Understanding the transition process of phase change and dehydration reaction of salt hydrate for thermal energy storage

2020 ◽  
Vol 166 ◽  
pp. 114655 ◽  
Author(s):  
T.S. Yan ◽  
T.X. Li ◽  
J.X. Xu ◽  
J.W. Chao
2016 ◽  
Vol 4 (43) ◽  
pp. 16906-16912 ◽  
Author(s):  
Michael Graham ◽  
Elena Shchukina ◽  
Paula Felix De Castro ◽  
Dmitry Shchukin

Nanocapsules containing salt hydrate for latent heat storage were proven to be thermally and chemically stable over 100 cycles.


Author(s):  
Tonny Tabassum Mainul Hasan ◽  
Latifa Begum

This study reports on the unsteady two-dimensional numerical investigations of melting of a paraffin wax (phase change material, PCM) which melts over a temperature range of 8.7oC. The PCM is placed inside a circular concentric horizontal-finned annulus for the storage of thermal energy. The inner tube is fitted with three radially diverging longitudinal fins strategically placed near the bottom part of the annulus to accelerate the melting process there. The developed CFD code used in Tabassum et al., 2018 is extended to incorporate the presence of fins. The numerical results show that the average Nusselt number over the inner tube surface, the total melt fraction, the total stored energy all increased at every time instant in the finned annulus compared to the annulus without fins. This is due to the fact that in the finned annulus, the fins at the lower part of the annulus promotes buoyancy-driven convection as opposed to the slow conduction melting that prevails at the bottom part of the plain annulus. Fins with two different heights have been considered. It is found that by extending the height of the fin to 50% of the annular gap about 33.05% more energy could be stored compared to the bare annulus at the melting time of 82.37 min for the identical operating conditions. The effects of fins with different heights on the temperature and streamfunction distributions are found to be different. The present study can provide some useful guidelines for achieving a better thermal energy storage system.


2021 ◽  
Vol 13 (5) ◽  
pp. 2590
Author(s):  
S. A. M. Mehryan ◽  
Kaamran Raahemifar ◽  
Leila Sasani Gargari ◽  
Ahmad Hajjar ◽  
Mohamad El Kadri ◽  
...  

A Nano-Encapsulated Phase-Change Material (NEPCM) suspension is made of nanoparticles containing a Phase Change Material in their core and dispersed in a fluid. These particles can contribute to thermal energy storage and heat transfer by their latent heat of phase change as moving with the host fluid. Thus, such novel nanoliquids are promising for applications in waste heat recovery and thermal energy storage systems. In the present research, the mixed convection of NEPCM suspensions was addressed in a wavy wall cavity containing a rotating solid cylinder. As the nanoparticles move with the liquid, they undergo a phase change and transfer the latent heat. The phase change of nanoparticles was considered as temperature-dependent heat capacity. The governing equations of mass, momentum, and energy conservation were presented as partial differential equations. Then, the governing equations were converted to a non-dimensional form to generalize the solution, and solved by the finite element method. The influence of control parameters such as volume concentration of nanoparticles, fusion temperature of nanoparticles, Stefan number, wall undulations number, and as well as the cylinder size, angular rotation, and thermal conductivities was addressed on the heat transfer in the enclosure. The wall undulation number induces a remarkable change in the Nusselt number. There are optimum fusion temperatures for nanoparticles, which could maximize the heat transfer rate. The increase of the latent heat of nanoparticles (a decline of Stefan number) boosts the heat transfer advantage of employing the phase change particles.


2021 ◽  
Vol 11 (13) ◽  
pp. 6234
Author(s):  
Ciprian Neagoe ◽  
Ioan Albert Tudor ◽  
Cristina Florentina Ciobota ◽  
Cristian Bogdanescu ◽  
Paul Stanciu ◽  
...  

Microencapsulation of sodium nitrate (NaNO3) as phase change material for high temperature thermal energy storage aims to reduce costs related to metal corrosion in storage tanks. The goal of this work was to test in a prototype thermal energy storage tank (16.7 L internal volume) the thermal properties of NaNO3 microencapsulated in zinc oxide shells, and estimate the potential of NaNO3–ZnO microcapsules for thermal storage applications. A fast and scalable microencapsulation procedure was developed, a flow calorimetry method was adapted, and a template document created to perform tank thermal transfer simulation by the finite element method (FEM) was set in Microsoft Excel. Differential scanning calorimetry (DSC) and transient plane source (TPS) methods were used to measure, in small samples, the temperature dependency of melting/solidification heat, specific heat, and thermal conductivity of the NaNO3–ZnO microcapsules. Scanning electron microscopy (SEM) and chemical analysis demonstrated the stability of microcapsules over multiple tank charge–discharge cycles. The energy stored as latent heat is available for a temperature interval from 303 to 285 °C, corresponding to onset–offset for NaNO3 solidification. Charge–self-discharge experiments on the pilot tank showed that the amount of thermal energy stored in this interval largely corresponds to the NaNO3 content of the microcapsules; the high temperature energy density of microcapsules is estimated in the range from 145 to 179 MJ/m3. Comparison between real tank experiments and FEM simulations demonstrated that DSC and TPS laboratory measurements on microcapsule thermal properties may reliably be used to design applications for thermal energy storage.


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