Formation characteristics of carbonaceous and nitrogenous disinfection by-products depending on residual organic compounds by CGS and DAF

2018 ◽  
Vol 26 (33) ◽  
pp. 34008-34017 ◽  
Author(s):  
Minsoo Maeng ◽  
Nirmal Kumar Shahi ◽  
Gwyam Shin ◽  
Heejong Son ◽  
Dongheui Kwak ◽  
...  
1975 ◽  
Vol 28 (9) ◽  
pp. 1981 ◽  
Author(s):  
DHT Fong ◽  
CL Bodkin ◽  
MA Long ◽  
JL Garnett

The stereochemistry of the tritiation of L-chiro-inositol, myo-inositol and hexa-O-methyl-L-chiro-inositol by self-radiation induced exchange with tritiated water of high specific activity has been investigated. Predominance of configurational retention was found to accompany tritium labelling in the two inositols, while substantial configurational inversion occurred in the hexa-O-methyl derivative. Tritiation occurred predominantly at C 1 in L-chiro-inositol, with slight inversion at this position alone accompanying the labelling. Comparison with Wilzbach T2 gas exposure results indicates the HTO method yields less by-products, myo-inositol having a radiochemical purity of 97%.


2010 ◽  
Vol 13 (5) ◽  
pp. 494-501 ◽  
Author(s):  
Cédric Gennequin ◽  
Serge Kouassi ◽  
Lucette Tidahy ◽  
Renaud Cousin ◽  
Jean-François Lamonier ◽  
...  

1992 ◽  
Vol 25 (2) ◽  
pp. 323-333 ◽  
Author(s):  
A. Bruchet ◽  
E. Costentin ◽  
M. F. Legrand ◽  
J. Mallevialle

The objective of the study was to determine the influence of chlorination by-products of naturally occuring nitrogenous organic compounds on tastes and odors in drinking waters. Amino acids, peptides and amino sugars have been chlorinated under various chlorine/nitrogen ratios. Six natural amino acids were shown to induce tastes and odors at concentrations in the range 10-20 µg/l after chlorination. A multicomponent mixture containing 2.5 µg/l each of these 6 amino acids consistently induced detectable odors after a contact time with chlorine of 2 hours. Investigation of the by-products indicated that the odors generated were systematically linked to the aliphatic aldehydes formed. The peptides investigated revealed varying degrees of odor formation potential, while the amino sugars did not impart any odor. Chlorinous odors occasionally detected during these experiments were thought to arise from the organic chloramines or other oxidation by-products.


Natural products are normally biodegradable, and problems arise mainly when excessive amounts accumulate as wastes. Recent research has suggested some new ways of recycling the organic materials in domestic refuse and sewage, in the organic by-products of industry and in agricultural wastes. If processes can be made economical, these materials could provide sources of energy and of animal foodstuffs, and environmental pollution could be decreased. The chemical residues from herbicides and pesticides present potential biological hazards to the operatives and to the environment. Many chemicals used in industry would be hazardous if allowed to remain in industrial effluents. Some of these materials can be rendered innocuous by microbial action, and it may be possible to develop strains with improved metabolic activities enabling them to deal more effectively with novel chemical compounds. Methods of constructing strains and the use of their enzymes for degrading synthetic chemicals are discussed.


2013 ◽  
Vol 69 (1) ◽  
pp. 202-207 ◽  
Author(s):  
Dimitris P. Zagklis ◽  
Christakis A. Paraskeva

The aim of the current study was the exploitation of agro-industrial wastes or by-products such as olive mill wastewater (OMW) and defective wines. A cost-effective system for their maximum exploitation is suggested, using a combined process of membrane filtration and other physicochemical processes. Wastewaters are first treated in a membrane system (prefiltration, ultrafiltration, nanofiltration, and reverse osmosis) where pure water and other organic fractions (by-products) are obtained. Organic fractions, called hereafter byproducts and not wastes, are further treated for the separation of organic compounds and isolation of high added value products. Experiments were performed with OMW and defective wines as characteristic agro-industrial wastewaters. Profit from the exploitation of agro-industrial wastewaters can readily help the depreciation of the indeed high cost process of membrane filtration. The simple phenolic fraction of the OMW was successfully isolated from the rest of the waste, and problems occurring during winemaking, such as high volatile acidity and odours, were tackled.


2014 ◽  
Vol 68 (9) ◽  
Author(s):  
Asier Aranzabal ◽  
Beñat Pereda-Ayo ◽  
M. González-Marcos ◽  
José González-Marcos ◽  
Rubén López-Fonseca ◽  
...  

AbstractChlorine-containing organic compounds (Cl-VOC) require special attention due to their distinct toxicity, high stability and persistence in the environment. Removal of Cl-VOC by catalytic oxidation over a wide variety of catalysts has been presented in literature. This paper reviews the state of the art in this subject, including different model compounds, nature of catalysts, and oxidation activity. Catalyst selectivity (CO2 vs. CO and HCl vs. Cl2), by-products formation and the causes of deactivation are also analyzed as the most important factors in the catalyst selection for practical applications.


2000 ◽  
Vol 122 (04) ◽  
pp. 64-66

This article describes features of an automated, closed sampling system that cuts waste and improves safety at a plastics factory. In order to monitor product composition and quality, tests must be performed on material entering and leaving the fluid-bed vessels. This means that samples must be drawn at eight locations, two in each processing stream. Morris, Illinois, complex of Equistar Chemicals LP, considered alternatives that could operate without an employee on the spot. Although sampling normally would be initiated by the computers that run the production process, a pushbutton override was installed at each location to allow on-demand sampling, which is helpful in problem-solving or gauging the progress of product changeover. Samples are collected and delivered by hand to the laboratory. At one time, hydrocarbons, or volatile organic compounds, which are by-products of the manufacturing process, would be present when samples were collected. That potential problem is avoided because the Bristol sampler body provides a built-in purging port intended for introducing an inert gas or fluid to flush clinging materials out of the spool. Automating has given the company more confidence that its samples and their data are representative. Because the samplers are completely enclosed, the finer particles remain as part of the sample.


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