Tailoring the self-assembly of linear alkyl chains for the design of advanced materials with technological applications

2018 ◽  
Vol 513 ◽  
pp. 911-922 ◽  
Author(s):  
Cristina E. Hoppe ◽  
Roberto J.J. Williams
2017 ◽  
Vol 19 (29) ◽  
pp. 19205-19216 ◽  
Author(s):  
Yi Hu ◽  
Kai Miao ◽  
Li Xu ◽  
Bao Zha ◽  
Mengying Long ◽  
...  

We explored the chain length effect on inducing the self-assembly of diverse structures by tiny modification of the alkyl chains.


2003 ◽  
Vol 771 ◽  
Author(s):  
Paolo Coppo ◽  
Michael L. Turner ◽  
Domenico C. Cupertino ◽  
Stephen G. Yeates

AbstractCyclopentadithiophene based homopolymers and copolymers have been investigated as semiconductor layers in field effect transistors. They generally show low hole mobilities due to a disordered amorphous structure in the solid state. FET mobility can be enhanced in the homopolymer, although this results in poor on/off ratio of the device. The low mobilities may be attributed to the presence of solubilizing alkyl chains normal to the long axis of the polymer which prevent the self assembly of the polymer into an ordered π-stacked configuration.


RSC Advances ◽  
2016 ◽  
Vol 6 (33) ◽  
pp. 27370-27377 ◽  
Author(s):  
Panpan Sun ◽  
Lijuan Shi ◽  
Fei Lu ◽  
Liqiang Zheng

The effects of anionic type, cationic structure and alkyl chain length are illustrated to regulate the self-assembly of zwitterionic SAILs.


1998 ◽  
Vol 76 (11) ◽  
pp. 1654-1659
Author(s):  
F Bensebaa ◽  
T H Ellis ◽  
E Kruus ◽  
R Voicu ◽  
Y Zhou

Layered materials composed of metal-alkanethiolate units have been synthesized and characterized. The self-assembly occurs at the interface between a metal-ion-containing aqueous phase and an alkanethiol-containing organic phase. Key features of the structure have been determined from X-ray diffraction and infrared spectroscopy measurements. The highly ordered bilayers are characterized by tilted, all-trans alkyl chains. A new model for the in-plane structure has been presented, which is based on a hexagonal arrangement of metal atoms in the central plane.Key words: self-assembly, alkanethiolates, layered materials, vibrational spectroscopy.


2014 ◽  
Vol 50 (57) ◽  
pp. 7683-7685 ◽  
Author(s):  
Kazukuni Tahara ◽  
Maria L. Abraham ◽  
Kosuke Igawa ◽  
Keisuke Katayama ◽  
Iris M. Oppel ◽  
...  

Tris-(2-hydroxybenzylidene)triaminoguanidinium salts having six alkyl chains with proper spacing served as new molecular building blocks for the formation of porous honeycomb networks by van der Waals interaction between interdigitated alkyl chains at the liquid/graphite interfaces.


2021 ◽  
Author(s):  
Nada Aljuaid ◽  
Mark Tully ◽  
Jani Seitsonen ◽  
Janne Ruokolainen ◽  
Ian Hamley

The self-assembly in aqueous solution of benzene-1,3,5-tricarboxamide (BTA) bearing one alkyl chain and two PEG (polyethylene glycol) chains or two alkyl chains and one PEG chain yields completely distinct nanostructures....


Author(s):  
M. Kessel ◽  
R. MacColl

The major protein of the blue-green algae is the biliprotein, C-phycocyanin (Amax = 620 nm), which is presumed to exist in the cell in the form of distinct aggregates called phycobilisomes. The self-assembly of C-phycocyanin from monomer to hexamer has been extensively studied, but the proposed next step in the assembly of a phycobilisome, the formation of 19s subunits, is completely unknown. We have used electron microscopy and analytical ultracentrifugation in combination with a method for rapid and gentle extraction of phycocyanin to study its subunit structure and assembly.To establish the existence of phycobilisomes, cells of P. boryanum in the log phase of growth, growing at a light intensity of 200 foot candles, were fixed in 2% glutaraldehyde in 0.1M cacodylate buffer, pH 7.0, for 3 hours at 4°C. The cells were post-fixed in 1% OsO4 in the same buffer overnight. Material was stained for 1 hour in uranyl acetate (1%), dehydrated and embedded in araldite and examined in thin sections.


Author(s):  
M. Sarikaya ◽  
J. T. Staley ◽  
I. A. Aksay

Biomimetics is an area of research in which the analysis of structures and functions of natural materials provide a source of inspiration for design and processing concepts for novel synthetic materials. Through biomimetics, it may be possible to establish structural control on a continuous length scale, resulting in superior structures able to withstand the requirements placed upon advanced materials. It is well recognized that biological systems efficiently produce complex and hierarchical structures on the molecular, micrometer, and macro scales with unique properties, and with greater structural control than is possible with synthetic materials. The dynamism of these systems allows the collection and transport of constituents; the nucleation, configuration, and growth of new structures by self-assembly; and the repair and replacement of old and damaged components. These materials include all-organic components such as spider webs and insect cuticles (Fig. 1); inorganic-organic composites, such as seashells (Fig. 2) and bones; all-ceramic composites, such as sea urchin teeth, spines, and other skeletal units (Fig. 3); and inorganic ultrafine magnetic and semiconducting particles produced by bacteria and algae, respectively (Fig. 4).


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