Effects of zinc salt addition on perfluorooctanoic acid (PFOA) removal by electrocoagulation with aluminum electrodes

Chemosphere ◽  
2021 ◽  
pp. 132665
Author(s):  
Yueh-Feng Li ◽  
Ching-Yao Hu ◽  
Yu-Chi Lee ◽  
Shang-Lien Lo
1960 ◽  
Vol 23 ◽  
pp. 390-395 ◽  
Author(s):  
W MACNEVIN ◽  
R WILSON

Author(s):  
Semeleva E.V. ◽  
Blinova E.V. ◽  
Zaborovsky A.V. ◽  
Vasilkina O.V. ◽  
Shukurov A.S.

In this work, we studied the pharmacological activity of zinc and magnesium salts of 2-aminoethanesulfonic acid in white non-linear male rats with amyotrophic lateral sclerosis, which was modeled by neurotoxicantsimplication into the pelvic part of spinal cord. After the reproduction of the pathology in animals, the indices of motor activity were recorded in the Rotarod test, and morphological studies of spinal cord sections stained according to Nisl in the Belshovsky modification were carried out. It was shown that the magnesium salt of 2-aminoethanesulfonic acid (compound LHT-317) to a greater extent reduces the development of motor disorders in experimental animals compared with the control group on the 4th day of observation. The course of intravenous administration of the studied compounds of 2-aminoethanesulfonic acid did not inhibit morphological changes in the spinal cord that develop in degenerative-dystrophic pathology of the central nervous system: connections. Moreover, if, against the background of treatment with zinc salt, the total area of motor zones in animals of the experimental group exceeded that of control rats, then the number of motoneurons did not differ from the control.


Author(s):  
Kh. Kh. Khamidulina ◽  
E. V. Tarasova ◽  
A. S. Proskurina ◽  
A. R. Egiazaryan ◽  
I. V. Zamkova ◽  
...  

Currently, perfluorooctanoic acid (PFOA) has no hygienic standards in the air of the working area and objects of the human environment in the Russian Federation. By the decision of the Stockholm Convention SC-9/12, PFOA, its salts and derivatives are included in Part I of Annex A of the Stockholm Convention on Persistent Organic Pollutants in 2019 (with exceptions for possible use). The Rotterdam Convention on the Prior Informed Consent Procedure for Certain Hazardous Chemicals and Pesticides in International Trade included PFOA, its salts and derivatives in the list of potential candidates for inclusion in Annex III of the Rotterdam Convention at the next meeting COP10 in 2021. The use of this chemical on the territory of the Russian Federation entails water and air pollution. Industrial emissions and waste water from fluoropolymer production, thermal use of materials and products containing polytetrafluoroethylene, biological and atmospheric degradation of fluorotelomer alcohols, waste water from treatment facilities are the sources of the release of PFOA into the environment. Analysis of international databases has showed that PFOA is standardized in the air of the working area in Germany, Japan, and Switzerland. In the countries of the European Union, as well as the USA and Canada, the issue of PFOA standardizing in drinking water is being now actively under discuss. Taking into account the high toxicity and hazard of the substance and the serious concern of the civil society of the Russian Federation, the Federal Service for Supervision of Consumer Rights Protection and Human Wellbeing requested the Russian Register of Potentially Hazardous Chemical and Biological Substances to develop MACs for perfluorooctanoic acid in the air of the working area and water as soon as possible. The MACs for PFOA have been proposed using risk analysis: 0,005 mg/m3, aerosol, hazard class 1 – in the air of the working area and 0,0002 mg/L, the limiting hazard indicator – sanitary-toxicological, hazard class 1 – in the water.


2018 ◽  
Vol 21 (8) ◽  
pp. 583-593 ◽  
Author(s):  
Sara Rahnama ◽  
Shahab Shariati ◽  
Faten Divsar

Objective: In this research, a novel magnetite titanium dioxide nanocomposite functionalized by amine groups (Fe3O4@SiO2@TiO2-NH2) was synthesized and its ability for efficient removal of Acid Fuchsine as an anionic dye from aqueous solutions was investigated. Method: The core-shell structure of Fe3O4@SiO2@TiO2 was prepared using Fe3O4 as magnetic core, tetra ethyl orthosilicate as silica and tetra butyl titanate as titanium source for shell. The synthesized nanocomposites (particle size lower than 44 nm) were characterized by FT-IR, XRD, DRS, SEM and TGA instruments. The various experimental parameters affecting dye removal efficiency were investigated and optimized using Taguchi fractional factorial design. Results: The synthesized adsorbent showed the highest removal efficiency of Acid Fuchsine (99 %) at pH= 3.5, without salt addition and during stirring at contact times less than 10 minutes. The study of kinetic models at two concentration levels showed the fast dye sorption on the surface of proposed nanocomposites with pseudo second order kinetic model (R2=1). Also, the fitting of Acid Fuchsine sorption data to Freundlich, Langmuir and Temkin isotherms suggested that Freundlich model gave a better fitting than other models (R2=0.9936, n=2). Conclusion: Good chemical stability, excellent magnetic properties, very fast adsorption kinetics and high removal efficiency make the synthesized nanocomposite as a proper recoverable sorbent for removal of Acid Fuchsine dye from wastewaters.


Chemosphere ◽  
2021 ◽  
Vol 280 ◽  
pp. 130660
Author(s):  
Sanny Verma ◽  
Bineyam Mezgebe ◽  
Endalkachew Sahle-Demessie ◽  
Mallikarjuna N. Nadagouda

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