scholarly journals Environment-friendly green chemistry approaches for an efficient synthesis of 1-amidoalkyl-2-naphthols catalyzed by tannic acid

2018 ◽  
Vol 11 (1) ◽  
pp. 91-98 ◽  
Author(s):  
Rajesh K. Singh ◽  
Robita Duvedi
Author(s):  
Prasad Panchabhai ◽  
Neelakandan Kaliaperumal ◽  
Gopalakrishnan Mannathusamy ◽  
Anbuselvan Chinnadurai

The article confers a scalable manufacturing process of Fenspiride HCl. 4-aminomethyl-1-(2-phenylethyl)-piperidin-4-ol is the main building block in Fenspiride HCl synthesis. The reported reagents for 4-aminomethyl-1-(2-phenylethyl)-piperidin-4-ol synthesis are costly, explosive, highly toxic, produce hazardous waste, and also need to be handled with most care. The paper introduces aqueous ammonia as an alternate reagent in Fenspiride HCl and used in 4-aminomethyl-1-(2-phenylethyl)-piperidin-4-ol synthesis. The new green chemistry aspect makes the process environment-friendly and cheaper. It also eliminates toxic, sensitive, and hazardous reagents and makes the process safe on uncomplicated on bulk scale production. The high pure Fenspiride HCl is obtained by following this process and meets the ICH limits with good yield.


2019 ◽  
Vol 64 (8) ◽  
pp. 645-650
Author(s):  
Davood SHEIKH ◽  
◽  
Ali VARASTEH MORADI ◽  
Zahra HEKMATIAN ◽  
◽  
...  

2013 ◽  
Vol 667 ◽  
pp. 251-254 ◽  
Author(s):  
Ropisah Mie ◽  
Mohd Wahid Samsudin ◽  
Laily B. Din

The development of reliable and eco-friendly metallic nanoparticles needs some consideration on the chemical procedures involved in the synthesis of nanomaterials. The conventional methods in the production of metallic nanoparticles generate a large amount of hazardous byproducts. Thus, there is a need for ‘green chemistry’ that includes a clean, nontoxic and environment-friendly method of nanoparticle synthesis [1]. As an alternative, biological methods are considered safe and ecologically sound for the nanomaterial fabrication [2]. Therefore, in this review special attention is focused on the biosynthesis of nanoparticles from natural resources as compared as ordinary chemical method. Biosynthesis of nanoparticles using plant is a new development of green nanotechnology beneficial to environmental and to the plant itself. It also plays a significant role in the field of biology and medicine.


2010 ◽  
Vol 2 (2) ◽  
pp. 322-329 ◽  
Author(s):  
M. M. Hossain ◽  
M. A. Foysal ◽  
M. Mahabub ◽  
Al- Amin

MW-assisted treatment of oximinoacetanilides obtained from substituted primary aromatic amines was carried out in conc. H2SO4 medium for 5-10 sec to give cyclic amides (isatins) through intramolecular cyclization by means of electrophilic aromatic substitution. Isatins reacted with thiosemicarbazide under MW-condition gave the corresponding Schiff-bases. The Schiff-bases undergo cyclization in presence of minimal Ac2O under MW-irradiation for 3-4 min to give the spiro-thiadiazoline acetyl derivatives in excellent yield. Keywords:  Microwave-synthesis; Isatins; Schiff-base; spiro-Thiadiazoline; Green chemistry. © 2010 JSR Publications. ISSN: 2070-0237 (Print); 2070-0245 (Online). All rights reserved.  DOI: 10.3329/jsr.v2i2.3731               J. Sci. Res. 2 (2), 322-329 (2010)  


RSC Advances ◽  
2017 ◽  
Vol 7 (87) ◽  
pp. 55206-55214 ◽  
Author(s):  
Jimmy Nelson Appaturi ◽  
Mohd Rafie Johan ◽  
R. Jothi Ramalingam ◽  
Hamad A. Al-Lohedan ◽  
J. Judith Vijaya

Here we describe the synthesis of butyl levulinate by alcoholysis of furfuryl alcohol with n-butanol over a series of titanium incorporated mesoporous KIT-6 molecular sieve catalysts prepared by a simple sol–gel treatment.


2021 ◽  
Author(s):  
Yaning Xu ◽  
Fengxi Li ◽  
Nan Zhao ◽  
Jiali Su ◽  
Chunyu Wang ◽  
...  

In this work, an environment-friendly and efficient artificial Vitreoscilla hemoglobin (VHb) for the synthesis of 2-aminobenzoxazoles and 2-aminobenzothiazoles has been reported. We demonstrate an expression-based porphyrin substitution strategy to produce...


2021 ◽  
Vol 25 ◽  
Author(s):  
Yogesh Brijwashi Sharma ◽  
Bhakti Umesh Hirlekar ◽  
Yogesh P. Bharitkar ◽  
Abhijit Hazra

Green chemistry is an essential part of the chemistry for the organic synthesis and also plays a principal role to save the environment from the harmful and toxic catalysts. Fruit juice catalyzed chemistry is a vital part of green chemistry in which lemon juice play a potential role in a various organic transformations. This review article has been summarized (from 2011-2020) with the application and importance of lemon juice in synthetic organic transformation as well as synthesis of various type of nanoparticles and catalysts. This review article can help the researcher to develop the route for the synthesis of various scaffolds, small molecules, nanoparticles and catalysts under economical and environment friendly condition.


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