ZnAl2O4 as a novel high-surface-area ozonation catalyst: One-step green synthesis, catalytic performance and mechanism

2015 ◽  
Vol 260 ◽  
pp. 623-630 ◽  
Author(s):  
Hui Zhao ◽  
Yuming Dong ◽  
Pingping Jiang ◽  
Guangli Wang ◽  
Jingjing Zhang ◽  
...  
Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3602 ◽  
Author(s):  
Neel Narayan ◽  
Ashokkumar Meiyazhagan ◽  
Robert Vajtai

Nanoparticles play a significant role in various fields ranging from electronics to composite materials development. Among them, metal nanoparticles have attracted much attention in recent decades due to their high surface area, selectivity, tunable morphologies, and remarkable catalytic activity. In this review, we discuss various possibilities for the synthesis of different metal nanoparticles; specifically, we address some of the green synthesis approaches. In the second part of the paper, we review the catalytic performance of the most commonly used metal nanoparticles and we explore a few roadblocks to the commercialization of the developed metal nanoparticles as efficient catalysts.


2010 ◽  
Vol 20 (11) ◽  
pp. 2092 ◽  
Author(s):  
Shu-Lei Chou ◽  
Jia-Zhao Wang ◽  
David Wexler ◽  
Konstantin Konstantinov ◽  
Chao Zhong ◽  
...  

2003 ◽  
Vol 788 ◽  
Author(s):  
A. Akash ◽  
B. Nair ◽  
K. Minnick ◽  
M. Wilson ◽  
J. Hartvigsen

ABSTRACTA novel nano-ceramic material, called HSA-CERCANAM®, which has a very high surface area with a nanopore network has been developed. HSA-CERCANAM® can be casted in various shapes and forms resulting in a monolithic piece that has surface area as high as 80–100 m2/g. The surface area and the nanopore network of HSA-CERCANAM® remains stable at temperatures as high as 1000°C. Furthermore, the unique nature of HSA-CERCANAM® allows it to be casted on and around features, either sacrificial or permanent. Using sacrificial features, microchannels can be incorporated internally into the monolithic HSA-CERCANAM® piece in a simple, one-step process. Further, this monolithic ceramic component, which has an intrinsically high surface area and a nanopore network, can be infiltrated with a desired catalyst. This could offer clear technological advantages over currently available microreactors. The surface area, porosity, catalyst type and infiltration levels are some of the ways in which tailored microstructures can be realized in components such as mixers, heat exchangers, extractors, filters or reaction chambers thereby leading to highly efficient, multi-functional ceramic micro-devices.


2020 ◽  
Vol 8 (35) ◽  
pp. 18318-18326 ◽  
Author(s):  
Hailong Peng ◽  
Yangcenzi Xie ◽  
Zicheng Xie ◽  
Yunfeng Wu ◽  
Wenkun Zhu ◽  
...  

Porous high entropy alloy CrMnFeCoNi exhibited remarkable catalytic activity and stability toward p-nitrophenol hydrogenation. The enhanced catalytic performance not only resulted from the high surface area, but also from exposed high-index facets with terraces.


2013 ◽  
Vol 662 ◽  
pp. 202-206
Author(s):  
Jia Feng Wu ◽  
Yu Mei Zhao ◽  
Peng Liang

A series of nano-sized iron oxide supported on 3D wormlike hierarchical mesoporous SiO2 catalysts were synthesized by one-step hydrothermal synthesis. The samples were characterized by XRD, N2 sorption, FT-IR, UV–Vis, TEM and ICP-AES. The catalysts were probed for the oxidation of phenol employing hydrogen peroxide. The results indicate that the materials exhibit high surface area and 3D wormlike hierarchical pore, iron ions exist as isolated framework species when the weight percentage content of iron is below 0.24 and nano-size iron oxide is dispersed in the surface (iron content above 0.24 wt%). Catalytic performance indicates that nano-size iron oxide supported on SiO2 is useful to enhance both the catalytic activity and the selectivity of target products compared with isolated iron species.


RSC Advances ◽  
2014 ◽  
Vol 4 (93) ◽  
pp. 51184-51193 ◽  
Author(s):  
Qing Zhang ◽  
Tao Wu ◽  
Peng Zhang ◽  
Ruijuan Qi ◽  
Rong Huang ◽  
...  

Hierarchical Ni/Al2O3 nanocomposite possesses a high surface area, high loading of well dispersed metal nanoparticles, and a hierarchical hollow structure. The strong interaction between metal and support and the large open accessible surface lead to excellent sintering and carbon resistance, and superior catalytic performance in methane dry reforming.


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