Release of soil colloids increase the PFAS concentration from saturated soil during flow interruption

2021 ◽  
pp. 117297
Author(s):  
Annesh Borthakur ◽  
Brian K. Cranmer ◽  
Gregory P. Dooley ◽  
Jens Blotevogel ◽  
Shaily Mahendra ◽  
...  
Author(s):  
J. Thieme ◽  
J. Niemeyer ◽  
P. Guttman

In soil science the fraction of colloids in soils is understood as particles with diameters smaller than 2μm. Clay minerals, aquoxides of iron and manganese, humic substances, and other polymeric materials are found in this fraction. The spatial arrangement (microstructure) is controlled by the substantial structure of the colloids, by the chemical composition of the soil solution, and by thesoil biota. This microstructure determines among other things the diffusive mass flow within the soils and as a result the availability of substances for chemical and microbiological reactions. The turnover of nutrients, the adsorption of toxicants and the weathering of soil clay minerals are examples of these surface mediated reactions. Due to their high specific surface area, the soil colloids are the most reactive species in this respect. Under the chemical conditions in soils, these minerals are associated in larger aggregates. The accessibility of reactive sites for these reactions on the surface of the colloids is reduced by this aggregation. To determine the turnover rates of chemicals within these aggregates it is highly desirable to visualize directly these aggregation phenomena.


1995 ◽  
Vol 31 (5-6) ◽  
pp. 311-315 ◽  
Author(s):  
Timothy M. Straub ◽  
Ian L. Pepper ◽  
Charles P. Gerba

Current methods for the detection of enteric viruses in soil involve elution of viruses from soil colloids using beef extract or other proteins. These eluates are then assayed in cell culture and observed daily for cytopathic effects (CPE). While this method is suitable for detection of enteric viruses by cell culture, these eluates contain humic acids and heavy metals that interfere with polymerase chain reaction (PCR) detection. Using beef extract eluates prepared from sludge amended soil, 10 different methods of eluate purification were evaluated for their ability to remove PCR inhibition and maximize sensitivity. The treatment method providing the greatest sensitivity of poliovirus detection by PCR was the combination of Sephadex G-50 and Chelex-100. Using this method 2 plaque forming units (PFU) could be detected after reverse transcription and 30 cycles of PCR. Thirty (30) cycles of seminested PCR were performed on these samples to verify nucleic acid sequences and increase sensitivity after the first 30 cycles of PCR. Using seminested PCR, sensitivity of detection using the Sephadex G-50 and Chelex-100 treatment method to 0.2 PFU. In addition to providing excellent sensitivity for viruses in sludge amended soils, this treatment method is relatively simple compared to other methods.


Author(s):  
J. L. Mroginski ◽  
H. G. Castro ◽  
J. M. Podestá ◽  
P. A. Beneyto ◽  
A. R. Anonis

2021 ◽  
Vol 11 (10) ◽  
pp. 4663
Author(s):  
Raquel Cela-Dablanca ◽  
Carolina Nebot ◽  
Lucia Rodríguez López ◽  
David Ferández-Calviño ◽  
Manuel Arias-Estévez ◽  
...  

Antibiotics in wastewater, sewage sludge, manures, and slurries constitute a risk for the environment when spread on soils. This work studies the adsorption and desorption of the antibiotic cefuroxime (CFX) in 23 agricultural and forest soils, using batch-type experiments. Our results show that the adsorption values were between 40.75 and 99.57% in the agricultural soils, while the range was lower (from 74.57 to 93.46%) in forest soils. Among the Freundlich, Langmuir, and Linear models, the Freundlich equation shows the best fit for the adsorption results. In addition, agricultural soils with higher pH are the ones that present the highest adsorption. Further confirmation of the influence of pH on adsorption is given by the fact that Freundlich’s KF parameter and the Linear model Kd parameter shows a positive correlation with pH and with the exchangeable Ca and Mg values, which are known to affect the charges of the soil colloids and the formation of cationic bridges between adsorbents and adsorbate. In addition, Freundlich’s n parameter shows a positive and significant correlation with the organic matter content, related to the high adsorption taking place on forest soils despite their pH < 5. Regarding desorption, in most cases, it is lower than 1%, which indicates that CFX is adsorbed in a rather irreversible way onto these soils. Overall, these results can be considered relevant regarding their potential impact on environmental quality and public health.


Author(s):  
Fumiaki Nagashima ◽  
Hiroshi Kawase

Summary P-wave velocity (Vp) is an important parameter for constructing seismic velocity models of the subsurface structures by using microtremors and earthquake ground motions or any other geophysical exploration data. In order to reflect the ground survey information in Japan to the Vp structure, we investigated the relationships among Vs, Vp, and depth by using PS-logging data at all K-NET and KiK-net sites. Vp values are concentrated at around 500 m/s and 1,500 m/s when Vs is lower than 1,000 m/s, where these concentrated areas show two distinctive characteristics of unsaturated and saturated soil, respectively. Many Vp values in the layer shallower than 4 m are around 500 m/s, which suggests the dominance of unsaturated soil, while many Vp values in the layer deeper than 4 m are larger than 1,500 m/s, which suggests the dominance of saturated soil there. We also investigated those relationships for different soil types at K-NET sites. Although each soil type has its own depth range, all soil types show similar relationships among Vs, Vp, and depth. Then, considering the depth profile of Vp, we divided the dataset into two by the depth, which is shallower or deeper than 4 m, and calculated the geometrical mean of Vp and the geometrical standard deviation in every Vs bins of 200 m/s. Finally, we obtained the regression curves for the average and standard deviation of Vp estimated from Vs to get the Vp conversion functions from Vs, which can be applied to a wide Vs range. We also obtained the regression curves for two datasets with Vp lower and higher than 1,200 m/s. These regression curves can be applied when the groundwater level is known. In addition, we obtained the regression curves for density from Vs or Vp. An example of the application for those relationships in the velocity inversion is shown.


2021 ◽  
Vol 136 ◽  
pp. 104211
Author(s):  
Song Xu ◽  
L.H. Tong ◽  
Changjie Xu ◽  
Haibin Ding

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