Pt nanoparticles synthesized by successive ionic layers deposition method and their electrocatalytic properties in hydrogen evolution reaction during water splitting in the acidic medium

2022 ◽  
pp. 163640
Author(s):  
Maria V. Kaneva ◽  
Larisa B. Gulina ◽  
Valeri P. Tolstoy
Keyword(s):  
Hydrogen Evolution ◽  
Water Splitting ◽  
Hydrogen Evolution Reaction ◽  
Acidic Medium ◽  
Pt Nanoparticles ◽  
Deposition Method ◽  
Electrocatalytic Properties

First electrochemical synthesis of mesoporous RhNi alloy films for an alkali-mediated hydrogen evolution reaction

2021 ◽  
Vol 9 (5) ◽  
pp. 2754-2763
Author(s):  
Kenya Kani ◽  
Hyunsoo Lim ◽  
Andrew E. Whitten ◽  
Kathleen Wood ◽  
Anya J. E. Yago ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Electrochemical Synthesis ◽  
Polymeric Micelles ◽  
Deposition Method ◽  
Alloy Films ◽  
Electrocatalytic Properties ◽  
Self Assembled

The mesoporous RhNi alloy films are synthesized by controlling the concentration of Rh precursor, applied potentials, and pH via the electrochemical co-deposition method with self-assembled polymeric micelles templates for enhancing electrocatalytic properties.

scholarly journals Molybdenum Disulfide Nanosheets Decorated with Platinum Nanoparticle as a High Active Electrocatalyst in Hydrogen Evolution Reaction

2022 ◽  
Vol 17 (1) ◽  
Author(s):  
Mina Razavi ◽  
M. Sookhakian ◽  
Boon Tong Goh ◽  
Hadariah Bahron ◽  
Eyas Mahmoud ◽  
...  
Keyword(s):  
Molybdenum Disulfide ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Acidic Medium ◽  
High Performance ◽  
Hydrogen Adsorption ◽  
Electrochemical Impedance ◽  
Pt Nanoparticles ◽  
Platinum Nanoparticle ◽  
Molybdenum Disulfide Nanosheets

AbstractElectrochemical hydrogen evolution reaction (HER) refers to the process of generating hydrogen by splitting water molecules with applied external voltage on the active catalysts. HER reaction in the acidic medium can be studied by different mechanisms such as Volmer reaction (adsorption), Heyrovsky reaction (electrochemical desorption) or Tafel reaction (recombination). In this paper, facile hydrothermal methods are utilized to synthesis a high-performance metal-inorganic composite electrocatalyst, consisting of platinum nanoparticles (Pt) and molybdenum disulfide nanosheets (MoS2) with different platinum loading. The as-synthesized composite is further used as an electrocatalyst for HER. The as-synthesized Pt/Mo-90-modified glassy carbon electrode shows the best electrocatalytic performance than pure MoS2 nanosheets. It exhibits Pt-like performance with the lowest Tafel slope of 41 mV dec−1 and superior electrocatalytic stability in an acidic medium. According to this, the HER mechanism is related to the Volmer-Heyrovsky mechanism, where hydrogen adsorption and desorption occur in the two-step process. According to electrochemical impedance spectroscopy analysis, the presence of Pt nanoparticles enhanced the HER performance of the MoS2 nanosheets because of the increased number of charge carriers transport.

Hierarchically porous FeNi3@FeNi layered double hydroxide nanostructures: One-step fast electrodeposition and highly efficient electrocatalytic performances for overall water splitting

2021 ◽  
Author(s):  
Zihao Liu ◽  
Shifeng Li ◽  
Fangfang Wang ◽  
Mingxia Li ◽  
Yonghong Ni
Keyword(s):  
Hydrogen Evolution ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Hydrogen Evolution Reaction ◽  
Oxygen Evolution Reaction ◽  
Electrocatalytic Activity ◽  
Hierarchically Porous ◽  
One Step ◽  
Double Hydroxide

FeNi-layered double hydroxide (LDH) is thought to be an excellent electrocatalyst for oxygen evolution reaction (OER), but it always shows extremely poor electrocatalytic activity toward hydrogen evolution reaction (HER) in...

scholarly journals Engineering single-atomic ruthenium catalytic sites on defective nickel-iron layered double hydroxide for overall water splitting

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Panlong Zhai ◽  
Mingyue Xia ◽  
Yunzhen Wu ◽  
Guanghui Zhang ◽  
Junfeng Gao ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Water Splitting ◽  
Layered Double Hydroxide ◽  
Hydrogen Evolution Reaction ◽  
Active Sites ◽  
Density Functional ◽  
Rational Design ◽  
Single Atom ◽  
Nickel Iron ◽  
Double Hydroxide

AbstractRational design of single atom catalyst is critical for efficient sustainable energy conversion. However, the atomic-level control of active sites is essential for electrocatalytic materials in alkaline electrolyte. Moreover, well-defined surface structures lead to in-depth understanding of catalytic mechanisms. Herein, we report a single-atomic-site ruthenium stabilized on defective nickel-iron layered double hydroxide nanosheets (Ru1/D-NiFe LDH). Under precise regulation of local coordination environments of catalytically active sites and the existence of the defects, Ru1/D-NiFe LDH delivers an ultralow overpotential of 18 mV at 10 mA cm−2 for hydrogen evolution reaction, surpassing the commercial Pt/C catalyst. Density functional theory calculations reveal that Ru1/D-NiFe LDH optimizes the adsorption energies of intermediates for hydrogen evolution reaction and promotes the O–O coupling at a Ru–O active site for oxygen evolution reaction. The Ru1/D-NiFe LDH as an ideal model reveals superior water splitting performance with potential for the development of promising water-alkali electrocatalysts.

Electrocatalytic properties of cobalt-molybdenum alloy deposits in the hydrogen evolution reaction

2008 ◽  
Vol 44 (12) ◽  
pp. 1350-1358 ◽  
Author(s):  
V. V. Kuznetsov ◽  
A. A. Kalinkina ◽  
T. V. Pshenichkina ◽  
V. V. Balabaev
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Molybdenum Alloy ◽  
Electrocatalytic Properties

scholarly journals Catalytic activity of Co-nanocrystal-doped tungsten carbide arising from an internal magnetic field

RSC Advances ◽  
2021 ◽  
Vol 11 (23) ◽  
pp. 14063-14070
Author(s):  
M. Morishita ◽  
A. Nozaki ◽  
H. Yamamoto ◽  
N. Fukumuro ◽  
M. Mori ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Catalytic Activity ◽  
Tungsten Carbide ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Pt Nanoparticles ◽  
Internal Magnetic Field ◽  
Co Doped

The catalytic activity of the Co-doped WC is 30% higher than that of Pt nanoparticles for the hydrogen evolution reaction arising from an internal magnetic field.

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