Role of N2O and equivalence ratio on NOx formation of methane/nitrous oxide premixed flames

2021 ◽  
Vol 223 ◽  
pp. 42-54 ◽  
Author(s):  
Chun-Han Chen ◽  
Yueh-Heng Li
2000 ◽  
Vol 122 (3) ◽  
pp. 405-411 ◽  
Author(s):  
Anuj Bhargava ◽  
Med Colket ◽  
William Sowa ◽  
Kent Casleton ◽  
Dan Maloney

An experimental and modeling study has been performed jointly by UTRC and DOE-FETC to determine the effect of humidity in the combustion air on emissions and stability limits of gas turbine premixed flames. This study focuses on developing gas turbine combustor design criteria for the Humid Air Turbine (HAT) cycle. The experiments were conducted at different moisture levels (0 percent, 5 percent, 10 percent, and 15 percent by mass in the air), at a total pressure of 200 psi, pilot levels (0 percent, 1 percent, 3 percent, and 5 percent total fuel), and equivalence ratio (0.4 to 0.8 depending on the moisture levels). The moisture levels were achieved by injecting steam into dry air well upstream of the fuel-air premixing nozzle. Computations were made for comparison to the experiments using GRI Mech 2.11 kinetics and thermodynamic database for modeling the flame chemistry. A Perfectly Stirred Reactor (PSR) network code was used to create a network of PSRs to simulate the flame. Excellent agreement between the measured and modeled NOx (5–10 percent) was obtained. Trends of added moisture reducing NOx and the effects of equivalence ratio and piloting level were well predicted. The CO predictions were higher by about 30–50 percent. The CO discrepancies are attributed to in-probe oxidation. The agreement between the data and model predictions over a wide range of conditions indicate the consistency and reliability of the measured data and usefulness of the modeling approach. An analysis of NOx formation revealed that at constant equilibrium temperature, Teq, the presence of steam leads to lower O-atom concentration which reduces “Zeldovich and N2O” NOx while higher OH-atom concentration reduces “Fenimore” NOx.[S0742-4795(00)00703-1]


Author(s):  
Anuj Bhargava ◽  
Med Colket ◽  
William Sowa ◽  
Kent Casleton ◽  
Dan Maloney

An experimental and modeling study has been performed jointly by UTRC and DOE-FETC to determine the effect of humidity in the combustion air on emissions and stability limits of gas turbine premixed flames. This study focuses on developing gas turbine combustor design criteria for the Humid Air Turbine (HAT) cycle. The experiments were conducted at different moisture levels (0%, 5%, 10% and 15% by mass in the air), at a total pressure of 200 psi, pilot levels (0%, 1%, 3% and 5% total fuel), and equivalence ratio (0.4 to 0.8 depending on the moisture levels). The moisture levels were achieved by injecting steam into dry air well upstream of the fuel-air premixing nozzle. Computations were made for comparison to the experiments using GRI Mech 2.11 kinetics and thermodynamic database for modeling the flame chemistry. A Perfectly Stirred Reactor (PSR) network code was used to create a network of PSRs to simulate the flame. Excellent agreement between the measured and modeled NOx (5–10%) was obtained. Trends of added moisture reducing NOx and the effects of equivalence ratio and piloting level were well predicted. The CO predictions were higher by about 30–50%. The CO discrepancies are attributed to in-probe oxidation. The agreement between the data and model predictions over a wide range of conditions indicate the consistency and reliability of the measured data and usefulness of the modeling approach. An analysis of NOx formation revealed that at constant equilibrium temperature, Teq, the presence of steam leads to lower O-atom concentration which reduces “Zeldovich and N2O” NOx while higher OH-atom concentration reduces “Fenimore” NOx.


2013 ◽  
Vol 781-784 ◽  
pp. 2471-2475 ◽  
Author(s):  
B. M. Masum ◽  
M.A. Kalam ◽  
H.H. Masjuki ◽  
S. M. Palash

Active research and development on using ethanol fuel in gasoline engine had been done for few decades since ethanol served as a potential of infinite fuel supply. This paper discussed analytically and provides data on the effects of compression ratio, equivalence ratio, inlet temperature, inlet pressure and ethanol blend in cylinder adiabatic flame temperature (AFT) and nitrogen oxide (NO) formation of a gasoline engine. Olikara and Borman routines were used to calculate the equilibrium products of combustion for ethanol gasoline blended fuel. The equilibrium values of each species were used to predict AFT and the NO formation of combustion chamber. The result shows that both adiabatic flame temperature and NO formation are lower for ethanol-gasoline blend than gasoline fuel.


Author(s):  
Fan Gong ◽  
Yong Huang

The objective of this work is to investigate the flame stabilization mechanism and the impact of the operating conditions on the characteristics of the steady, lean premixed flames. It’s well known that the flame base is very important to the existence of a flame, such as the flame after a V-gutter, which is typically used in ramjet and turbojet or turbofan afterburners and laboratory experiments. We performed two-dimensional simulations of turbulent premixed flames anchored downstream of the heat-conducting V-gutters in a confined passage for kerosene-air combustion. The flame bases are symmetrically located in the shear layers of the recirculation zone immediately after the V-gutter’s trailing edge. The effects of equivalence ratio of inlet mixture, inlet temperature, V-gutter’s thermal conductivity and inlet velocity on the flame base movements are investigated. When the equivalence ratio is raised, the flame base moves upstream slightly and the temperature gradient dT/dx near the flame base increases, so the flame base is strengthened. When the inlet temperature is raised, the flame base moves upstream very slightly, and near the flame base dT/dx increases and dT/dy decreases, so the flame base is strengthened. As the V-gutter’s thermal conductivity increases, the flame base moves downstream, and the temperature gradient dT/dx near the flame base decreases, so the flame base is weakened. When the inlet velocity is raised, the flame base moves upstream, and the convection heat loss with inlet mixture increases, so the flame base is weakened.


2018 ◽  
Vol 141 (4) ◽  
Author(s):  
Ping Wang ◽  
Qian Yu ◽  
Prashant Shrotriya ◽  
Mingmin Chen

In the present work, the fluctuations of equivalence ratio in the PRECCINSTA combustor are investigated via large eddy simulations (LES). Four isothermal flow cases with different combinations of global equivalence ratios (0.7 or 0.83) and grids (1.2 or 1.8 million cells) are simulated to study the mixing process of air with methane, which is injected into the inlet channel through small holes. It is shown that the fluctuations of equivalence ratio are very large, and their ranges are [0.4, 1.3] and [0.3, 1.2] for cases 0.83 and 0.7, respectively. For simulating turbulent partially premixed flames in this burner with the well-known dynamically thickened flame (DTF) combustion model, a suitable multistep reaction mechanism should be chosen aforehand. To do that, laminar premixed flames of 15 different equivalence ratios are calculated using three different methane/air reaction mechanisms: 2S_CH4_BFER, 2sCM2 reduced mechanisms and GRI-Mech 3.0 detailed reaction mechanism. The variations of flame temperature, flame speed and thickness of the laminar flames with the equivalence ratios are compared in detail. It is demonstrated that the applicative equivalence ratio range for the 2S_CH4_BFER mechanism is [0.5, 1.3], which is larger than that of the 2sCM2 mechanism [0.5, 1.2]. Therefore, it is recommended to use the 2S_CH4_BFER scheme to simulate the partially premixed flames in the PRECCINSTA combustion chamber.


2017 ◽  
Vol 54 (1) ◽  
pp. 119-135 ◽  
Author(s):  
Pengwei Yao ◽  
Xiaosha Li ◽  
Jiancan Liu ◽  
Yufang Shen ◽  
Shanchao Yue ◽  
...  

2018 ◽  
Vol 54 (9) ◽  
pp. 1097-1100 ◽  
Author(s):  
Sharareh Bagherzadeh ◽  
Neal P. Mankad

N2O reactivity of a [Cu2S] complex implies that tetranuclearity imparts oxidative stability to the CuZ site in nitrous oxide reductase.


Sign in / Sign up

Export Citation Format

Share Document