Cost effective and facile low temperature hydrothermal fabrication of Cu2S thin films for hydrogen evolution reaction in seawater splitting

Author(s):  
T. Marimuthu ◽  
R. Yuvakkumar ◽  
P. Senthil Kumar ◽  
G. Ravi ◽  
Xueqing Xu ◽  
...  
CrystEngComm ◽  
2021 ◽  
Author(s):  
Qian Zhang ◽  
Shuihua Tang ◽  
Lieha Shen ◽  
Weixiang Yang ◽  
Zhen Tang ◽  
...  

Developing cost-effective and high-performance electrocatalysts for hydrogen evolution reaction (HER) are imperative thanks to rapid increase of fuel-cell driven vehicles. Tungsten (W) possesses advantages of optimized hydrogen adsorption energy and...


2018 ◽  
Vol 30 (4) ◽  
pp. 045603 ◽  
Author(s):  
Wenxu Yin ◽  
Zhantong Ye ◽  
Xue Bai ◽  
Dong He ◽  
Xiaoyu Zhang ◽  
...  

Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 929 ◽  
Author(s):  
Sajjad Hussain ◽  
Kamran Akbar ◽  
Dhanasekaran Vikraman ◽  
Rana Afzal ◽  
Wooseok Song ◽  
...  

To find an effective alternative to scarce, high-cost noble platinum (Pt) electrocatalyst for hydrogen evolution reaction (HER), researchers are pursuing inexpensive and highly efficient materials as an electrocatalyst for large scale practical application. Layered transition metal dichalcogenides (TMDCs) are promising candidates for durable HER catalysts due to their cost-effective, highly active edges and Earth-abundant elements to replace Pt electrocatalysts. Herein, we design an active, stable earth-abundant TMDCs based catalyst, WS(1−x)Sex nanoparticles-decorated onto a 3D porous graphene/Ni foam. The WS(1−x)Sex/graphene/NF catalyst exhibits fast hydrogen evolution kinetics with a moderate overpotential of ~−93 mV to drive a current density of 10 mA cm−2, a small Tafel slope of ~51 mV dec−1, and a long cycling lifespan more than 20 h in 0.5 M sulfuric acid, which is much better than WS2/NF and WS2/graphene/NF catalysts. Our outcomes enabled a way to utilize the TMDCs decorated graphene and precious-metal-free electrocatalyst as mechanically robust and electrically conductive catalyst materials.


2016 ◽  
Vol 4 (36) ◽  
pp. 13731-13735 ◽  
Author(s):  
Yingjie Li ◽  
Haichuan Zhang ◽  
Ming Jiang ◽  
Yun Kuang ◽  
Hailiang Wang ◽  
...  

A self-supported amorphous Co–Mo–S ultrathin film with hierarchical pores formed via low-temperature sulfurization exhibits high performance toward acidic hydrogen evolution.


2020 ◽  
Vol MA2020-01 (37) ◽  
pp. 1535-1535
Author(s):  
Marcelo Videa ◽  
D. Alfonso Crespo-Yapur ◽  
Alejandra Medrano

Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 912
Author(s):  
Duong Nguyen Nguyen ◽  
Uk Sim ◽  
Jung Kyu Kim

Hydrogen-evolution reaction (HER) is a promising technology for renewable energy conversion and storage. Electrochemical HER can provide a cost-effective method for the clean production of hydrogen. In this study, a biomimetic eco-friendly approach to fabricate nitrogen-doped carbon nanosheets, exhibiting a high HER performance, and using a carbonized polydopamine (C-PDA), is described. As a biopolymer, polydopamine (PDA) exhibits high biocompatibility and can be easily obtained by an environmentally benign green synthesis with dopamine. Inspired by the polymerization of dopamine, we have devised the facile synthesis of nitrogen-doped nanocarbons using a carbonized polydopamine for the HER in acidic media. The N-doped nanocarbons exhibit excellent performance for H2 generation. The required overpotential at 5 mA/cm2 is 130 mV, and the Tafel slope is 45 mV/decade. Experimental characterizations confirm that the excellent performance of the N-doped nanocarbons can be attributed to the multisite nitrogen doping, while theoretical computations indicate the promotion effect of tertiary/aromatic nitrogen doping in enhancing the spin density of the doped samples and consequently in forming highly electroactive sites for HER applications.


2016 ◽  
Vol 6 (6) ◽  
pp. 1952-1956 ◽  
Author(s):  
Dezhi Wang ◽  
Dezun Zhang ◽  
Chaoyun Tang ◽  
Pan Zhou ◽  
Zhuangzhi Wu ◽  
...  

Co-promoted molybdenum phosphide nanoparticles have been successfully prepared and explored for the first time as a cost-effective electrocatalyst for hydrogen evolution reaction (HER).


2018 ◽  
Vol 5 (10) ◽  
pp. 2425-2431 ◽  
Author(s):  
Zhaoqing Ding ◽  
Zhenghua Tang ◽  
Ligui Li ◽  
Kai Wang ◽  
Wen Wu ◽  
...  

Designing a highly active, robust and cost-effective electrocatalyst with multiple functionalities toward overall water splitting and rechargeable Zn–air battery applications is crucial and urgent for the development of sustainable energy sources.


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