Electrochemical method to vinyl fluorides (II). Cathodic cleavage and carboxylation of 1-fluoro-2-(4-biphenylyl)vinyl phenyl sulphoxide in nonaqueous media

1995 ◽  
Vol 40 (7) ◽  
pp. 829-835 ◽  
Author(s):  
Akira Kunugi ◽  
Shinya Mori ◽  
Seiji Komatsu ◽  
Hiroshi Matsui ◽  
Hidemitsu Uno ◽  
...  
Keyword(s):  
Electrochemical Method ◽  
Nonaqueous Media ◽  
Vinyl Fluorides

Electrochemical method to vinyl fluorides—I. Cathodic elimination of 1-fluoro-2-arylvinyl phenyl sulphones in acetonitrile

1993 ◽  
Vol 38 (7) ◽  
pp. 1037-1041 ◽  
Author(s):  
Akira Kunugi ◽  
Kenji Yamane ◽  
Mikito Yasuzawa ◽  
Hiroshi Matsui ◽  
Hidemitsu Uno ◽  
...  
Keyword(s):  
Electrochemical Method ◽  
Vinyl Fluorides

scholarly journals Electrochemical Method to Vinyl Fluorides III. Electrochemical Cleavage of 1-Fluoro-2-arylvinyl Phenyl Sulfoxides in Acetonitrile

1995 ◽  
Vol 63 (5) ◽  
pp. 433-436
Author(s):  
Akira KUNUGI ◽  
Shinya MORI ◽  
Mikito YASUZAWA ◽  
Hidemitsu UNO ◽  
Katsuji SAKAMOTO
Keyword(s):  
Electrochemical Method ◽  
Vinyl Fluorides

Stereodivergent Alkyne Hydrofluorination Using a Simple Practical Reagent

2020 ◽  
Author(s):  
Rui Guo ◽  
Xiaotian Qi ◽  
Hengye Xiang ◽  
Paul Geaneoates ◽  
Ruihan Wang ◽  
...  
Keyword(s):  
Bond Formation ◽  
Biologically Active ◽  
Dft Studies ◽  
Thermodynamic Control ◽  
Important Goal ◽  
Peptide Bonds ◽  
Metal Free ◽  
Vinyl Cation ◽  
E And Z Isomers ◽  
Vinyl Fluorides

Vinyl fluorides play an important role in drug development as they serve as bioisosteres for peptide bonds and are found in a range of biologically active molecules. The discovery of safe, general and practical procedures to prepare vinyl fluorides remains an important goal and challenge for synthetic chemistry. Here we introduce an inexpensive and easily-handled reagent and report simple, scalable, and metal-free protocols for the regioselective and stereodivergent hydrofluorination of alkynes to access both the E and Z isomers of vinyl fluorides. These conditions were suitable for a diverse collection of alkynes, including several highly-functionalized pharmaceutical derivatives. Mechanistic and DFT studies support C–F bond formation through a vinyl cation intermediate, with the (E)- and (Z)-hydrofluorination products forming under kinetic and thermodynamic control, respectively.<br>

MEASUREMENT OF THE DIFFUSIVITY OF OXYGEN IN HIGH--TEMPERATURE LIQUID SILVER BY ELECTROCHEMICAL METHOD

2010 ◽  
Vol 46 (3) ◽  
pp. 277-281 ◽  
Author(s):  
Yunming GAO ◽  
Jianxin SONG ◽  
Yeqin ZHANG ◽  
Xingmin GUO
Keyword(s):  
High Temperature ◽  
Electrochemical Method ◽  
Liquid Silver ◽  
Temperature Liquid

Influence of medium on alkaline hydrolysis of succinic acid monomethyl and monopropyl esters

1980 ◽  
Vol 45 (11) ◽  
pp. 2873-2882
Author(s):  
Vladislav Holba ◽  
Ján Benko
Keyword(s):  
Succinic Acid ◽  
Kinetic Parameters ◽  
Alkaline Hydrolysis ◽  
Specific Interactions ◽  
Nonaqueous Media ◽  
The Media ◽  
Kinetics Of ◽  
Hydrolysis Of

The kinetics of alkaline hydrolysis of succinic acid monomethyl and monopropyl esters were studied in mixed aqueous-nonaqueous media at various temperatures and ionic strengths. The results of measurements are discussed in terms of electrostatic and specific interactions between the reactants and other components of the reaction mixture. The kinetic parameters in the media under study are related to the influence of the cosolvent on the solvation sphere of the reactants.

Detecting Critical Crevice Temperature for Duplex Stainless Steels in Chloride Solutions

CORROSION ◽  
2011 ◽  
Vol 67 (2) ◽  
pp. 025004-1-025004-7 ◽  
Author(s):  
D. Han ◽  
Y. Jiang ◽  
B. Deng ◽  
L. Zhang ◽  
J. Gao ◽  
...  
Keyword(s):  
Stainless Steels ◽  
Crevice Corrosion ◽  
Electrochemical Method ◽  
Duplex Stainless Steels ◽  
Good Reproducibility ◽  
X Ray ◽  
Initiation Step ◽  
Critical Pitting Temperature ◽  
Preferential Dissolution ◽  
Scanning Electron

Abstract A simple and rapid electrochemical method for the evaluation of crevice corrosion in duplex stainless steels (DSS) is described. Three types of DSS—namely, UNS S32101, UNS S31803, and UNS S32750—were tested in 1 mol/L sodium chloride (NaCl) solutions. Results showed good reproducibility with a typical standard deviation of below 3°C. The critical pitting temperature (CPT) for the same specimens was also investigated in 1 mol/L NaCl solutions. An approximately 20°C decrease from CPT to critical crevice temperature (CCT) was observed and subsequently explained. Then, the morphologies of crevice corrosion were studied using scanning electron microscopy with energy-dispersive x-ray spectroscopy (SEM/EDS) method. The SEM/EDS study revealed that the ferrite phase was the site where preferential dissolution took place at the initiation step of crevice corrosion, which was in accordance with the prediction by calculating the critical crevice index. Moreover, repassivation was detected with the development of crevice corrosion. The reason was clarified by combining the results obtained with a successful diffusion model, and eventually the crevice corrosion progress was illustrated schematically.

scholarly journals An electrochemical method to investigate the effects of compound composition on gold dissolution in thiosulfate solution

2020 ◽  
Vol 9 (1) ◽  
pp. 496-502 ◽  
Author(s):  
Zhaohui Zhang ◽  
Bailong Liu ◽  
Mei Wu ◽  
Longxin Sun
Keyword(s):  
Dissolution Rate ◽  
Current Density ◽  
Polarization Resistance ◽  
Electrochemical Method ◽  
Corrosion Current Density ◽  
Corrosion Potential ◽  
Corrosion Current ◽  
Gold Dissolution ◽  
Tafel Polarization ◽  
Edta Solution

AbstractThe electrochemical behavior of gold dissolution in the Cu2+–NH3–S2O32−–EDTA solution has been investigated in detail by deriving and analyzing the Tafel polarization curve, as this method is currently widely implemented for the electrode corrosion analysis. The dissolution rate of gold in Cu2+–NH3–S2O32−–EDTA solution was determined based on the Tafel polarization curves, and the effects of various compound compositions in a Cu2+–NH3–S2O32−–EDTA mixture on the corrosion potential and corrosion current density were analyzed. The results showed that the corrosion potential and polarization resistance decreased, whereas the corrosion current density increased for certain concentrations of S2O32−–NH3–Cu2+ and EDTA, indicating that the dissolution rate of gold had changed. The reason for promoting the dissolution of gold is also discussed.

scholarly journals Electrochemical bubble generation via hydrazine oxidation for the in situ control of an electrodeposited conducting polymer micro/-nanostructure

RSC Advances ◽  
2021 ◽  
Vol 11 (18) ◽  
pp. 11020-11025
Author(s):  
David Possetto ◽  
Luciana Fernández ◽  
Gabriela Marzari ◽  
Fernando Fungo
Keyword(s):  
Conducting Polymer ◽  
Electrochemical Method ◽  
Bubble Generation ◽  
Hydrazine Oxidation ◽  
In Situ Control

An electrochemical method to manipulate the size and density of electrodeposited polypyrrole structures at the micro-nanoscale by the discharge of hydrazine.

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