Review and prospects of microporous zeolite catalysts for CO2 photoreduction

2021 ◽  
Vol 23 ◽  
pp. 101042
Author(s):  
An-Ya Lo ◽  
Fariborz Taghipour
Author(s):  
G. McMahon ◽  
T. Malis

As with all techniques which are relatively new and therefore underutilized, diamond knife sectioning in the physical sciences continues to see both developments of the technique and novel applications.Technique Developments Development of specific orientation/embedding procedures for small pieces of awkward shape is exemplified by the work of Bradley et al on large, rather fragile particles of nuclear waste glass. At the same time, the frequent problem of pullout with large particles can be reduced by roughening of the particle surface, and a proven methodology using a commercial coupling agent developed for glasses has been utilized with good results on large zeolite catalysts. The same principle (using acid etches) should work for ceramic fibres or metal wires which may only partially pull out but result in unacceptably thick sections. Researchers from the life sciences continue to develop aspects of embedding media which may be applicable to certain cases in the physical sciences.


2017 ◽  
Vol 68 (1) ◽  
pp. 116-120
Author(s):  
Iuliean Vasile Asaftei ◽  
Neculai Catalin Lungu ◽  
Lucian Mihail Birsa ◽  
Ioan Gabriel Sandu ◽  
Laura Gabriela Sarbu ◽  
...  

The conversion of n-heptanes into aromatic hydrocarbons benzene, toluene and xylenes (BTX), by the chromatographic pulse method in the temperature range of 673 - 823K was performed over the HZSM-5 and Ag-HZSM-5 zeolites modified by ion exchange with AgNO3 aqueous solutions. The catalysts, HZSM-5 (SiO2/Al2O3 = 33.9), and Ag-HZSM-5 (Ag1-HZSM-5 wt. % Ag1.02, Ag2-HZSM-5 wt. % Ag 1.62; and Ag3-HZSM-5 wt. % Ag 2.05 having different acid strength distribution exhibit a conversion and a yield of aromatics depending on temperature and metal content. The yield of aromatic hydrocarbons BTX appreciably increased by incorporating silver cations Ag+ into HZSM-5.


Catalysts ◽  
2015 ◽  
Vol 5 (4) ◽  
pp. 2122-2133 ◽  
Author(s):  
Masakazu Iwamoto ◽  
Ryota Takezawa ◽  
Masao Morimoto

2014 ◽  
Vol 9 ◽  
pp. 139-150 ◽  
Author(s):  
Bambang Heru Susanto ◽  
Mohammad Nasikin ◽  
Sukirno ◽  
Andri Wiyo

2021 ◽  
Vol 19 (1) ◽  
pp. 745-754
Author(s):  
Khoirina Dwi Nugrahaningtyas ◽  
Eddy Heraldy ◽  
Rachmadani ◽  
Yuniawan Hidayat ◽  
Indriana Kartini

Abstract The properties of three types of CoMo/USY catalysts with different synthesized methods have been studied. The sequential and co-impregnation methods followed by activation using calcination and reduction process have been conducted. The properties of the catalysts were examined using Fourier-transform-infrared (FTIR) spectroscopy, X-ray diffraction (XRD) with refinement, and surface area analyzer (SAA). The FTIR spectrum study revealed the enhanced intensity of its Bronsted acid site, and the XRD diffractogram pattern verified the composition of pure metals, oxides, and alloys in the catalyst. The SAA demonstrated the mesoporous features of the catalyst. Scanning electron microscopy showed an irregular particle morphology. Additional analysis using the transmission electron microscopy indicated that the metal has successfully impregnated without damaging the USY structure.


2021 ◽  
Author(s):  
Amit Gautam ◽  
Saddam Sk ◽  
Amritanjali Tiwari ◽  
Moses Abraham Bokinala ◽  
P. Vijayanand ◽  
...  

A highly efficient hybrid ZnCdS-rGO/MoS2 heterostructure is successfully synthesized through a hot injection approach and control loading of rGO/MoS2. The synergism provides an unprecedently high H2-generation rate 193.4 mmol H2...


Author(s):  
Guohua Jing ◽  
Johannes W. Schwank ◽  
Alexander J Hill ◽  
Huawang Zhao ◽  
Lei Ma ◽  
...  

Future emission standards are becoming increasingly stringent. Around 50% of targeted tailpipe emissions are emitted during the cold-start period, mainly due to the ineffectiveness of catalytic converters in the after-treatment...


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