Fabrication of hierarchical porous hollow carbon spheres with few-layer graphene framework and high electrochemical activity for supercapacitor

2018 ◽  
Vol 443 ◽  
pp. 367-373 ◽  
Author(s):  
Jing Chen ◽  
Min Hong ◽  
Jiafu Chen ◽  
Tianzhao Hu ◽  
Qun Xu
2021 ◽  
Vol 506 ◽  
pp. 230170
Author(s):  
Lantao Liu ◽  
Xiangyu Sun ◽  
Yue Dong ◽  
Dengke Wang ◽  
Zheng Wang ◽  
...  

2014 ◽  
Vol 2 (15) ◽  
pp. 5352-5357 ◽  
Author(s):  
Jinpeng Han ◽  
Guiyin Xu ◽  
Bing Ding ◽  
Jin Pan ◽  
Hui Dou ◽  
...  

The porous nitrogen-doped hollow carbon spheres derived from polyaniline are promising electrode materials for high performance supercapacitors due to their hierarchical porous structure and nitrogen-doping.


2019 ◽  
Vol 29 (32) ◽  
pp. 1903496 ◽  
Author(s):  
Daping Qiu ◽  
Jingyu Guan ◽  
Min Li ◽  
Cuihua Kang ◽  
Jinying Wei ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (20) ◽  
pp. 16141-16149 ◽  
Author(s):  
Min Hong ◽  
Jiafu Chen ◽  
Minxin Zhang ◽  
Xin Huang ◽  
Qun Xu

Discrete, uniform HCSs with hierarchical porous shell are fabricated by “secondary-crosslinking pyrolysis”, showing high specific capacitance of 192 F g−1.


2018 ◽  
Vol 10 (51) ◽  
pp. 44483-44493 ◽  
Author(s):  
Daping Qiu ◽  
Ang Gao ◽  
Zhenyu Xie ◽  
Lun Zheng ◽  
Cuihua Kang ◽  
...  

MRS Advances ◽  
2020 ◽  
Vol 5 (57-58) ◽  
pp. 2961-2972
Author(s):  
P.C. Meléndez-González ◽  
E. Garza-Duran ◽  
J.C. Martínez-Loyola ◽  
P. Quintana-Owen ◽  
I.L. Alonso-Lemus ◽  
...  

In this work, low-Pt content nanocatalysts (≈ 5 wt. %) supported on Hollow Carbon Spheres (HCS) were synthesized by two routes: i) colloidal conventional polyol, and ii) surfactant-free Bromide Anion Exchange (BAE). The nanocatalysts were labelled as Pt/HCS-P and Pt/HCS-B for polyol and BAE, respectively. The physicochemical characterization of the nanocatalysts showed that by following both methods, a good control of chemical composition was achieved, obtaining in addition well dispersed nanoparticles of less than 3 nm TEM average particle size (d) on the HCS. Pt/HCS-B contained more Pt0 species than Pt/HCS-P, an effect of the synthesis method. In addition, the structure of the HCS remains more ordered after BAE synthesis, compared to polyol. Regarding the catalytic activity for the Oxygen Reduction Reaction (ORR) in 0.5 M KOH, Pt/HCS-P and Pt/HCS-B showed a similar performance in terms of current density (j) at 0.9 V vs. RHE than the benchmark commercial 20 wt. % Pt/C. However, Pt/HCS-P and Pt/HCS-B demonstrated a 6 and 5-fold increase in mass catalytic activity compared to Pt/C, respectively. A positive effect of the high specific surface area of the HCS and its interactions with metal nanoparticles and electrolyte, which promoted the mass transfer, increased the performance of Pt/HCS-P and Pt/HCS-B. The high catalytic activity showed by Pt/HCS-B and Pt/HCS-P for the ORR, even with a low-Pt content, make them promising cathode nanocatalysts for Anion Exchange Membrane Fuel Cells (AEMFC).


2020 ◽  
Vol 35 (6) ◽  
pp. 630-645
Author(s):  
Jia-ying Yang ◽  
Hao-jie Han ◽  
Hlib Repich ◽  
Ri-cheng Zhi ◽  
Chang-zhen Qu ◽  
...  

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