Calculated rate constants for the reaction ClO + O → Cl + O2 between 220 and 1000 k

1979 ◽  
Vol 40 (1-2) ◽  
pp. 185-206 ◽  
Author(s):  
Richard L. Jaffe
Keyword(s):  
Rate Constants ◽  
Calculated Rate

scholarly journals A model of tetrahydrofuran low-temperature oxidation based on theoretically calculated rate constants

2018 ◽  
Vol 191 ◽  
pp. 252-269 ◽  
Author(s):  
Yann Fenard ◽  
Adrià Gil ◽  
Guillaume Vanhove ◽  
Hans-Heinrich Carstensen ◽  
Kevin M. Van Geem ◽  
...  
Keyword(s):  
Low Temperature ◽  
Rate Constants ◽  
Low Temperature Oxidation ◽  
Temperature Oxidation ◽  
Calculated Rate

Kinetics of iron(III) hydrolysis and precipitation in aqueous glycine solutions assessed by voltammetry

2009 ◽  
Vol 74 (10) ◽  
pp. 1531-1542 ◽  
Author(s):  
Vlado Cuculić ◽  
Ivanka Pižeta
Keyword(s):  
Ionic Strength ◽  
Complex Formation ◽  
Rate Constants ◽  
Glycine Concentration ◽  
First Order ◽  
Mercury Drop Electrode ◽  
Calculated Rate ◽  
Cathodic Voltammetry ◽  
Kinetics Of ◽  
Voltammetric Measurements

The kinetics of iron(III) hydrolysis and precipitation in aqueous glycine solutions were studied by cathodic voltammetry with a mercury drop electrode. The kinetics was controlled by changing ionic strength (I), pH and glycine concentration. Voltammetric measurements clearly showed formation and dissociation of a soluble Fe(III)–glycine complex, formation of iron(III) hydroxide and its precipitation. The rate constants of iron(III) hydroxide precipitation were assessed. The precipitation is first-order with respect to dissolved inorganic iron(III). The calculated rate constants of iron(III) precipitation varied from 0.18 × 10–5 s–1 (at 0.2 M total glycine, pH 7.30, I = 0.6 mol dm–3) to 2.22 × 10–3 s–1 (at 0.1 M total glycine, pH 7.30, I = 0.2 mol dm–3). At 0.5 M total glycine and I = 0.6 mol dm–3, the iron(III) precipitation was not observed.

Detailed kinetics of tetrafluoroethene ozonolysis

2018 ◽  
Vol 20 (44) ◽  
pp. 28059-28067 ◽  
Author(s):  
Tam V.-T. Mai ◽  
Minh v. Duong ◽  
Hieu T. Nguyen ◽  
Lam K. Huynh
Keyword(s):  
Experimental Data ◽  
Reaction Mechanism ◽  
Kinetic Analysis ◽  
Rate Constants ◽  
Rate Model ◽  
Rate Determining Step ◽  
Calculated Rate ◽  
Detailed Kinetics ◽  
Kinetics Of

The reaction mechanism was explored at the CCSD(T)/CBS//B3LYP/aug-cc-pVTZ level. Detailed kinetic analysis was firstly carried out using an ME/RRKM rate model with the inclusion of anharmonic and tunneling treatments. 1,3-Cycloaddition is found to be the rate-determining step. Calculated rate constants confirm the latest experimental data.

Calculated rate constants of the chemical reactions involving the main byproducts SO2F, SOF2, SO2F2of SF6decomposition in power equipment

2016 ◽  
Vol 49 (15) ◽  
pp. 155502 ◽  
Author(s):  
Yuwei Fu ◽  
Mingzhe Rong ◽  
Kang Yang ◽  
Aijun Yang ◽  
Xiaohua Wang ◽  
...  
Keyword(s):  
Chemical Reactions ◽  
Rate Constants ◽  
Power Equipment ◽  
Calculated Rate
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