Effect of Silica Nanofluid on Nanoscopic Pore Structure of Low-Permeability Petroleum Reservoir by Nitrogen Adsorption Technique: A Case Study

2019 ◽  
Vol 44 (6) ◽  
pp. 6167-6178
Author(s):  
Caspar Daniel Adenutsi ◽  
Zhiping Li ◽  
Zhichao Xu ◽  
Anthony Edem Hama ◽  
Lili Sun ◽  
...  
2014 ◽  
Vol 962-965 ◽  
pp. 34-40
Author(s):  
Ning Yang ◽  
Shu Heng Tang ◽  
Song Hang Zhang ◽  
Jun Jie Yi

Gas shales have a complex pore structure. Using mercury porosimetry and nitrogen adsorption experiment on shale of Longtan Formation in southeastern of Hunan, the pore structure characteristics were contrast analyzed, influencing factors and its impact on reservoir-forming were discussed. Longtan Formation shale is composed of nanopores, include the cylinder pores with two ends open and parallel-plate pores with four sides open. The efficiency of mercury ejection ranges 31.45%~63.82%, 51.94% on average, pores uniformity is well. The size of nanopores is 5~30nm, taking up 94.74% of the total volume and 98.08% of specific surface area. Brittle minerals content is high, as an important parameter influencing pore development. The nanopores have a strong ability to absorb gas, methane molecule exist in a structured way.


Minerals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 298
Author(s):  
Chenlong Ding ◽  
Jinxian He ◽  
Hongchen Wu ◽  
Xiaoli Zhang

Ordos Basin is an important continental shale gas exploration site in China. The micropore structure of the shale reservoir is of great importance for shale gas evaluation. The Taiyuan Formation of the lower Permian is the main exploration interval for this area. To examine the nanometer pore structures in the Taiyuan Formation shale reservoirs in the Lin-Xing area, Northern Shaanxi, the microscopic pore structure characteristics were analyzed via nitrogen adsorption experiments. The pore structure parameters, such as specific surface area, pore volume, and aperture distribution, of shale were calculated; the significance of the pore structure for shale gas storage was analyzed; and the main controlling factors of pore development were assessed. The results indicated the surface area and hole volume of the shale sample to be 0.141–2.188 m2/g and 0.001398–0.008718 cm3/g, respectively. According to the IUPAC (International Union of Pure and Applied Chemistry) classification, mesopores and macropores were dominant in the pore structure, with the presence of a certain number of micropores. The adsorption curves were similar to the standard IV (a)-type isotherm line, and the hysteresis loop type was mainly similar to H3 and H4 types, indicating that most pores are dominated by open type pores, such as parallel plate-shaped pores and wedge-shaped slit pores. The micropores and mesopores provide the vast majority of the specific surface area, functioning as the main area for the adsorption of gas in the shale. The mesopores and macropores provide the vast majority of the pore volume, functioning as the main storage areas for the gas in the shale. Total organic carbon had no notable linear correlation with the total pore volume and the specific surface area. Vitrinite reflectance (Ro) had no notable correlation with the specific surface area, but did have a low “U” curve correlation with the total pore volume. There was no relationship between the quartz content and specific surface area and total pore volume. In addition, there was no notable correlation between the clay mineral content and total specific surface area and total pore volume.


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