Infrared spectroscopy as a tool to evaluate pine woods treated by in situ polymerization with three different precursors and decayed by a white-rot fungus

Author(s):  
Andrey Pereira Acosta ◽  
Rafael de Avila Delucis ◽  
Cecília de Oliveira Voloski ◽  
Rafael Beltrame ◽  
Nidria Dias Cruz ◽  
...  
2003 ◽  
Vol 57 (5) ◽  
pp. 514-517 ◽  
Author(s):  
Christopher H. Vane

Abstract diffuse reflectance infrared spectroscopy (DRIFT) and elemental analysis were employed to monitor biodegradation of black gum wood ( Nyssa sylvatica) during growth of the shiitake mushroom ( Lentinula edodes). Black gum was decayed for up to 4.3 years by L. edodes, during which time it was sampled at 19, 31, and 52 months. Biodegraded woods displayed increased % O (w/w) and decreased % C (w/w) relative to the undecayed control. The DRIFT spectra of decayed black gum showed a decrease in relative intensity of absorption bands at 1735 cm−1 assigned to carboxyl functional groups from xylans and an increase in the absorption band at 1640 cm−1 assigned to conjugated carbonyl groups originating from lignin. Xylan decay was rapid initially but slowed after 19 months; however, oxidative decay of the lignin side chains occurred throughout the 52-month decay period. Overall elemental and DRIFT data show that both polysaccharides and lignin were decayed during cultivation of the edible white-rot fungus.


RSC Advances ◽  
2017 ◽  
Vol 7 (21) ◽  
pp. 12639-12649 ◽  
Author(s):  
Flávia Viana Avelar Dutra ◽  
Bruna Carneiro Pires ◽  
Tienne Aparecida Nascimento ◽  
Valdir Mano ◽  
Keyller Bastos Borges

Polyaniline (PAni), cellulose fiber (CF) and a PAni–CF composite, which were characterized by infrared spectroscopy, scanning electron microscopy and thermogravimetry, were investigated in adsorption studies of meloxicam (MLX) from aqueous media.


Holzforschung ◽  
2004 ◽  
Vol 58 (3) ◽  
pp. 311-315 ◽  
Author(s):  
H.-L. Lee ◽  
G.C. Chen ◽  
R.M. Rowell

Abstract Resistance of wood reacted in situ with phosphorus pentoxide-amine to the brown-rot fungus Gloeophyllum trabeum and white-rot fungus Trametes versicolor was examined. Wood reacted with either octyl, tribromo, or nitro derivatives were more resistant to both fungi. Threshold retention values of phosphoramide-reacted wood to white-rot fungus T. versicolor ranged from 2.9 to 13.3 mmol, while these for brown-rot fungus G. trabeum ranged from 8.1 to 19.2 mmol. Wood reacted with phosphoramide tested to be more resistant to white-rot than brown-rot attack.


2020 ◽  
Vol 7 (6) ◽  
pp. 246-274
Author(s):  
Ayodele A Otaiku ◽  
AI Alhaji

A major limitation of the white-rot fungus is its sensitivity during biodegradation of mixed matrix explosive pollutants and the scale of Kachia military shooting since 1967, Nigeria. The amplified 16S rRNA gene of each microbial isolate was processed for sequencing and characterization with Gene Bank database. Fungal species heavy metal reduction in increasing order of Aspergillus niger > Trametes versicolor > Rhizopus spp > Phanorochate chrysoporium > Penicillium spp were identified. The total explosive contents shows a significant difference for all locations in both dry and wet seasons (P<0.05) using Anova test. Microbial fungi consortium (MFC) bioremediate heavy metal significantly at 61.7% relative to isolated fungi species because of the lateral gene transfer/co-metabolism, where Trametes versicolor and Aspergillus niger act as gene mediators. MFC growth in 1% mineral salt medium munitions was significance than fungal species isolate. Deploying Myco Bio-augmentation / Phytoremediation/Biosimulation (Myco B-P-B) techniques to optimize the RDX and HMX characterized by a higher Nitrogen/Carbon ratio since fungi lack the beta-glucuronidase (GUS) gene to utilize carbon source directly. Pollutants bio-stimulation will enhances co-metabolism by MFC. Plant detoxification capabilities can be improved using fungi genes laccases and cytochrome P450 monooxygenase expressed effectively in plants using protoplast fusion


2019 ◽  
Vol 7 (19) ◽  
pp. 16757-16764 ◽  
Author(s):  
Gijs van Erven ◽  
Roelant Hilgers ◽  
Pieter de Waard ◽  
Erik-Jan Gladbeek ◽  
Willem J. H. van Berkel ◽  
...  

Author(s):  
Ezequiel Gallio ◽  
Paula Zanatta ◽  
Débora Duarte Ribes ◽  
Marília Lazarotto ◽  
Darci Alberto Gatto ◽  
...  

2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Giovanna Di Pasquale ◽  
Antonino Pollicino

Montmorillonite/polystyrene nanocomposites were prepared by in situ photopolymerization of styrene in the presence of 2% by weight of clay organomodified by two new imidazolium surfactants having in their structure an alkyl chain with 20 or 22 carbon atoms, respectively. Thermogravimetry showed that the new surfactants are more thermally stable than conventional alkylammonium surfactants. The properties of the obtained nanocomposites were compared with those of pristine polystyrene, with those of a microcomposite obtained by in situ polymerization of styrene in the presence of unmodified clay, and with those of a nanocomposite obtained starting from an organomodified clay with a short alkyl chain (12 carbon atoms) imidazolium surfactant. XRD, TEM, and rheological analysis showed that the clay/PS nanocomposites have a mixture of intercalated and partially exfoliated structure layers, where the higher the surfactant alkyl chain length, the higher the exfoliation degree. Kinetics curve of accelerated UV aging, obtained by following through infrared spectroscopy the increase of carbonyl functions during aging, showed that the rate of photooxidation of clay containing samples is higher than neat polystyrene. The rate is higher as a function of the degree of dispersion of the filler in the polymer matrix.


2012 ◽  
Vol 3 (1) ◽  
pp. 20-21
Author(s):  
A.Sangeetha A.Sangeetha ◽  
◽  
K.Thanigai K.Thanigai ◽  
Narasimhamurthy Narasimhamurthy ◽  
S.K.Nath S.K.Nath

2020 ◽  
Vol 93 (9) ◽  
pp. 289-292
Author(s):  
Yumi SHIMIZU ◽  
Shuma SATHO ◽  
Taro NAKAJIMA ◽  
Hiroaki KOUZAI ◽  
Kiminori SHIMIZU

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