Wettability alteration: A comprehensive review of materials/methods and testing the selected ones on heavy-oil containing oil-wet systems

2015 ◽  
Vol 220 ◽  
pp. 54-77 ◽  
Author(s):  
Mohammedalmojtaba Mohammed ◽  
Tayfun Babadagli
2019 ◽  
Vol 141 (7) ◽  
Author(s):  
Yanan Ding ◽  
Sixu Zheng ◽  
Xiaoyan Meng ◽  
Daoyong Yang

In this study, a novel technique of low salinity hot water (LSHW) injection with addition of nanoparticles has been developed to examine the synergistic effects of thermal energy, low salinity water (LSW) flooding, and nanoparticles for enhancing heavy oil recovery, while optimizing the operating parameters for such a hybrid enhanced oil recovery (EOR) method. Experimentally, one-dimensional displacement experiments under different temperatures (17 °C, 45 °C, and 70 °C) and pressures (about 2000–4700 kPa) have been performed, while two types of nanoparticles (i.e., SiO2 and Al2O3) are, respectively, examined as the additive in the LSW. The performance of LSW injection with and without nanoparticles at various temperatures is evaluated, allowing optimization of the timing to initiate LSW injection. The corresponding initial oil saturation, production rate, water cut, ultimate oil recovery, and residual oil saturation profile after each flooding process are continuously monitored and measured under various operating conditions. Compared to conventional water injection, the LSW injection is found to effectively improve heavy oil recovery by 2.4–7.2% as an EOR technique in the presence of nanoparticles. Also, the addition of nanoparticles into the LSHW can promote synergistic effect of thermal energy, wettability alteration, and reduction of interfacial tension (IFT), which improves displacement efficiency and thus enhances oil recovery. It has been experimentally demonstrated that such LSHW injection with the addition of nanoparticles can be optimized to greatly improve oil recovery up to 40.2% in heavy oil reservoirs with low energy consumption. Theoretically, numerical simulation for the different flooding scenarios has been performed to capture the underlying recovery mechanisms by history matching the experimental measurements. It is observed from the tuned relative permeability curves that both LSW and the addition of nanoparticles in LSW are capable of altering the sand surface to more water wet, which confirms wettability alteration as an important EOR mechanism for the application of LSW and nanoparticles in heavy oil recovery in addition to IFT reduction.


SPE Journal ◽  
2014 ◽  
Vol 20 (01) ◽  
pp. 79-87 ◽  
Author(s):  
S.M.. M. Shuwa ◽  
B.Y.. Y. Jibril ◽  
Y.M.. M. Al-Wahaibi ◽  
R.S.. S. Al-Hajri

Summary Because of increasing energy demand, unconventional resources such as heavy oil are being explored and recovered. Enhanced-oil-recovery (EOR) methods such as surfactants and polymer flooding must be optimized and new chemicals must be designed to produce more oil. This paper introduces a new deep eutectic solvent (DES) that is based on choline chloride/ethylene glycol for EOR. As preliminary investigations revealed, different concentrations of DES solutions in brine (0 to 100 vol%) were characterized by measuring density, viscosity, conductivity, surface tension, and refractive index at different temperatures (25 to 55°C). Then, the effects of the DES/brine solutions on emulsification with oil phase, wettability alteration, oil/solvent interfacial tension (IFT), formation damage, and tertiary heavy-oil recovery were studied. Potential of the DES solution on enhancing heavy-oil recovery was explored by use of coreflood experiments. This was performed at reservoir condition (pressure = 1,200 psi, temperature = 45 to 80°C) with Berea sandstone core samples and fluids from the field of interest (formation brine and crude oil). An increase in IFT rather than a decrease was observed between the DES/brine solution and the oil. The spontaneous-water-imbibition tests suggested that a decrease in oil-wetness led to an increase in oil production. Approximately 52% of residual oil after waterflooding was recovered with the DES from the coreflooding. The results show an increase in oil recovery with reservoir temperature (6, 13, and 16% on the basis of initial oil in place at 45, 60 and 80°C, respectively). The interaction of the DES with the core materials did not lead to formation damage, as demonstrated by the permeability measurements of the DES/brine solution before and after injection. Viscous forces and wettability alteration were found to be the dominant mechanisms for the tertiary oil-recovery enhancement.


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