THERMAL CONVERSION OF CELLULOSIC MATERIALS TO FUEL AND CHEMICALS

Author(s):  
Fred Shafizadeh
2019 ◽  
Author(s):  
Maria Teresa Odinolfi ◽  
Alessandro Romanato ◽  
Greta Bergamaschi ◽  
Alessandro Strada ◽  
Laura Sola ◽  
...  

The use of peptides in paper-based analytics is a highly appealing field, yet it suffers from severe limitations. This is mostly due to the loss of effective target recognition properties of this relatively small bioprobes upon nonspecific adsorption onto cellulose substrates. Here, we address this issue by introducing a simple polymer-based strategy to obtain clickable cellulosic surfaces, that we exploited for the chemoselective bioconjugation of peptide bioprobes. Our method largely outperformed standard adsorption-based immobilization strategy in a challenging, real-case immunoassay, namely the diagnostic discrimination of Zika+ individuals from healthy controls. Of note, the clickable polymeric coating not only allows efficient peptides bioconjugation, but it provides favorable anti-fouling properties to the cellulosic support. We envisage our strategy to broaden the repertoire of cellulosic materials manipulation and promote a renewed interest in peptide-based paper bioassays.


2019 ◽  
Author(s):  
Maria Teresa Odinolfi ◽  
Alessandro Romanato ◽  
Greta Bergamaschi ◽  
Alessandro Strada ◽  
Laura Sola ◽  
...  

The use of peptides in paper-based analytics is a highly appealing field, yet it suffers from severe limitations. This is mostly due to the loss of effective target recognition properties of this relatively small bioprobes upon nonspecific adsorption onto cellulose substrates. Here, we address this issue by introducing a simple polymer-based strategy to obtain clickable cellulosic surfaces, that we exploited for the chemoselective bioconjugation of peptide bioprobes. Our method largely outperformed standard adsorption-based immobilization strategy in a challenging, real-case immunoassay, namely the diagnostic discrimination of Zika+ individuals from healthy controls. Of note, the clickable polymeric coating not only allows efficient peptides bioconjugation, but it provides favorable anti-fouling properties to the cellulosic support. We envisage our strategy to broaden the repertoire of cellulosic materials manipulation and promote a renewed interest in peptide-based paper bioassays.


2020 ◽  
pp. 42-48
Author(s):  
Tatiana Safronova ◽  
◽  
Tatiana Shatalova ◽  
Snezhana Tikhonova ◽  
Yaroslav Filippov ◽  
...  

Powders of calcium pyrophosphate Ca2P2O7 in the form of γ- и β-modifications have been produced as a result of thermal conversion of brushite CaHPO4∙2H2O synthesized from phosphoric acid H3PO4 and calcium carbonate CaCO3 at the molar ratio P / Ca = 1.1. The resulting powders can be used for production of various functional materials including biocompatible and bioresorbable ones for the treatment of bone defects.


Cellulose ◽  
2021 ◽  
Author(s):  
Ahmed Fouzi Tarchoun ◽  
Djalal Trache ◽  
Thomas M. Klapötke ◽  
Burkhard Krumm ◽  
Abderrahmane Mezroua ◽  
...  
Keyword(s):  

2021 ◽  
Author(s):  
Kirill B. Larionov ◽  
Albert Zh. Kaltaev ◽  
Vladimir E. Gubin ◽  
Andrey V. Zenkov

2021 ◽  
Vol 3 (3) ◽  
Author(s):  
Munique Gonçalves Guimarães ◽  
Rafael Benjamin Werneburg Evaristo ◽  
Augusto César de Mendonça Brasil ◽  
Grace Ferreira Ghesti

AbstractThe present work analyzed the energy generation potential of Buriti (Mauritia flexuosa L. f.) by thermochemical reactions. The experimental part of the study performed immediate analyses, elemental analyses, lignocellulosic analysis, thermogravimetric analysis, calorific values, and syn gas concentrations measurements of the gasification of Buriti in a fixed-bed reactor. Additionally, numerical simulations estimated the syn gas concentrations of the gasification reactions of Buriti. The immediate analysis showed that Buriti has the highest ash content (4.66%) and highest volatile matter content (85%) compared to other Brazilian biomass analyzed, but the higher heating value was only 18.28 MJ.kg−1. The elemental analysis revealed that the oxygen to carbon ratio was 0.51 while hydrogen to carbon ratio was 1.74, indicating a good thermal conversion efficiency. The Lignocellulosic analysis of Buriti resulted in a high content of holocellulose (69.64%), a lignin content of 28.21% and extractives content of 7.52%. The thermogravimetry of the Buriti indicated that the highest mass loss (51.92%) occurred in a temperature range between 150 °C and 370 °C. Lastly, the experimental gasification study in a fixed-bed updraft gasifier resulted in syn gas concentrations of 14.4% of CO, 11.5% of CO2 and 17.5% of H2 while the numerical simulation results confirmed an optimal equivalence ratio of 1.7 to maximize CO and H2 concentrations. Therefore, based on the results presented by the present work, the gasification process is adequate to transform Buriti wastes into energy resources. Graphic abstract


2020 ◽  
Vol 34 (12) ◽  
pp. 16294-16301
Author(s):  
Marjan Bozaghian Bäckman ◽  
Anna Strandberg ◽  
Mikael Thyrel ◽  
Dan Bergström ◽  
Sylvia H. Larsson

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