Interfacial assembly and characterization of hybrid ultrathin films of manganese 5,10,15,20-tetra (4-pyridyl) porphine chloride tetrakis (methochloride) and its polymeric derivative with poly (4-vinylpyridine)

2013 ◽  
Vol 423 ◽  
pp. 154-161 ◽  
Author(s):  
Hong-Lei Wang ◽  
Jiang Liu ◽  
Xian-Xiu Zhu ◽  
Meng Chen ◽  
Dong-Jin Qian
Keyword(s):  
Ultrathin Films ◽  
Interfacial Assembly ◽  
Polymeric Derivative

SUPERCONDUCTING PROPERTIES OF BSCCO (2223) ULTRATHIN FILMS

2002 ◽  
Vol 09 (05n06) ◽  
pp. 1757-1760
Author(s):  
L. NAVARRETE ◽  
A. MARIÑO ◽  
H. SÁNCHEZ
Keyword(s):  
Electrical Properties ◽  
Magnetron Sputtering ◽  
Structural Characterization ◽  
Ultrathin Films ◽  
Rf Magnetron Sputtering ◽  
Ex Situ ◽  
Thermal Treatments ◽  
Superconducting Properties

Ultrathin films of (Bi–Pb)–Sr–Ca–Cu–O (2223) were produced by ex situ RF magnetron sputtering on MgO (100) substrates. Films with different thermal treatments and thickness varying between 30 nm and 300 nm were obtained and studied systematically. A structural characterization of these samples was carried out and correlated with their electrical properties and thickness.

Towards the Synthesis of Mono- and Bi-Functional Amphiphilic Oligothiophenes: Organic Materials for Opto-Electronic Applications

1999 ◽  
Vol 561 ◽  
Author(s):  
R.C. Advincula ◽  
S. Inaoka ◽  
M. Park ◽  
D. Phillips ◽  
D.M. Shin
Keyword(s):  
Physical Properties ◽  
Ultrathin Films ◽  
Organic Materials ◽  
Photophysical Properties ◽  
Electronic Devices ◽  
Synthesis And Characterization ◽  
Important Class ◽  
Maldi Tof Ms ◽  
Tof Ms

ABSTRACTIn this report, we describe our initial synthesis and characterization of mono-functional and bi-functional dibromoalkyl oligothiophenes to achieve amphiphilicity and telechelic functionality. Oligothiophenes are an important class of organic materials for opto-electronic devices and display applications. We have mono-functionalized oligothiophenes by the synthesis of a quinquethiophene bromoalkyl derivative. A bi-functional sexithiophene was derived primarily by the symmetrical coupling of terthiophene derivatives. Both were synthesized using Grignard coupling and lithiation reaction methodologies. UV-Vis, IR, NMR, MALDI-TOF-MS, and DSC confirmed the structure and physical properties of the oligomers. In addition, we have also synthesized an amphiphilic diamine derivative from the reaction of hexamethylenediamine with a bromoalkyl terthiophene derivative. Using photoluminescence, the photophysical properties of the oligomers were found to be that of typical oligothiophenes. Processing as ultrathin films for devices is currently being investigated.

Structural Characterization of Thin Metal Overlayers by X-ray Photoelectron and Auger-Electron Forward Scattering

1986 ◽  
Vol 83 ◽  
Author(s):  
W. F. Egelhoff
Keyword(s):  
Ultrathin Films ◽  
Surface Segregation ◽  
Metal Films ◽  
Epitaxial Films ◽  
Forward Scattering ◽  
Crystalline Lattice ◽  
Auger Electrons ◽  
X Ray ◽  
Metal Overlayers

ABSTRACTForward scattering of XPS and Auger electrons by atoms in a crystalline lattice produce beams of enhanced intensity radiating out from the surface at angles corresponding to the internuclear axes present in the top few atomic layers. This effect has been applied to analyze the mechanism of surface segregation in ultrathin metal films, to analyze the interdiffusion at the interfaces of ultrathin films, and to assess the effects of substrate contamination on the growth of epitaxial films. The systems studied in this work are Cu, Ni, and Co on Ni(100), however the purpose of this work is not to investigate these particular systems but to use them to illustrate the capabilities of forward scattering.

The optical characterization of metal-mediated aggregation behaviour of amphiphilic Zn(ii) phthalocyanines

2016 ◽  
Vol 18 (23) ◽  
pp. 15574-15583 ◽  
Author(s):  
P. Batat ◽  
M. Bayar ◽  
B. Pur ◽  
E. Çoker ◽  
V. Ahsen ◽  
...  
Keyword(s):  
Ultrathin Films ◽  
Optical Characterization ◽  
Aggregation Behaviour ◽  
P Addition

Addition of Ag+ cations induces J-aggregation in ultrathin films of both symmetrically and asymmetrically substituted Zn(ii) phthalocyanines.

Characterization of Asymmetric Polydiacetylene Ultrathin Films

1995 ◽  
Vol 382 ◽  
Author(s):  
D. W. Cheong ◽  
V. Shivshankar ◽  
H. C. Wang ◽  
C. M. Sung ◽  
J. Kumar ◽  
...  
Keyword(s):  
Ultrathin Films ◽  
Second Harmonic ◽  
Film Deposition ◽  
Asymmetric Structure ◽  
Blodgett Film ◽  
Force Microscopy ◽  
Langmuir Blodgett ◽  
Atomic Force ◽  
Ft Ir

ABSTRACTNonlinear optical (NLO) ultrathin films of a preforrned asymmetric polydiacetylene have been fabricated by Z-type Langmuir-Blodgett film deposition from the air-water interface. Induced in-plane orientation of the polydiacetylene backbone on the substrates has been confirmed by UV/Vis, FT-IR dichroism, and degenerate four wave mixing (DFWM) studies. All the measurements indicate that the backbone is prefe rentially oriented along the dipping direction. Second harmonic generation study suggests that the LB multilayers form an asymmetric structure (Z-type) due to the accumulation of 2-dimensional ordered monolayer and the dominant induced second order polarization is in the plane of the film. The film morphology and molecular orientation have been investigated by atomic force microscopy (AFM).

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