Synergetic effect of UiO-66 and plasmonic AgNPs on PET waste support towards degradation of nerve agent simulant

Abstract To exploit the potential of ecological intensification during sunflower cropping, it is crucial to understand the potential synergies between crop management and ecosystem services. We therefore examined the effect of pollination intensification on sunflower yield and productivity under various levels of soil fertilization over two seasons in the eastern Free State, South Africa. We manipulated soil fertility with fertilizer applications and pollination with exclusion bags. We found a synergetic effect between pollination and soil fertilization whereby increasing pollination intensity led to a far higher impact on sunflower yield when the soil had been fertilized. Specifically, the intensification of insect pollination increased seed yield by approximately 0.4 ton/ha on nutrient poor soil and by approximately 1.7 ton/ha on moderately fertilized soil. Our findings suggest that sunflower crops on adequate balanced soil fertility will receive abundant insect pollination and may gain more from both synergies than crops grown in areas with degraded soil fertility.

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Influence of HAP on the Morpho-Structural Properties and Corrosion Resistance of ZrO2-Based Composites for Biomedical Applications

Crystals ◽

10.3390/cryst11020202 ◽

2021 ◽

Vol 11 (2) ◽

pp. 202

Author(s):

Réka Barabás ◽

Carmen Ioana Fort ◽

Graziella Liana Turdean ◽

Liliana Bizo

Keyword(s):

Electrochemical Impedance ◽

Artificial Saliva ◽

Synergetic Effect ◽

Composite Layer ◽

Charge Transfer Resistance ◽

Processing Route ◽

Dental Alloys ◽

Metallic Electrode ◽

Transfer Resistance ◽

X Ray

In the present work, ZrO2-based composites were prepared by adding different amounts of antibacterial magnesium oxide and bioactive and biocompatible hydroxyapatite (HAP) to the inert zirconia. The composites were synthesized by the conventional ceramic processing route and morpho-structurally analyzed by X-ray powder diffraction (XRPD) and scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS). Two metallic dental alloys (i.e., Ni–Cr and Co–Cr) coated with a chitosan (Chit) membrane containing the prepared composites were exposed to aerated artificial saliva solutions of different pHs (i.e., 4.3, 5, 6) and the corrosion resistances were investigated by electrochemical impedance spectroscopy technique. The obtained results using the two investigated metallic dental alloys shown quasi-similar anticorrosive properties, having quasi-similar charge transfer resistance, when coated with different ZrO2-based composites. This behavior could be explained by the synergetic effect between the diffusion process through the Chit-composite layer and the roughness of the metallic electrode surface.

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Adaptive Neuro-Fuzzy Inference System for Modelling the Effect of Slurry Impacts on PLA Material Processed by FDM

Polymers ◽

10.3390/polym13010118 ◽

2020 ◽

Vol 13 (1) ◽

pp. 118

Author(s):

Bahaa Saleh ◽

Ibrahem Maher ◽

Yasser Abdelrhman ◽

Mahmoud Heshmat ◽

Osama Abdelaal

Keyword(s):

Weight Gain ◽

Fused Deposition Modeling ◽

Synergetic Effect ◽

Solid Particles ◽

Percentage Error ◽

Inference System ◽

Average Percentage ◽

Fused Deposition ◽

Effect Of Water ◽

Neuro Fuzzy

In this research, the effect of water-silica slurry impacts on polylactic acid (PLA) processed by fused deposition modeling (FDM) is examined under different conditions with the assistance of an adaptive neuro-fuzzy interference system (ANFIS). Building orientation, layer thickness, and slurry impact angle are considered as the controllable variables. Weight gain resulting from water, net weight gain, and total weight gain are the predicting variables. Results uncover the accomplishment of the ANFIS model to appropriately appraise slurry erosion in correlation with comparing real data. Both experimental and ANFIS results are almost identical with average percentage error less than 5.45 × 10−6. We observed during the slurry impacts tests that all specimens showed an increase in their weights. This weight gain was finally interpreted to the synergetic effect of water absorption and the solid particles fragmentations immersed within the specimens due to the successive slurry impacts.

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