scholarly journals Correction to: Log-based rock compressibility estimation for Asmari carbonate formation

Author(s):  
Rahman Ashena ◽  
Peter Behrenbruch ◽  
Ali Ghalambor
2020 ◽  
Vol 10 (7) ◽  
pp. 2771-2783
Author(s):  
Rahman Ashena ◽  
Peter Behrenbruch ◽  
Ali Ghalambor

Author(s):  
Michael Nolan

The conversion of CO<sub>2</sub> to fuels is of significant importance in enabling the production of sustainable fuels, contributing to alleviating greenhouse gas emissions. While there are a number of key steps required to convert CO<sub>2</sub>, the initial step of adsorption and activation by the catalyst is critical. Well-known metal oxides such as oxidised TiO<sub>2</sub> or CeO<sub>2</sub> are unable to promote this step. In addressing this difficult problem, recent experimental work shows the potential for bismuth-containing materials to activate and convert CO<sub>2</sub>, but the origin of this activity is not yet clear. Additionally, nanostructures can show enhanced activity towards CO<sub>2</sub>. In this paper we present density functional theory (DFT) simulations of CO<sub>2</sub> activation on heterostructured materials composed of extended rutile and anatase TiO<sub>2</sub> surfaces modified with nanoclusters with Bi<sub>2</sub>O<sub>3</sub> stoichiometry. These heterostructures show low coordinated Bi sites in the nanoclusters and a valence band edge that is dominated by Bi-O states. These two factors mean that supported Bi<sub>2</sub>O<sub>3</sub> nanoclusters are able to adsorb and activate CO<sub>2</sub>. Computed adsorption energies lie in the range of -0.54 eV to -1.01 eV. In these strong adsorption modes, CO<sub>2</sub> is activated, in which the molecule bends giving O-C-O angles of 126 - 130<sup>o</sup> and elongation of C-O distances up to 1.28 Å, with no carbonate formation. The electronic properties show a strong CO<sub>2</sub>-Bi-oxygen interaction that drives the interaction of CO<sub>2</sub> to induce the structural distortions. Bi<sub>2</sub>O<sub>3</sub>-TiO<sub>2</sub> heterostructures can be reduced to form Bi<sup>2+</sup> and Ti<sup>3+</sup> species. The interaction of CO<sub>2</sub> with this electron-rich, reduced system can produce CO directly, reoxidising the heterostructure or form an activated carboxyl species (CO<sub>2</sub><sup>-</sup>) through electron transfer from the heterostructure to CO<sub>2</sub>. These results highlight that a semiconducting metal oxide modified with suitable metal oxide nanoclusters can activate CO<sub>2</sub>, thus overcoming the difficulties associated with the difficult first step in CO<sub>2</sub> conversion.


Author(s):  
A. Chaterine

This study accommodates subsurface uncertainties analysis and quantifies the effects on surface production volume to propose the optimal future field development. The problem of well productivity is sometimes only viewed from the surface components themselves, where in fact the subsurface component often has a significant effect on these production figures. In order to track the relationship between surface and subsurface, a model that integrates both must be created. The methods covered integrated asset modeling, probability forecasting, uncertainty quantification, sensitivity analysis, and optimization forecast. Subsurface uncertainties examined were : reservoir closure, regional segmentation, fluid contact, and SCAL properties. As the Integrated Asset Modeling is successfully conducted and a matched model is obtained for the gas-producing carbonate reservoir, highlights of the method are the following: 1) Up to ± 75% uncertainty range of reservoir parameters yields various production forecasting scenario using BHP control with the best case obtained is 335 BSCF of gas production and 254.4 MSTB of oil production, 2) SCAL properties and pseudo-faults are the most sensitive subsurface uncertainty that gives major impact to the production scheme, 3) EOS modeling and rock compressibility modeling must be evaluated seriously as those contribute significantly to condensate production and the field’s revenue, and 4) a proposed optimum production scenario for future development of the field with 151.6 BSCF gas and 414.4 MSTB oil that yields a total NPV of 218.7 MMUSD. The approach and methods implemented has been proven to result in more accurate production forecast and reduce the project cost as the effect of uncertainty reduction.


2020 ◽  
Author(s):  
Carolyn D. Bland ◽  
◽  
Timothy M. Gallagher ◽  
Daniel O. Breecker

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 4097
Author(s):  
Wooyong Seong ◽  
Hyungwoo Hahm ◽  
Seyong Kim ◽  
Jongwoo Park ◽  
Khalil A. Abboud ◽  
...  

Bimetallic bis-urea functionalized salen-aluminum catalysts have been developed for cyclic carbonate synthesis from epoxides and CO2. The urea moiety provides a bimetallic scaffold through hydrogen bonding, which expedites the cyclic carbonate formation reaction under mild reaction conditions. The turnover frequency (TOF) of the bis-urea salen Al catalyst is three times higher than that of a μ-oxo-bridged catalyst, and 13 times higher than that of a monomeric salen aluminum catalyst. The bimetallic reaction pathway is suggested based on urea additive studies and kinetic studies. Additionally, the X-ray crystal structure of a bis-urea salen Ni complex supports the self-assembly of the bis-urea salen metal complex through hydrogen bonding.


2014 ◽  
Vol 78 (6) ◽  
pp. 1473-1477
Author(s):  
Jan Přikryl ◽  
Andri Stefánsson

The interaction of CO2-rich water with olivine was studied using geochemical reaction modelling in order to gain insight into the effects of temperature, acid supply (CO2) and extent of reaction on the secondary mineralogy, water chemistry and mass transfer. Olivine (Fo93) was dissolved at 150 and 250ºC and pCO2 of 2 and 20 bar in a closed system and an open system with secondary minerals allowed to precipitate. The progressive water–rock interaction resulted in increased solution pH, with gradual carbonate formation starting at pH 5 and various Mg-OH and Mg-Si minerals becoming dominant at pH>8. The major factor determining olivine alteration is the pH of the water. In turn, the pH value is determined by acid supply, reaction progress and temperature.


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