Oxidative degradation of sulfamethoxazole from secondary treated effluent by ferrate(VI): kinetics, by-products, degradation pathway and toxicity assessment

Author(s):  
Behjat Jebalbarezi ◽  
Reza Dehghanzadeh ◽  
Samira Sheikhi ◽  
Najmeh Shahmahdi ◽  
Hassan Aslani ◽  
...  
Catalysts ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1432
Author(s):  
Edyta Kudlek

Every compound that potentially can be harmful to the environment is called a Contaminant of Emerging Concern (CEC). Compounds classified as CECs may undergo different transformations, especially in the water environment. The intermediates formed in this way are considered to be toxic against living organisms even in trace concentrations. We attempted to identify the intermediates formed during single chlorination and UV-catalyzed processes supported by the action of chlorine and hydrogen peroxide or ozone of selected contaminants of emerging concern. The analysis of post-processing water samples containing benzocaine indicated the formation of seven compound intermediates, while ibuprofen, acridine and β-estradiol samples contained 5, 5, and 3 compound decomposition by-products, respectively. The number and also the concentration of the intermediates decreased with the time of UV irradiation. The toxicity assessment indicated that the UV-catalyzed processes lead to decreased toxicity nature of post-processed water solutions.


2019 ◽  
Vol 17 (1) ◽  
pp. 1017-1025
Author(s):  
Mohamed Réda Arhoutane ◽  
Muna Shueai Yahya ◽  
Miloud El Karbane ◽  
Kacem El Kacemi

AbstractIn the context of environmental protection, where there is a need to develop effective operations for carrying out appropriate treatment of polluted water by pharmaceuticals. Therefore, the present study aims at evaluating the degradation for gentamicin through electro-Fenton (EF) operation, through taking into consideration the effect of several parameters of experimental in the process, namely, the concentration of initial gentamicin, the applied current and the Fe+2 (II) quantities. The (EF) operation employed involves a carbon-felt as cathode and platinum as anode at pH 3. Studies for the gentamicin kinetics is monitored by HPLC giving a pseudo-first order reaction following by a chemical oxygen demand, with a reached degree of mineralization 96% after of four hours of treatment through current 100 mA/cm2 with 0.1 mM of Fe+2. We find that the degradation for molecule of gentamicin is accompanied by an augmentation of the biodegradability, assesse through the Biochemical Oxygen Demand (BOD5) on chemical oxygen demand (COD) ratio, that augmentation from 0 to 0.41 before treatment after 30 min for EF treatment, showing that there is potential for conjugation of the EF process and the biological process. Furthermore, the by-products have been identified on the basis of HPLC-MS/MS results.


2004 ◽  
Vol 50 (5) ◽  
pp. 227-234 ◽  
Author(s):  
M. Petrovic ◽  
P. Gehringer ◽  
H. Eschweiler ◽  
D. Barceló

A commercial blend of nonylphenol ethoxylates (NPEOs) was chosen as representative for non-ionic polyethoxylated surfactants to study the oxidative degradation of this class of surfactants in water using ozonation as well as electron beam irradiation with and without the addition of ozone as treatment processes. The electron beam irradiation processes applied represent so-called Advanced Oxidation Processes (AOPs); the combined ozone/electron beam irradiation is, moreover, the most powerful AOP which can be applied in aqueous systems. It was found that both ozonation and the two AOPs applied were able to decompose not only the NPEOs but also the polyethyleneglycoles (PEGs) formed as by-products from NPEO degradation to residual concentrations below the limit of detection. Moreover, the treatment processes were also used to study the oxidative degradation of nonylphenoxy acetic acid (NPEC) and of nonylphenol (NP) which are formed as by-products from biodegradation of NPEOs.


2020 ◽  
Vol 171 ◽  
pp. 115451
Author(s):  
Marina Ariño Martin ◽  
Jayaraman Sivaguru ◽  
John McEvoy ◽  
Prinpida Sonthiphand ◽  
Andre Delorme ◽  
...  

Chemosphere ◽  
2020 ◽  
Vol 238 ◽  
pp. 124572 ◽  
Author(s):  
Joana M.C. Fernandes ◽  
Rose Marie O.F. Sousa ◽  
Irene Fraga ◽  
Ana Sampaio ◽  
Carla Amaral ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 612 ◽  
Author(s):  
Juan José Rueda-Márquez ◽  
Irina Levchuk ◽  
Manuel Manzano ◽  
Mika Sillanpää

The application of Fenton-based advanced oxidation processes (AOPs), such as photo-Fenton or electro-Fenton for wastewater treatment have been extensively studied in recent decades due to its high efficiency for the decomposition of persistent organic pollutants. Usually Fenton-based AOPs are used for the degradation of targeted pollutant or group of pollutants, which often leads to the formation of toxic by-products possessing a potential environmental risk. In this work, we have collected and reviewed recent findings regarding the feasibility of Fenton-based AOPs (photo-Fenton, UVC/H2O2, electro-Fenton and galvanic Fenton) for the detoxification of real municipal and industrial wastewaters. More specifically, operational conditions, relevance and suitability of different bioassays for the toxicity assessment of various wastewater types, cost estimation, all of which compose current challenges for the application of these AOPs for real wastewater detoxification are discussed.


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