Cobalt carbonate hydroxide hydrate nanowire array modified by sulfur doping for aqueous asymmetric supercapacitors

2021 ◽  
pp. 133776
Author(s):  
Ting Xiao ◽  
Zhixin Wang ◽  
Tao Jiang ◽  
Yushuai Yao ◽  
Lihua Jiang ◽  
...  
Keyword(s):  
Nanowire Array ◽  
Asymmetric Supercapacitors ◽  
Cobalt Carbonate ◽  
Sulfur Doping ◽  
Carbonate Hydroxide ◽  
Hydroxide Hydrate

scholarly journals Facile Synthesis of Carbon Cloth Supported Cobalt Carbonate Hydroxide Hydrate Nanoarrays for Highly Efficient Oxygen Evolution Reaction

2021 ◽  
Vol 9 ◽  
Author(s):  
Yubing Yan
Keyword(s):  
Electron Microscopy ◽  
Oxygen Evolution ◽  
Current Density ◽  
Oxygen Evolution Reaction ◽  
Active Sites ◽  
Carbon Cloth ◽  
High Porosity ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Hydroxide Hydrate

Developing efficient and low-cost replacements for noble metals as electrocatalysts for the oxygen evolution reaction (OER) remain a great challenge. Herein, we report a needle-like cobalt carbonate hydroxide hydrate (Co(CO3)0.5OH·0.11H2O) nanoarrays, which in situ grown on the surface of carbon cloth through a facile one-step hydrothermal method. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) characterizations demonstrate that the Co(CO3)0.5OH nanoarrays with high porosity is composed of numerous one-dimensional (1D) nanoneedles. Owing to unique needle-like array structure and abundant exposed active sites, the Co(CO3)0.5OH@CC only requires 317 mV of overpotential to reach a current density of 10 mA cm−2, which is much lower than those of Co(OH)2@CC (378 mV), CoCO3@CC (465 mV) and RuO2@CC (380 mV). For the stability, there is no significant attenuation of current density after continuous operation 27 h. This work paves a facile way to the design and construction of electrocatalysts for the OER.

Flexible coaxial fiber-shaped asymmetric supercapacitors based on manganese, nickel co-substituted cobalt carbonate hydroxides

2020 ◽  
Vol 8 (4) ◽  
pp. 1837-1848 ◽  
Author(s):  
Xueying Cao ◽  
Ying Liu ◽  
Yuxue Zhong ◽  
Liang Cui ◽  
Aitang Zhang ◽  
...  
Keyword(s):  
Carbon Fibers ◽  
Electrochemical Performances ◽  
Asymmetric Supercapacitor ◽  
Asymmetric Supercapacitors ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide

A wearable coaxial fiber-shaped asymmetric supercapacitor based on well-aligned Mn, Ni co-substituted Co carbonate hydroxide nanoneedle arrays on carbon fibers is successfully fabricated, and it exhibits excellent electrochemical performances.

scholarly journals Simple Synthesis of Cobalt Carbonate Hydroxide Hydrate and Reduced Graphene Oxide Hybrid Structure for High-Performance Room Temperature NH3 Sensor

Sensors ◽  
2019 ◽  
Vol 19 (3) ◽  
pp. 615 ◽  
Author(s):  
Chang Wang ◽  
Huan Wang ◽  
Dan Zhao ◽  
Xianqi Wei ◽  
Xin Li ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Gas Sensor ◽  
Room Temperature ◽  
Gas Sensing ◽  
Hybrid Structure ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Reduced Graphene ◽  
Hydroxide Hydrate

A novel hybrid structure sensor based on cobalt carbonate hydroxide hydrate (CCHH) and reduced graphene oxide (RGO) was designed for room temperature NH3 detection. This hybrid structure consisted of CCHH and RGO (synthesized by a one-step hydrothermal method), in which RGO uniformly dispersed in CCHH, being used as the gas sensing film. The resistivity of the hybrid structure was highly sensitive to the changes on NH3 concentration. CCHH in the hybrid structure was the sensing material and RGO was the conductive channel material. The hybrid structure could improve signal-to-noise ratio (SNR) and the sensitivity by obtaining the optimal mass proportion of RGO, since the proportion of RGO was directly related to sensitivity. The gas sensor with 0.4 wt% RGO showed the highest gas sensing response reach to 9% to 1 ppm NH3. Compared to a conventional gas sensor, the proposed sensor not only showed high gas sensing response at room temperature but also was easy to achieve large-scale production due to the good stability and simple synthesis process.

Boosted Oxygen Evolution Reactivity via Atomic Iron Doping in Cobalt Carbonate Hydroxide Hydrate

2020 ◽  
Vol 12 (36) ◽  
pp. 40220-40228
Author(s):  
Shan Zhang ◽  
Bolong Huang ◽  
Liguang Wang ◽  
Xiaoyan Zhang ◽  
Haishuang Zhu ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Iron Doping ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Hydroxide Hydrate

Precisely tailoring ZIF-67 nanostructures from cobalt carbonate hydroxide nanowire arrays: toward high-performance battery-type electrodes

2015 ◽  
Vol 3 (32) ◽  
pp. 16688-16694 ◽  
Author(s):  
Dongbo Yu ◽  
Liang Ge ◽  
Bin Wu ◽  
Liang Wu ◽  
Huanting Wang ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
High Performance ◽  
Nanowire Array ◽  
Nanowire Arrays ◽  
Nanotube Array ◽  
Unique Structure ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Facile Transformation

A facile transformation of a cobalt carbonate hydroxide nanowire array to a ZIF-67-based nanotube array was achieved, and the ZIF-67-derived mesoporous Co3O4 nanotube array exhibited remarkable electrochemical performance as a battery-type electrode due to its unique structure.

Cubic Nanostructures of Nickel–Cobalt Carbonate Hydroxide Hydrate as a High-Performance Oxygen Evolution Reaction Electrocatalyst in Alkaline and Near-Neutral Media

2020 ◽  
Vol 59 (22) ◽  
pp. 16690-16702 ◽  
Author(s):  
Kannimuthu Karthick ◽  
Sugumar Subhashini ◽  
Rishabh Kumar ◽  
Sridhar Sethuram Markandaraj ◽  
Muthukumar Muthu Teepikha ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Cobalt Carbonate ◽  
Nickel Cobalt ◽  
Carbonate Hydroxide ◽  
Neutral Media ◽  
Hydroxide Hydrate

Controllable fabrication of urchin-like Co3O4 hollow spheres for high-performance supercapacitors and lithium-ion batteries

2016 ◽  
Vol 45 (38) ◽  
pp. 15155-15161 ◽  
Author(s):  
Fashen Chen ◽  
Xiaohe Liu ◽  
Zhian Zhang ◽  
Ning Zhang ◽  
Anqiang Pan ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Hydrothermal Synthesis ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Hollow Spheres ◽  
Lithium Ion ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Controllable Fabrication ◽  
Hydroxide Hydrate

Urchin-like cobalt oxide (Co3O4) hollow spheres can be successfully prepared by thermal decomposition of cobalt carbonate hydroxide hydrate (Co(CO3)0.5(OH)·0.11H2O) obtained by template-assisted hydrothermal synthesis.

ChemInform Abstract: Preparation and X-Ray Diffraction Characterization of the Kambaldaite- Like Sodium Cobalt Carbonate Hydroxide Hydrate, Na2Co8(CO3)6(OH)6. times.6 H2O.

ChemInform ◽  
2010 ◽  
Vol 26 (11) ◽  
pp. no-no
Author(s):  
K. PETROV ◽  
E. MIRTCHEVA ◽  
J. L. MARTIN DE VIDALES ◽  
R. ROJAS ◽  
O. GARCIA-MARTINEZ
Keyword(s):  
X Ray Diffraction ◽  
X Ray ◽  
Cobalt Carbonate ◽  
Carbonate Hydroxide ◽  
Hydroxide Hydrate
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