Synergistic interaction of anions and cations in preparation of VPO catalysts promoted by polyoxometalate-ionic liquids

2019 ◽  
Vol 582 ◽  
pp. 117106 ◽  
Author(s):  
Kang Li ◽  
Bin He ◽  
Jiancai Liu ◽  
Huiling Zhang ◽  
Ruirui Zhang ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Synergistic Interaction ◽  
Vpo Catalysts ◽  
Anions And Cations

Mechanistic Insight toward the Roles of Anions and Cations in the Degradation of Poly (ethylene terephthalate) Catalyzed by Ionic Liquids

2021 ◽  
Author(s):  
Zhaoyang Ju ◽  
Lei Zhou ◽  
Xingmei Lu ◽  
Yao Li ◽  
Xiaoqian Yao ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ionic Liquids ◽  
Ethylene Terephthalate ◽  
High Catalytic Activity ◽  
Mechanistic Insight ◽  
Poly Ethylene Terephthalate ◽  
Anions And Cations ◽  
Poly Ethylene

Ionic liquids (ILs) have shown high catalytic activity in the degradation of poly (ethylene terephthalate) (PET), but the effects of anions and cations as well as the mechanism remain ambiguous....

Synthesis of vanadium phosphorus oxide catalysts promoted by iron-based ionic liquids and their catalytic performance in selective oxidation ofn-butane

2018 ◽  
Vol 8 (17) ◽  
pp. 4515-4525 ◽  
Author(s):  
Fei Dai ◽  
Zihang Li ◽  
Xuejing Chen ◽  
Bin He ◽  
Ruixia Liu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Selective Oxidation ◽  
Catalytic Performance ◽  
Oxide Catalysts ◽  
Phosphorus Oxide ◽  
Vpo Catalysts ◽  
Vanadium Phosphorus Oxide ◽  
Iron Based

Catalytic performance of undoped and Fe-doped VPO catalysts.

Synergistic corrosion inhibition effect of thiazolyl-based ionic liquids between anions and cations for copper in HCl solution

2019 ◽  
Vol 483 ◽  
pp. 901-911 ◽  
Author(s):  
Li Feng ◽  
Shengtao Zhang ◽  
Yao Lu ◽  
Bochuan Tan ◽  
Shijin Chen ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Corrosion Inhibition ◽  
Inhibition Effect ◽  
Anions And Cations ◽  
Hcl Solution

Structural Effects of Anions and Cations on the Aggregation Behavior of Ionic Liquids in Aqueous Solutions

2008 ◽  
Vol 112 (51) ◽  
pp. 16682-16689 ◽  
Author(s):  
Huiyong Wang ◽  
Jianji Wang ◽  
Shibiao Zhang ◽  
Xiaopeng Xuan
Keyword(s):  
Ionic Liquids ◽  
Aqueous Solutions ◽  
Aggregation Behavior ◽  
Structural Effects ◽  
Anions And Cations

scholarly journals Discovering Low Toxicity Ionic Liquids for Saccharomyces cerevisiae by Using the Agar Well Diffusion Test

Processes ◽  
2020 ◽  
Vol 8 (9) ◽  
pp. 1163 ◽  
Author(s):  
Fatiha Missoun ◽  
Antonia Pérez de los Ríos ◽  
Víctor Ortiz-Martínez ◽  
María José Salar-García ◽  
Jesús Hernández-Fernández ◽  
...  
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Ionic Liquids ◽  
Alkyl Chain ◽  
Biotechnological Applications ◽  
Diffusion Test ◽  
Preliminary Screening ◽  
Low Toxicity ◽  
Anions And Cations ◽  
Enormous Number ◽  
Cation Nature

Ionic liquids (ILs) are new solvents widely used in many technologies due to their unique and advantageous physicochemical properties. In biotechnological applications, ILs can be used along with microorganisms such as Saccharomyces cerevisiae. Due to the enormous number of ILs that can be synthesized through the combination of different anions and cations, it is necessary to have an easy and quick tool for the preliminary screening of their biocompatibility for being used in biotechnological applications. In this work, the agar well diffusion test was successfully applied as a rapid method to identify toxic/nontoxic ILs toward S. cerevisiae. Sixty-three ILs containing a diverse set of cations and anions were used. Through this methodology, nine fully biocompatible ILs toward S. cerevisiae were identified, including: [Bmim+] [NO3−], [HOPmim+] [NO3−], [Bmim+] [NTf2−], [N8,8,8,1+] [NTf2−], [S2,2,2+] [NTf2−], [EMPyr+] [NTf2−], [BMPi+] [NTf2−], [Moxa+] [MeSO4−] and [Chol+] [H2PO4−]. The analysis of the results also provides preliminary rules to enable the design of biocompatible ILs with S. cerevisiae. In this context, the toxicity was mainly determined by the cation nature although some anions can also display a strong influence on the IL biocompatibility as the bistriflimide anion. Besides, it was observed that an increase in the alkyl chain length of cations, such as imidazolium or pyridinium, involves an increase in the IL toxicity.

On the different roles of anions and cations in the solvation of enzymes in ionic liquids

2011 ◽  
Vol 13 (4) ◽  
pp. 1649-1662 ◽  
Author(s):  
Marco Klähn ◽  
Geraldine S. Lim ◽  
Abirami Seduraman ◽  
Ping Wu
Keyword(s):  
Ionic Liquids ◽  
Anions And Cations

Ionic Liquids in Agrochemistry

2020 ◽  
Vol 24 (11) ◽  
pp. 1181-1195 ◽  
Author(s):  
Assel Ten ◽  
Alexey Zazybin ◽  
Darya Zolotareva ◽  
Anuar Dauletbakov ◽  
Khadichahan Rafikova ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Ionic Liquids ◽  
Antimicrobial Agents ◽  
Review Article ◽  
Biologically Active ◽  
Solubility In Water ◽  
Advantages And Disadvantages ◽  
Anions And Cations ◽  
Plant Growth Stimulants ◽  
Active Substances

: In this review article, we present the latest research in the field of ionic liquids containing biologically active anions and cations, their potential application in the field of agrochemistry and agriculture. The article describes examples of the use of ionic liquids as herbicides, fungicides, antimicrobial agents, deterrents and plant growth stimulants. It also indicates the advantages and disadvantages of using ionic liquids, such as their multitasking, toxicity, thermal stability and solubility in water in comparison with commercial chemicals. Readers will find in the article the prospects for the use of ionic liquids in agriculture, as well as the high value of using ILs as multifunctional biologically active substances.

Enhancing thermoelectrochemical properties by tethering ferrocene to the anion or cation of ionic liquids: altered thermodynamics and solubility

2017 ◽  
Vol 19 (35) ◽  
pp. 24255-24263 ◽  
Author(s):  
Leigh Aldous ◽  
Jeffrey J. Black ◽  
Maximo C. Elias ◽  
Bruno Gélinas ◽  
Dominic Rochefort
Keyword(s):  
Ionic Liquids ◽  
Current Theory ◽  
Entropy Changes ◽  
Anions And Cations

The thermoelectrochemistry of ferrocene tethered to anions and cations expands current theory to entropy changes involving zwitterions and adjacent charges.

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