated and correlated with the adsorption behaviors. The effects of solution pH on the adsorption were also studied.

scholarly journals Biosorption of Colour, Copper and Zinc in Textile Wastewater using Carbonized Orange Peels

2021 ◽  
Vol 6 (2) ◽  
Author(s):  
P. H. Kumaraiah
Keyword(s):  
Adsorption Isotherms ◽  
Contact Time ◽  
Textile Wastewater ◽  
Second Order ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Copper Adsorption ◽  
Orange Peels ◽  
Copper And Zinc ◽  
Pseudo Second Order

Recently, low-cost adsorbents from sustainable sources are required for the remediation of textile wastewater. Carbonized Orange Peels (COPs) was utilized in remediating colour, Zinc and Copper from textile wastewater. The initial and final pH, colour and trace metals’ composition of the wastewater used were determined for the adsorption processes. Batch adsorption experiment was carried out on COPs and textile wastewater’s mixture to find effects of COP’s dosage, agitation, pH and contact time on the colour, Zinc and Copper’s removal from the wastewater. The adsorption isotherms and kinetic studies were conducted using Langmuir, Freundlich, Pseudo-first-order and Pseudo-second-order models. Findings established that the optimum removal of colour, Zinc and Copper respectively occurred at an adsorbent dosage of 2.5, 0.5 and 3.0 g/100ml, pH of 10, 4 and 2, rotating speed of 100, 250 and 250 rpm, contact time of 40, 60, and 40 mins. The adsorption isotherms revealed only copper adsorption as optimum and well fitted Langmuir isotherm. Pseudo-second-order kinetic model best suited adsorption data of the colour and metal ions with high correlation coefficient (R2) exceeding 0.95. Conclusively, COPs is effective in remediating the colour, copper and zinc from the wastewater, thus, recommended as suitable adsorbent for treatment of textile wastewater

scholarly journals Removal of Zinc by Bitter Orange Peels Activated Carbon and Commercially Activated Carbon, a Comparison Study.

2017 ◽  
Vol 5 (1) ◽  
pp. 120-131
Author(s):  
Laith Hamdan Hawal
Keyword(s):  
Activated Carbon ◽  
Removal Efficiency ◽  
Flow Rate ◽  
Treatment Time ◽  
Activated Carbons ◽  
Bitter Orange ◽  
Orange Peels ◽  
Effects Of Ph ◽  
Zinc Concentrations ◽  
Adsorbent Materials

 In this study, a comparison between using activated carbon prepared from bitter orange peels (BOAC) and a common commercially activated carbon (CAC), which is brought from the market, as adsorbent materials. This study was designed to find out which of these two activated carbons is more effective in the removal of zinc from waste water. This work examines the use of bitter orange peels, which are available as waste in local markets and in household garbage as an alternative presage to prepare an activated carbon by using (H2SO4) as activating reagent. The effects of pH, initial zinc concentrations, treatment time, adsorbent media bed height and the flow rate of simulated synthetic aqueous solution (SSAS) on the removal efficiency of zinc were all studied under 24oC The results indicated that the removal efficiency of zinc increases with decreasing in pH of SSAS. When the initial concentration of zinc increases in SSAS, the removal efficiency of zinc was decreased. The study proved that the increasing of contact time leads to greater removal efficiency. When the height of adsorbent media in fixed column increases, the removal efficiency was increased. The experiments also showed that the removal efficiency of zinc from the SSAS increased, when the flow rate decreased. It could be concluded from this work that (BOAC) is better than (CAC) as an adsorbent materials in the removal of zinc; with a removal efficiency of (90%, 86%), respectively

scholarly journals Adsorption Isotherms Study of Methylene Blue Dye on Membranes from Electrospun Nanofibers

2018 ◽  
Vol 34 (6) ◽  
pp. 2884-2894 ◽  
Author(s):  
Wedad J. Fendi ◽  
Juman A. Naser
Keyword(s):  
Methylene Blue ◽  
Adsorption Isotherms ◽  
Electrospun Nanofibers ◽  
Formaldehyde Resin ◽  
Blue Dye ◽  
Methylene Blue Dye ◽  
Electrospinning Method ◽  
Ftir Technique ◽  
Nanofiber Membranes ◽  
Langmuir And Freundlich Models

P-cresol formaldehyde resin was prepared and characterized by FTIR technique, then composited with polystyrene in order to produce electrospun nanofiber membrane by the electrospinning method. Zinc oxide nanoparticles was prepared and characterized by FTIR, XRD SEM and EDX techniques in order to modified first membrane. Both prepared nanofiber membranes characterized by SEM and EDX techniques and used as adsorbents to adsorb methylene blue dye from their aqueous solutions. The factors of adsorption were investigated, contact time, initial concentration, adsorbent dosage, ionic strength and temperature. The adsorption isotherms described by Langmuir and Freundlich models. So, thermodynamic functions ∆G, ∆H and ∆S of adsorption were estimated.

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