Synthesis of a zeolitic imidazolate hybrid nanocomposite and its effects on the physical property changes in the cured epoxy compositions

Author(s):  
Jeong Hoon Park ◽  
Hye Jin Kim ◽  
Tae Hee Kim ◽  
Hyeon-Gook Kim ◽  
Bongkuk Seo ◽  
...  
2021 ◽  
Vol 8 ◽  
Author(s):  
Chen Xupeng ◽  
Sun Zhuowen ◽  
Pang Jianyong

The main purpose of this study is to determine the metakaolin (MK) impacts on the concrete durability when the concrete is subjected to joint corrosion of SO42−,Mg2+ and, Cl−. Four groups of concrete test samples, which contained different MK contents, were designed and tested in order to see their physical property changes and macro-morphology differences during the cyclic corrosion process. And a series of approaches, including XRD, FTIR, SEM, and EDS, were applied to study the concrete phase composition changes and the micro-morphology features of all groups. According to the test results, when reaching 20 cycles, the concrete sample with 10% MK showed the best concrete physical properties; when reaching 120 cycles, the concrete with 5% MK content showed the best durability, produced similar amount of corrosion products to ordinary concrete, and presented relatively compacted micro-structure and small internal porosity. Mg2+ actually has a great impact on metakaolin. The corrosion product quantity increased significantly when MK admixture reached 15%. Due to the great number of produced M-S-H, the corrosive ions damaged the concrete for a second time, leading to serious aggregate peeling-off, powder surface of test samples, and porous micro-structure.


2019 ◽  
Vol 9 (9) ◽  
pp. 1740 ◽  
Author(s):  
Jiang ◽  
Oh ◽  
Kim ◽  
He ◽  
Oh

Leakage in below-grade concrete structures are repaired using various types of grout-injection materials, but the selection of optimal material types with a consideration of the environmental degradation factors are not conducted. Different degradation factors can act on the waterproofing membranes or grout-injection materials simultaneously. Especially in the early stages of installation, the injected grout materials in the cracks for leakage repair or for reforming damaged waterproofing layers are subject to complex forms of degradation factors. In such cases, physical property changes to the materials can reduce the waterproofing performance of the grout-injection materials. In this study, a technical evaluation regime is proposed for selecting the optimal repair material to be used in underground concrete structure leakage cracks. In this study, six environmental degradation factors (thermal stress, chemical corrosion, erosion due to ground water flow, hydrostatic pressure, substrate movement, and humidity on concrete surface) are identified. Corresponding evaluation methods based on the ISO TS 16774 test method series were used for each factor to assess the performance evaluation of four different types of grout-injection materials (acrylic resin, epoxy resin, polyurethane foam, and synthetic polymerized rubber gel). Based on the test results, a new comprehensive evaluation regime is presented that allows a quantitative performance comparison between each type of grout-injection material.


2003 ◽  
Vol 802 ◽  
Author(s):  
B. W. Chung ◽  
S. R. Thompson ◽  
C. H. Woods ◽  
D. J. Hopkins ◽  
W. H. Gourdin ◽  
...  

Plutonium, because of its radioactive nature, ages from the “inside out” by means of self-irradiation damage and thus produces Frankel-type defects (vacancies and self-interstitial atoms) and defect clusters. The self-irradiation damage in Plutonium-239 occurs mainly by α-particle decay, where most of the damage comes from the U-235 recoil nucleus. The defects resulting from the residual lattice damage and helium in-growth could result in microstructural and physical property changes. Because these self-irradiation effects would normally require decades to measure, with a fraction (7.5 wt%) of Pu-238 is added to the reference plutonium alloy thus accelerating the aging process by approximately 18 times the normal rate. By monitoring the properties of the Pu-238 spiked alloy over a period of about 3.5 years, the properties of plutonium in storage can be projected for periods up to about 60 years. This paper presents density and volume changes observed from the immersion density and dilatometry measurements equivalent to aging the reference plutonium alloys to nine years.


Diabetes ◽  
1995 ◽  
Vol 44 (1) ◽  
pp. 125-131 ◽  
Author(s):  
C. B. Sanjeevi ◽  
T. P. Lybrand ◽  
C. DeWeese ◽  
M. Landin-Olsson ◽  
I. Kockum ◽  
...  

2006 ◽  
Vol 986 ◽  
Author(s):  
Brandon W. Chung ◽  
Bill Choi ◽  
Cheng Saw ◽  
Stephen Thompson ◽  
Conrad Woods ◽  
...  

AbstractWe present changes in volume, immersion density, and tensile property observed from accelerated aged plutonium alloys. Accelerated alloys (or spiked alloys) are plutonium alloys enriched with approximately 7.5 weight percent of the faster-decaying 238Pu to accelerate the aging process by approximately 17 times the rate of unaged weapons-grade plutonium. After sixty equivalent years of aging on spiked alloys, the dilatometry shows the samples at 35°C have swelled in volume by 0.15 to 0.17 % and now exhibit a near linear volume increase due to helium in-growth. The immersion density of spiked alloys shows decrease in density, similar normalized volumetric changes (expansion) for spiked alloys. Tensile tests show increasing yield and engineering ultimate strength as spiked alloys are aged.


2005 ◽  
Vol 63 (2) ◽  
pp. 193-198 ◽  
Author(s):  
Quintino R. Araujo ◽  
Nicholas B. Comerford ◽  
Andrew V. Ogram ◽  
Abid Al-Agely ◽  
Lindolfo P. Santos. Filho ◽  
...  

2004 ◽  
Vol 77 (2) ◽  
pp. 242-256 ◽  
Author(s):  
Arnis U. Paeglis

Abstract Heat aging stability is a hallmark of EPDM rubber and a requirement for use in automotive, roofing and other applications. Retention of physical properties after accelerated heat aging is a typical specification for such long-term uses. This paper examines the utility of such tests in predicting results over a range of temperatures, 116 °C, 125 °C, 135 °C and 150 °C, in some cases for as long as 365 days. A simple empirical model was developed to predict the retention of physical properties using fractional strain energy, that is, the ratio of the aged to unaged products of tensile strength and elongation at break. Characteristic rates, an Arrhenius rate relationship and activation energies were determined. This model provides a basis to predict physical property changes over a wide range of temperatures and times, as well as for considerations of equivalent heat aging tests and use in different applications.


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