The interlayer coupling modulation of a g-C3N4/WTe2 heterostructure for solar cell applications

g-C3N4/WTe2 heterostructure with tunable vdW gap shows a favorable solar energy conversion performance.

A small-sized DSSC panel based on the Uruguayan national flower dye tested at the Antarctic Artigas Base

The construction of a small-sized panel based on anthocyanins from Erythrina crista-galli as sensitizers is reported in this work. The device, named KD12, was placed indoors at the Artigas Antarctic Scientific Base from March 2019 to December 2020. Here is released for the first time, the indoor installation of dye-sensitized solar cells based on pigments from the Uruguayan national flower at an Antarctic Base and the evaluation of their performance during nineteen months. The panel showed good stability and maintained its efficiency conversion performance over the period. The output power, voltage and conversion efficiency generated for this device mainly depended on irradiance and external factors as light reflection due to snow or artificial bulbs near the area. Additional protection was provided by the double-glass window in front of the panel, lowering lighting irradiance and changing spectral characteristics of the light incident the device. A new prospect raised here: the potential application of anthocyanins as sensitizers for indoor electricity generation in the Antarctic area with long term operability, where low temperatures are helpful considering the thermal stability of the dyes. These constitute an interesting first step of a low-cost alternative searching for clean energy generation sources, focusing on a cold region like Antarctica.

Resolving Local Reaction Environment toward an Optimized CO2-to-CO Conversion Performance

The local reaction environment, especially the electrode-electrolyte interface and the relevant hydrodynamic boundary layer in the vicinity of cathode, plays a vital role in defining the activity and selectivity of...

Study of GeSn (0.524 eV) Single-Junction Thermophotovoltaic Cells Based on Device Transport Model

Based on the transport equation of the semiconductor device model for 0.524 eV GeSn alloy and the experimental parameters of the material, thermal-electricity conversion performance governed by GeSn diode has been systematically studied in its normal and inverted structure. For the normal p+/n (n+/p) structure, it is demonstrated here that an optimal base doping N d(a) = 3 (7)×1018 cm-3 is observed, and the superior p+/n structure can reach the higher performance. To reduce material consumption, an economical active layer can be comprised of 100-300 nm emitter and 3-6 μm base to attain comparable performance as that for the optimal configuration. The results can offer many useful guidelines for the fabrication of economical GeSn thermophotovoltaic devices.

PbS1−xSex-Quantum-Dot@MWCNT/P3HT Nanocomposites with Tunable Photoelectric Conversion Performance

The photoelectric performance of quantum dots (QDs)-based nanocomposites is closely related to the optical properties of QDs, which play a critical role in the optical absorption and separation/transfer of charge carriers. Herein, we report a nanocomposite composed of light absorber PbS1−xSex quantum dots (QDs), electron-conducting multiwalled carbon nanotubes (MWCNTs) and hole-conducting poly-3-hexylthiophene (P3HT) with tunable photoelectric conversion performance. In addition to using the quantization effect, we proposed solid-solution PbS1−xSex QDs (x = 0, 0.25, 0.5, 0.75, 1) for band gap engineering. In particular, we successfully synthesized relatively small (~5.3 nm) and uniform QDs via the hot-injection method by using PbCl2, S/Se powder and environmentally friendly oleylamine (OLA) as the precursors and/or solvent. By increasing the content of Se, the band gap of PbS1−xSex QDs decreased along with the decrease in the conduction band and valence band edges. The suitable energy level alignment enabled the efficient transfer of photoinduced charge carriers, and hence a much higher photoelectric conversion performance of the PbS1−xSex-QD@MWCNT/P3HT nanocomposites than the individual QDs, P3HT, and binary PbS1−xSex-QD@MWCNT, as well as the best performance, was achieved over PbS0.75Se0.25-QD@MWCNT/P3HT.