scholarly journals Effect of sugar cane straw ash (SCSA) as solid precursor and the alkaline activator composition on alkali-activated binders based on blast furnace slag (BFS)

2017 ◽  
Vol 144 ◽  
pp. 214-224 ◽  
Author(s):  
J.C.B. Moraes ◽  
M.M. Tashima ◽  
J.L. Akasaki ◽  
J.L.P. Melges ◽  
J. Monzó ◽  
...  
2018 ◽  
Vol 30 (6) ◽  
pp. 04018084 ◽  
Author(s):  
João Claudio Bassan de Moraes ◽  
Mauro Mitsuuchi Tashima ◽  
José Luiz Pinheiro Melges ◽  
Jorge Luís Akasaki ◽  
José Monzó ◽  
...  

2018 ◽  
Vol 163 ◽  
pp. 06001
Author(s):  
Miroslav Komljenović ◽  
Nataša Džunuzović ◽  
Violeta Nikolić

Durability of binders, mortars and concretes in aggressive environments is of crucial importance for their commercial application. In this paper the resistance to external sulfate attack of two different alkaliactivated binders (AABs), based either on blast furnace slag (BFS) or fly ash/blast furnace slag (FA/BFS) blend, was compared with two different commercially available Portland cement (CEM II) blended either with BFS or with FA and BFS. Comparison of sulfate resistance was based on compressive strength testing (the loss of strength) of mortar samples exposed to sodium sulfate attack up to 180 days and samples cured under controlled conditions for the same period of time. Furthermore, the evolution of microstructure of alkali-activated binders and pH of sodium silicate solution during testing were also analyzed. Despite different gel chemistry being involved, both alkali-activated binders based either on BFS or FA/BFS blend showed excellent resistance to external sulfate attack and even better than selected Portland cements tested under the same experimental conditions.


2018 ◽  
Vol 761 ◽  
pp. 15-18 ◽  
Author(s):  
Jan Koplík ◽  
Tomáš Solný ◽  
Lukáš Kalina ◽  
Jiří Másilko

It is well known, that alkali-activated materials (AAMs) are suitable for immobilization of heavy metals and other hazardous materials. This study is focused on the characterization of inhibition of three metals – Sr2+, Bi3+and Zn2+in alkali-activated matrices. Two type of matrices were prepared – alkali-activated blast furnace slag (BFS) and alkali-activated fly ash (FA). Sodium water glass was used as alkaline activator. The ability of these matrices to fix the metals were proved by leaching tests. Compressive strength was measured to characterize mechanical properties of the matrices. Scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectroscopy (EDS) was used to examine distribution and chemical state of metals within the matrices. The observed metals mainly formed the insoluble compounds after alkali activation.


2011 ◽  
Vol 287-290 ◽  
pp. 916-921
Author(s):  
Kyung Taek Koh ◽  
Gum Sung Ryu ◽  
Si Hwan Kim ◽  
Jang Hwa Lee

This paper examines the effects of the mixture ratio of fly ash/slag, the type of alkaline activators and curing conditions on the workability, compressive strength and microstructure of cementless alkali-activated mortar. The investigation showed that the mixture ratio of fly ash/slag and the type of alkaline activator have significant influence on the workability and strength, whereas the curing temperature has relatively poor effect. An alkali-activated mortar using a binder composed of 50% of fly ash and 50% of granulated blast furnace slag and alkaline activator made of 9M NaOH and sodium silicate in proportion of 1:1 is seen to be able to develop a compressive strength of 65 MPa at age of 28 days even when cured at ambient temperature of 20°C.


2019 ◽  
Vol 215 ◽  
pp. 371-380 ◽  
Author(s):  
Katrijn Gijbels ◽  
Remus Ion Iacobescu ◽  
Yiannis Pontikes ◽  
Sonja Schreurs ◽  
Wouter Schroeyers

2021 ◽  
Vol 5 (2) ◽  
pp. 59
Author(s):  
Dhruv Sood ◽  
Khandaker M. Anwar Hossain

Alkali-activated binders (AABs) are developed through the activation of aluminosilicate-rich materials using alkaline reagents. The characteristics of AABs developed using a novel dry-mixing technique incorporating powder-based reagents/activators are extensively explored. A total of forty-four binder mixes are assessed in terms of their fresh and hardened state properties. The influence of mono/binary/ternary combinations of supplementary cementitious materials (SCMs)/precursors and different types/combinations/dosages of powder-based reagents on the strength and workability properties of different binder mixes are assessed to determine the optimum composition of precursors and the reagents. The binary (55% fly ash class C and 45% ground granulated blast furnace slag) and ternary (25% fly ash class C, 35% fly ash class F and 40% ground granulated blast furnace slag) binders with reagent-2 (calcium hydroxide and sodium sulfate = 2.5:1) exhibited desired workability and 28-day compressive strengths of 56 and 52 MPa, respectively. Microstructural analyses (in terms of SEM/EDS and XRD) revealed the formation of additional calcium aluminosilicate hydrate with sodium or mixed Ca/Na compounds in binary and ternary binders incorporating reagent-2, resulting in higher compressive strength. This research confirms the potential of producing powder-based cement-free green AABs incorporating binary/ternary combinations of SCMs having the desired fresh and hardened state properties under ambient curing conditions.


2017 ◽  
Vol 63 (1) ◽  
pp. 22-26
Author(s):  
Pavel Mec ◽  
Lucie Gembalová

Abstract Alkali-activated binders (AAB) are very intensively studied materials nowadays. Because of possible usage as secondary raw materials, they can be environmentally efficient. Intensive research is focused especially on binder matrix, composition and its structure. For industrial usage, it is necessary to work with some aggregate for the preparation of mortars and concretes. Due to different structures of alkali-activated binders, the interaction with the aggregate will be different in comparison to an ordinary Portland cement binder. This paper deals with the study of interactions between several types of rocks used as aggregate and alkali-activated blast furnace slag. The research was focused especially on mechanical properties of prepared mortars.


2017 ◽  
Vol 68 (6) ◽  
pp. 1182-1187
Author(s):  
Ilenuta Severin ◽  
Maria Vlad

This article presents the influence of the properties of the materials in the geopolymeric mixture, ground granulated blast furnace slag (GGBFS) + wheat straw ash (WSA) + uncalcined red mud (RMu), and ground granulated blast furnace slag + wheat straw ash + calcined red mud (RMc), over the microstructure and mechanical properties of the synthesised geopolymers. The activation solutions used were a NaOH solution with 8M concentration, and a solution realised from 50%wt NaOH and 50%wt Na2SiO3. The samples were analysed: from the microstructural point of view through SEM microscopy; the chemical composition was determined through EDX analysis; and the compressive strength tests was done for samples tested at 7 and 28 days, respectively. The SEM micrographies of the geopolymers have highlighted a complex structure and an variable compressive strength. Compressive strength varied from 24 MPa in the case of the same recipe obtained from 70% of GGBFS + 25% WSA +5% RMu, alkaline activated with NaOH 8M (7 days testing) to 85 MPa in the case of the recipe but replacing RMu with RMc with calcined red mud, alkaline activated with the 50%wt NaOH and 50%wt Na2SiO3 solution (28 days testing). This variation in the sense of the rise in compressive strength can be attributed to the difference in reactivity of the materials used in the recipes, the curing period, the geopolymers structure, and the presence of a lower or higher rate of pores, as well as the alkalinity and the nature of the activation solutions used.


Sign in / Sign up

Export Citation Format

Share Document