Chemical and colorimetric analysis for the characterization of degradation forms and surface colour modification of building stone materials

2021 ◽  
Vol 302 ◽  
pp. 124356
Author(s):  
Roberta Occhipinti ◽  
Antonio Stroscio ◽  
Cristina Maria Belfiore ◽  
Germana Barone ◽  
Paolo Mazzoleni
Coatings ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 330 ◽  
Author(s):  
Michela Ricca ◽  
Emilia Le Pera ◽  
Maurizio Licchelli ◽  
Andrea Macchia ◽  
Marco Malagodi ◽  
...  

This paper presents the results of a laboratory experimentation carried out on stone materials in the framework of the CRATI project (Knowledge and Restoration through Advanced Integrated Technologies) aimed at testing new products with consolidating properties by means of an integrated methodological approach. After the preliminary characterization of stone materials collected in the pilot site, the second stage of the activities within the project were focused on the formulation and testing of products for the conservation of the same materials against decay, especially salt crystallization, one of the most aggressive and common degrading processes. The San Domenico Church, located in the old town of Cosenza (Calabria, Southern Italy) has been chosen as the pilot site and for the in situ tests. Several specimens with the same features of the stone materials used in San Domenico church were collected from a historical quarry near the city of Cosenza. These specimens were treated and then artificially degraded by salt crystallization tests in order to evaluate their susceptibility to weathering intensity. Three different consolidating products were used; respectively, two commercial and another one formulated in laboratory: (a) a suspension of nanosilica (Nano Estel®); (b) a suspension of nanolime (CaLoSiL®), and (c) a suspension of nano calcium-hydroxide dispersed in isopropyl alcohol and then mixed with diammonium hydrogen phosphate. A systematic approach, including minero-petrographic, geochemical and physico-mechanical techniques, was applied to evaluate (a) the nature and main features of materials; (b) the efficacy of consolidating treatments, and (c) the resistance of treated stone to the salt crystallization processes. The tested products demonstrated a significant efficiency to consolidate and protect stone material samples, enhancing their resistance to salt crystallization. Thus, such a case history may be useful in order to plan appropriate restoration interventions that consider the interactions between the building stone and the protective/consolidating product.


Heritage ◽  
2019 ◽  
Vol 2 (3) ◽  
pp. 2597-2611 ◽  
Author(s):  
Mario Bandiera ◽  
Patrice Lehuédé ◽  
Marco Verità ◽  
Luis Alves ◽  
Isabelle Biron ◽  
...  

This work aims to characterise the chemical composition of Roman opaque red glass sectilia dated to the 2nd century A.D and to shed light on Roman glassmaking production of different shades of red, from red to reddish-brown. Due to the lack of technical historical sources for this period many questions about technological aspects still remain. In this project a multi-disciplinary approach is in progress to investigate the red glass sectilia with several red hues from the Imperial Villa of Lucius Verus (161–169 A.D.) in Rome. First, colorimetric measurements were taken to identify the various red hues. The second step was chemical characterization of the samples and the identification of crystalline colouring phases. Particle Induced X-Ray Emission (PIXE) analysis was used to investigate the chemical composition of these glass samples, while the crystalline phases were identified by Raman Spectroscopy and Scanning Electrons Microscope with Energy Dispersive X-ray Spectrometry (SEM-EDS). Using SEM-EDS nanoparticles were detected as a colouring agent, the chemical composition and the morphology of which has been studied in depth. This information has been compared with the colorimetric analysis to establish any correlation with the different colour hues.


1997 ◽  
Vol 32 (1-4) ◽  
pp. 43-50 ◽  
Author(s):  
F Ciardelli ◽  
M Aglietto ◽  
L Montagnini di Mirabello ◽  
E Passaglia ◽  
S Giancristoforo ◽  
...  

2021 ◽  
Author(s):  
Adil Binal ◽  
Aylin Sel

Abstract Bacterial weathering plays a significant role in rock weathering, yet only a limited number of studies was conducted on this topic. The recent rapid developments in geomicrobiology are expected to increase the pace of research in this area. The extent and duration of the biological weathering processes on mineral and rock samples and minerals preferred by bacteria are still not fully understood due to the wide variety of both bacterial species and rock types. Biological weathering of rock types found in Turkey has also not been studied before. Here, we investigated the effects of two species of bacteria actively contributing to rock weathering on three rock types commonly used as building stone materials in Turkey. Granite, andesite, and limestone samples could interact with Bacillus species (B. subtilis and B. pumilus) in closed system reactors. Samples obtained from these reactors were analysed via Scanning Electron Microscopy (SEM) monitoring to identify morphological features and chemical composition changes. Chemical elements consumed most by bacteria were identified. Changes in the colour index were determined via RGB measurements. The effects of experimental conditions on bacterial growth were monitored via daily optical density measurements. The effects of bacteria on the physical properties of rock samples were also evaluated. B. subtilis and B. pumilus were found to be more aggressive on limestone/andesite and granite, respectively.


Measurement ◽  
2018 ◽  
Vol 125 ◽  
pp. 257-261 ◽  
Author(s):  
Emanuele Piuzzi ◽  
Erika Pittella ◽  
Stefano Pisa ◽  
Andrea Cataldo ◽  
Egidio De Benedetto ◽  
...  

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