Boosting the performance of a Reverse Electrodialysis – Multi-Effect Distillation Heat Engine by novel solutions and operating conditions

2019 ◽  
Vol 253 ◽  
pp. 113489 ◽  
Author(s):  
B. Ortega-Delgado ◽  
F. Giacalone ◽  
A. Cipollina ◽  
M. Papapetrou ◽  
G. Kosmadakis ◽  
...  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Gabriel Valencia-Ortega ◽  
Sergio Levario-Medina ◽  
Marco Antonio Barranco-Jiménez

Abstract The proposal of models that account for the irreversibilities within the core engine has been the topic of interest to quantify the useful energy available during its conversion. In this work, we analyze the energetic optimization and stability (local and global) of three power plants, nuclear, combined-cycle, and simple-cycle ones, by means of the Curzon–Ahlborn heat engine model which considers a linear heat transfer law. The internal irreversibilities of the working fluid measured through the r-parameter are associated with the so-called “uncompensated Clausius heat.” In addition, the generalization of the ecological function is used to find operating conditions in three different zones, which allows to carry out a numerical analysis focused on the stability of power plants in each operation zone. We noted that not all power plants reveal stability in all the operation zones when irreversibilities are considered through the r-parameter on real-world power plants. However, an improved stability is shown in the zone limited by the maximum power output and maximum efficiency regimes.


Entropy ◽  
2018 ◽  
Vol 20 (9) ◽  
pp. 666
Author(s):  
Julien Ramousse ◽  
Christophe Goupil

Thermoelectric system’s operation needs careful attention to ensure optimal power conversion depending on the application aims. As a ternary diagram of bithermal systems allows a synthetic graphical analysis of the performance attainable by any work-heat conversion system, thermoelectric systems operation is plotted as a parametric curve function of the operating conditions (electric current and reservoirs’ temperature), based on the standard model of Ioffe. The threshold of each operating mode (heat engine, heat pump, thermal dissipation, and forced thermal transfer), along with the optimal efficiencies and powers of the heat pump and heat engine modes, are characterized graphically and analytically as a function of the material properties and the operating conditions. The sensibility of the performance aims (maximum efficiency vs. maximum power) with the operating conditions is, thus, highlighted. In addition, the specific contributions of each phenomenon involved in the semiconductor (reversible Seebeck effect, irreversible heat leakage by conduction and irreversible thermal dissipation by Joule effect) are discussed in terms of entropy generation. Finally, the impact of the exo-irreversibilities on the performance is analyzed by taking the external thermal resistances into account.


Desalination ◽  
2019 ◽  
Vol 457 ◽  
pp. 8-21 ◽  
Author(s):  
Rafael Ortiz-Imedio ◽  
Lucia Gomez-Coma ◽  
Marcos Fallanza ◽  
Alfredo Ortiz ◽  
Raquel Ibañez ◽  
...  

Energies ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 5510
Author(s):  
Andrea Zaffora ◽  
Andrea Culcasi ◽  
Luigi Gurreri ◽  
Alessandro Cosenza ◽  
Alessandro Tamburini ◽  
...  

Bipolar Membrane Reverse Electrodialysis (BMRED) can be used to produce electricity exploiting acid-base neutralization, thus representing a valuable route in reusing waste streams. The present work investigates the performance of a lab-scale BMRED module under several operating conditions. By feeding the stack with 1 M HCl and NaOH streams, a maximum power density of ~17 W m−2 was obtained at 100 A m−2 with a 10-triplet stack with a flow velocity of 1 cm s−1, while an energy density of ~10 kWh m−3 acid could be extracted by a complete neutralization. Parasitic currents along feed and drain manifolds significantly affected the performance of the stack when equipped with a higher number of triplets. The apparent permselectivity at 1 M acid and base decreased from 93% with the five-triplet stack to 54% with the 38-triplet stack, which exhibited lower values (~35% less) of power density. An important role may be played also by the presence of NaCl in the acidic and alkaline solutions. With a low number of triplets, the added salt had almost negligible effects. However, with a higher number of triplets it led to a reduction of 23.4–45.7% in power density. The risk of membrane delamination is another aspect that can limit the process performance. However, overall, the present results highlight the high potential of BMRED systems as a productive way of neutralizing waste solutions for energy harvesting.


Author(s):  
Muhammad I. Rashad ◽  
Hend A. Faiad ◽  
Mahmoud Elzouka

This paper presents the operating principle of a novel solar rotary crank-less heat engine. The proposed engine concept uses air as working fluid. The reciprocating motion is converted to a rotary motion by the mean of unbalanced mass and Coriolis effect, instead of a crank shaft. This facilitates the engine scaling and provides several degrees of freedom in terms of structure design and configuration. Unlike classical heat engines (i.e. Stirling), the proposed engine can be fixed to the ground which significantly reduce the generation unit cost. Firstly, the engine’s configuration is illustrated. Then, order analysis for the engine is carried out. The combined dynamics and thermal model is developed using ordinary differential equations which are then numerically solved by Simulink™. The resulting engine thermodynamics cycle is described. It incorporates the common thermodynamics processes (isobaric, isothermal, isochoric processes). Finally, the system behavior and performance are analyzed along with studying the effect of various design parameters on operating conditions such as engine speed, output power and efficiency.


2016 ◽  
Vol 139 (3) ◽  
Author(s):  
German Amador Diaz ◽  
Jorge Duarte Forero ◽  
Jesus Garcia ◽  
Adriana Rincon ◽  
Armando Fontalvo ◽  
...  

The application of equilibrium thermodynamics in the study of thermal plant performance under real operating conditions is a constant challenge. In this paper, an analysis of a reservoir pressure piston working between two linear flow resistances is performed by considering the friction of the piston cylinder system on the walls. The proposed model is developed to obtain the optimum power output and speed of the piston in terms of first law efficiency. If the friction on the piston–cylinder assembly is neglected, the expressions obtained are consistent with those presented in the literature under laminar regime. It was also demonstrated that for both laminar and turbulent regimes with overall size constraints, the power delivered can be maximized by balancing the upstream and downstream flow resistances of the piston. This paper also evaluated the influence of the overall size constraints and flow regime on the performance of the piston cylinder. This analysis is equivalent to evaluate the irreversibilities in an endo-irreversible Carnot heat engine with heat loss resistance between the engine and its heat reservoirs. The proposed model introduced some modifications to the results obtained from the recent literature and led to important conclusions. Finally, the proposed model was applied to calculate the lost available work in a turbine operating at steady flow conditions with an ideal gas as working fluid.


Energies ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 3206 ◽  
Author(s):  
◽  
George Kosmadakis ◽  
Francesco Giacalone ◽  
Bartolomé Ortega-Delgado ◽  
Andrea Cipollina ◽  
...  

In the examined heat engine, reverse electrodialysis (RED) is used to generate electricity from the salinity difference between two artificial solutions. The salinity gradient is restored through a multi-effect distillation system (MED) powered by low-temperature waste heat at 100 °C. The current work presents the first comprehensive economic and environmental analysis of this advanced concept, when varying the number of MED effects, the system sizing, the salt of the solutions, and other key parameters. The levelized cost of electricity (LCOE) has been calculated, showing that competitive solutions can be reached only when the system is at least medium to large scale. The lowest LCOE, at about 0.03 €/kWh, is achieved using potassium acetate salt and six MED effects while reheating the solutions. A similar analysis has been conducted when using the system in energy storage mode, where the two regenerated solutions are stored in reservoir tanks and the RED is operating for a few hours per day, supplying valuable peak power, resulting in a LCOE just below 0.10 €/kWh. A life-cycle assessment has been also carried out, showing that the case with the lowest environmental impact is the same as the one with the most attractive economic performance. Results indicate that the material manufacturing has the main impact; primarily the metallic parts of the MED. Overall, this study highlights the development efforts required in terms of both membrane performance and cost reduction, in order to make this technology cost effective in the future.


2020 ◽  
Vol 595 ◽  
pp. 117522 ◽  
Author(s):  
F. Giacalone ◽  
F. Vassallo ◽  
F. Scargiali ◽  
A. Tamburini ◽  
A. Cipollina ◽  
...  

Membranes ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 48
Author(s):  
Pauline Zimmermann ◽  
Simon Birger Byremo Solberg ◽  
Önder Tekinalp ◽  
Jacob Joseph Lamb ◽  
Øivind Wilhelmsen ◽  
...  

The Reverse electrodialysis heat engine (REDHE) combines a reverse electrodialysis stack for power generation with a thermal regeneration unit to restore the concentration difference of the salt solutions. Current approaches for converting low-temperature waste heat to electricity with REDHE have not yielded conversion efficiencies and profits that would allow for the industrialization of the technology. This review explores the concept of Heat-to-Hydrogen with REDHEs and maps crucial developments toward industrialization. We discuss current advances in membrane development that are vital for the breakthrough of the RED Heat Engine. In addition, the choice of salt is a crucial factor that has not received enough attention in the field. Based on ion properties relevant for both the transport through IEMs and the feasibility for regeneration, we pinpoint the most promising salts for use in REDHE, which we find to be KNO3, LiNO3, LiBr and LiCl. To further validate these results and compare the system performance with different salts, there is a demand for a comprehensive thermodynamic model of the REDHE that considers all its units. Guided by such a model, experimental studies can be designed to utilize the most favorable process conditions (e.g., salt solutions).


2022 ◽  
pp. 127-162
Author(s):  
Marina Micari ◽  
Francesco Giacalone ◽  
Andrea Cipollina ◽  
Giorgio Micale ◽  
Alessandro Tamburini

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