The pyrolysis behaviors of phosphorus-containing organosilicon compound modified APP with different polyether segments and their flame retardant mechanism in polyurethane foam

2019 ◽  
Vol 173 ◽  
pp. 106784 ◽  
Author(s):  
Yajun Chen ◽  
Linshan Li ◽  
Xiaoqing Qi ◽  
Lijun Qian
RSC Advances ◽  
2018 ◽  
Vol 8 (48) ◽  
pp. 27470-27480 ◽  
Author(s):  
Yajun Chen ◽  
Linshan Li ◽  
Lijun Qian

The centralized release of nonflammable gas and quick formation of crosslinked structure increase the flame retardant properties of polyurethane foams.


2014 ◽  
Vol 53 (3) ◽  
pp. 1160-1171 ◽  
Author(s):  
Ming-Jun Chen ◽  
Chun-Rong Chen ◽  
Yi Tan ◽  
Jian-Qian Huang ◽  
Xiu-Li Wang ◽  
...  

Author(s):  
Amanda Silva ◽  
Enio Henrique Pires da Silva ◽  
Danilo Janes ◽  
Romeu Rony Cavalcante da Costa ◽  
Giovanna Gabriela Crem Silva

Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 127 ◽  
Author(s):  
Yu Sun ◽  
Yazhen Wang ◽  
Li Liu ◽  
Tianyuan Xiao

A 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) acrylate, (6-oxidodibenzo [c,e][1,2] oxaphosphinin-6-yl) methyl acrylate (DOPOAA), has been prepared. Copolymers of styrene (St) and DOPOAA were prepared by emulsion polymerization. The chemical structures of copolymers containing levels of DOPOAA were verified using Fourier transform infrared (FT-IR) spectroscopy and 1H nuclear magnetic resonance (1H-NMR) spectroscopy. The thermal properties and flame-retardant behaviors of DOPO-containing monomers and copolymers were observed using thermogravimetric analysis and micro calorimetry tests. From thermogravimetric analysis (TGA), it was found out that the T5% for decomposition of the copolymer was lower than that of polystyrene (PS), but the residue at 700 °C was higher than that of PS. The results from micro calorimetry (MCC) tests indicated that the rate for the heat release of the copolymer combustion was lower than that for PS. The limiting oxygen index (LOI) for combustion of the copolymer rose with increasing levels of DOPOAA. These data indicate that copolymerization of the phosphorus-containing flame-retardant monomer, DOPOAA, into a PS segment can effectively improve the thermal stability and flame retardancy of the copolymer.


RSC Advances ◽  
2017 ◽  
Vol 7 (48) ◽  
pp. 30334-30344 ◽  
Author(s):  
Dizhu Yue ◽  
Oluwasola Oribayo ◽  
Garry L. Rempel ◽  
Qinmin Pan

The utilization of sustainable forestry waste resources in the production of polyurethane (PU) foam is a promising green alternative to the use of un-sustainable resources.


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