Reverse electrodialysis heat engine (REDHE)

2022 ◽  
pp. 127-162
Author(s):  
Marina Micari ◽  
Francesco Giacalone ◽  
Andrea Cipollina ◽  
Giorgio Micale ◽  
Alessandro Tamburini
2019 ◽  
Vol 253 ◽  
pp. 113489 ◽  
Author(s):  
B. Ortega-Delgado ◽  
F. Giacalone ◽  
A. Cipollina ◽  
M. Papapetrou ◽  
G. Kosmadakis ◽  
...  

Energies ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 3206 ◽  
Author(s):  
◽  
George Kosmadakis ◽  
Francesco Giacalone ◽  
Bartolomé Ortega-Delgado ◽  
Andrea Cipollina ◽  
...  

In the examined heat engine, reverse electrodialysis (RED) is used to generate electricity from the salinity difference between two artificial solutions. The salinity gradient is restored through a multi-effect distillation system (MED) powered by low-temperature waste heat at 100 °C. The current work presents the first comprehensive economic and environmental analysis of this advanced concept, when varying the number of MED effects, the system sizing, the salt of the solutions, and other key parameters. The levelized cost of electricity (LCOE) has been calculated, showing that competitive solutions can be reached only when the system is at least medium to large scale. The lowest LCOE, at about 0.03 €/kWh, is achieved using potassium acetate salt and six MED effects while reheating the solutions. A similar analysis has been conducted when using the system in energy storage mode, where the two regenerated solutions are stored in reservoir tanks and the RED is operating for a few hours per day, supplying valuable peak power, resulting in a LCOE just below 0.10 €/kWh. A life-cycle assessment has been also carried out, showing that the case with the lowest environmental impact is the same as the one with the most attractive economic performance. Results indicate that the material manufacturing has the main impact; primarily the metallic parts of the MED. Overall, this study highlights the development efforts required in terms of both membrane performance and cost reduction, in order to make this technology cost effective in the future.


2020 ◽  
Vol 595 ◽  
pp. 117522 ◽  
Author(s):  
F. Giacalone ◽  
F. Vassallo ◽  
F. Scargiali ◽  
A. Tamburini ◽  
A. Cipollina ◽  
...  

Membranes ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 48
Author(s):  
Pauline Zimmermann ◽  
Simon Birger Byremo Solberg ◽  
Önder Tekinalp ◽  
Jacob Joseph Lamb ◽  
Øivind Wilhelmsen ◽  
...  

The Reverse electrodialysis heat engine (REDHE) combines a reverse electrodialysis stack for power generation with a thermal regeneration unit to restore the concentration difference of the salt solutions. Current approaches for converting low-temperature waste heat to electricity with REDHE have not yielded conversion efficiencies and profits that would allow for the industrialization of the technology. This review explores the concept of Heat-to-Hydrogen with REDHEs and maps crucial developments toward industrialization. We discuss current advances in membrane development that are vital for the breakthrough of the RED Heat Engine. In addition, the choice of salt is a crucial factor that has not received enough attention in the field. Based on ion properties relevant for both the transport through IEMs and the feasibility for regeneration, we pinpoint the most promising salts for use in REDHE, which we find to be KNO3, LiNO3, LiBr and LiCl. To further validate these results and compare the system performance with different salts, there is a demand for a comprehensive thermodynamic model of the REDHE that considers all its units. Guided by such a model, experimental studies can be designed to utilize the most favorable process conditions (e.g., salt solutions).


2019 ◽  
Vol 189 ◽  
pp. 1-13 ◽  
Author(s):  
F. Giacalone ◽  
F. Vassallo ◽  
L. Griffin ◽  
M.C. Ferrari ◽  
G. Micale ◽  
...  

2019 ◽  
Vol 194 ◽  
pp. 140-159 ◽  
Author(s):  
B. Ortega-Delgado ◽  
F. Giacalone ◽  
P. Catrini ◽  
A. Cipollina ◽  
A. Piacentino ◽  
...  

Desalination ◽  
2019 ◽  
Vol 453 ◽  
pp. 77-88 ◽  
Author(s):  
M. Micari ◽  
A. Cipollina ◽  
F. Giacalone ◽  
G. Kosmadakis ◽  
M. Papapetrou ◽  
...  

2017 ◽  
Vol 206 ◽  
pp. 1334-1353 ◽  
Author(s):  
A. Tamburini ◽  
M. Tedesco ◽  
A. Cipollina ◽  
G. Micale ◽  
M. Ciofalo ◽  
...  

2019 ◽  
Vol 20 (23) ◽  
pp. 5860
Author(s):  
Fabao Luo ◽  
Yang Wang ◽  
Maolin Sha ◽  
Yanxin Wei

The main objective of this study is to explore the influence of ion composition on the trans-membrane potential across the ion exchange membrane (IEM), and thus offers a reference for the deep insight of “reverse electrodialysis heat engine” running in the composite systems. In comparison to the natural system (river water | seawater), the performance of the reverse electrodialysis (RED) stack was examined using NaHCO3, Na2CO3, and NH4Cl as the supporting electrolyte in the corresponding compartment. The effect of flow rates and the concentration ratio in the high salt concentration compartment (HCC)/low salt concentration compartment (LCC) on energy generation was investigated in terms of the open-circuit voltage (OCV) and power density per membrane area. It was found that the new system (0.49 M NaCl + 0.01 M NaHCO3|0.01 M NaHCO3) output a relatively stable power density (0.174 W·m−2), with the open-circuit voltage 2.95 V under the low flow rate of 0.22 cm/s. Meanwhile, the simulated natural system (0.5 M NaCl|0.01 M NaCl) output the power density 0.168 W·m−2, with the open-circuit voltage 2.86 V under the low flow rate of 0.22 cm/s. The findings in this work further confirm the excellent potential of RED for the recovery of salinity gradient energy (SGP) that is reserved in artificially-induced systems (wastewaters).


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