Wafer-scale plasmonic metal-dielectric-metal structural color featuring high saturation and low angular dependence

Structural color has been studied through various methods due to its distinguished features of stability, durability, high information storage density and high integration. However, the artificial structural color samples do not exhibit superior performance in color saturation and low angular dependence. Here, we present an approach to acquire additive reflective color based on a metal-dielectric-metal (MDM) stack. The upper layer composed of Ag particles is perforated in a hexagonal arrangement which profits from the dielectric anodic aluminum oxide (AAO) membrane, the size and shape of the Ag particles are getting inhomogeneous as the deposition thickness of the upper layer increasing, which expands the desired absorption range of surface plasmons. The residual non-anodized Al foil serves as a highly reflective substrate for efficient color presenting through the thin-film interference in this plasmonic MDM system. As a result, the color gamut area of this MDM stack is extended 8 times in CIE chromaticity coordinates. Finally, a wafer-scale (diameter of 83 mm) badge of Harbin Engineering University (HEU) with highly saturated colors and a pattern characterized with low angle-dependent property (up to 60°) are presented, which exhibit promising prospects in commercial coloring and imaging.

Photocatalytic Properties of Silver Nanospherical Arrays Driven by Surface Plasmons

Surface-enhanced Raman scattering (SERS) is a promising technique to study the plasma-driven photocatalytic reactions. Hemispherical alumina nanoarrays with a regular hexagonal arrangement are firstly prepared; then, silver hemispherical nanoarrays are synthesized on the surface of the arrays by silver evaporation. When a laser with a specific wavelength (633 nm) is irradiated on the silver nanoarrays, a large number of regularly arranged local surface plasmon enhancement regions (called “hot spots”) would be generated on its surface. After that, a layer of evenly distributed p-aminothiophenol (PATP) probe molecules was placed on the substrate and the photocatalytic reaction of PATP was driven by the local surface plasmon to form four 4′-di-mercaptoazobenzene (DMAB). Then, under the same experimental conditions, the later product was reversely reacted to form PATP molecule by the action of plasma in the presence of in situ sodium borohydride. SERS can be used to monitor the whole process of the photocatalytic reaction of PATP probe molecules driven by the plasma on the surface of the silver nanoarrays. This research achieves the drawing and erasing of molecular graphics in the micro- and nano-scales, as well as information encryption, reading, and erasing that have strong application value.

Dual scaled approach SPR-based PCF RI sensor with ultra-low loss

We demonstrate an ultra-low loss photonic crystal fiber (PCF) sensor based on surface plasmon resonance (SPR)in this paper. In this refractive index (RI) sensor, we explored hexagonal-arrangement of airholes and employed only two different sizes of it. The formation of airholes makes the confinement loss (CL) surprisingly low. The maximum CL is as low as 10.71 and 28.58 dB/cm for x and y-pol modes, respectively within a range of refractive indices 1.33-1.40. The maximum gained amplitude sensitivity is -1212 RIU−1 and -2430 RIU−1, and the maximum figure of merit is as high as 583 and 467 respectively for x and y-polarization (pol) modes respectively. In addition to that, we got a maximum wavelength sensitivity, Sw of 14,000nm/RIU for both x and y-pol modes with a minimum sensor resolution of 7.143x10−6. Gold is preferred over other materials as the plasmonic material for its inert behaviour and higher chemical stability. The analysis was carried out using the finite element method (FEM). This sensor, with its elegant configuration, fabrication feasibility, ultra-low loss, stands out to be an effective and eminent prospect in the current burgeoning SPR sensor realm and also prompts further creative exploration in its hexagonal lattice arrangements.

Innovation in 3D Braiding Technology and Its Applications

Braids are generally divided into 2D braids and 3D braids. Two-dimensional braids include flat braids and circular braids. Circular braids represent three-dimensional textiles, as they enclose a volume, but consist of a two-dimensional yarn architecture. Three-dimensional braids are defined by a three-dimensional yarn architecture. Historically, 3D braids were produced on row and column braiding machines with Cartesian or radial machine beds, by bobbin movements around inlay yarns. Three-dimensional rotary braiding machines allow a more flexible braiding process, as the bobbins are moved via individually controlled horn gears and switches. Both braiding machines at the Institut für Textiltechnik (ITA) of RWTH Aachen University, Germany, are based on the principal of 3D rotary machines. The fully digitized 3D braiding machine with an Industry 4.0 standard enables the near-net-shape production of three-dimensionally braided textile preforms for lightweight applications. The preforms can be specifically reinforced in all three spatial directions according to the application. Complex 3D structures can be produced in just one process step due to the high degree of design freedom. The 3D hexagonal braiding technology is used in the field of medical textiles. The special shape of the horn gears and their hexagonal arrangement provides the densest packing of the bobbins on the machine bed. In addition, the lace braiding mechanism allows two bobbins to occupy the position between two horn gears, maximizing the number of bobbins. One of the main applications is the near-net-shape production of tubular structures, such as complex stent structures. Three-dimensional braiding offers many advantages compared to 2D braiding, e.g., production of complex three-dimensional geometries in one process step, connection of braided layers, production of cross-section changes and ramifications, and local reinforcement of technical textiles without additional process steps. In the following review, the latest developments in 3D braiding, the machine development of 3D braiding machines, as well as software and simulation developments are presented. In addition, various applications in the fields of lightweight construction and medical textiles are introduced.

CONSTRUCTION OF ADAPTIVE NOISE COMPENSATOR COMPLEXES WITH HYBRID MIRROR ANTENNAS

Представлены результаты исследования возможности использования антенных решеток с гексагональным расположением облучателей в целях создания на их базе эффективных комплексов адаптивных компенсаторов помех. The article presents the results of the research on the possibility of using antenna arrays with a hexagonal arrangement of irradiators to create effective complexes of adaptive noise compensators based on hybrid mirror antennas.

Ultrawide-angle and high-efficiency metalens in hexagonal arrangement

Wide-angle optical systems play a vital role in imaging applications and have been researched for many years. In traditional lenses, attaining a wide field of view (FOV) by using a single optical component is difficult because these lenses have crucial aberrations. In this study, we developed a wide-angle metalens with a numerical aperture of 0.25 that provided a diffraction-limited FOV of over 170° for a wavelength of 532 nm without the need for image stitching or multiple lenses. The designed wide-angle metalens is free of aberration and polarization, and its full width of half maximum is close to the diffraction limit at all angles. Moreover, the metalens which is designed through a hexagonal arrangement exhibits higher focusing efficiency at all angles than most-seen square arrangement. The focusing efficiencies are as high as 82% at a normal incident and 45% at an incident of 85°. Compared with traditional optical components, the proposed metalens exhibits higher FOV and provides a more satisfactory image quality because of aberration correction. Because of the advantages of the proposed metalens, which are difficult to achieve for a traditional single lens, it has the potential to be applied in camera systems and virtual and augmented reality.

Combining valproate and bipyridyl ligands to construct a 0D core-shell Zn5(μ3-OH)2 cluster and a 2D layered coordination network with a [Zn3(μ3-OH)]2 SBU

Starting from the proposed zinc carboxylate cluster tetrakis(μ-2-propylpentanoato)dizinc(II), Zn2(μ2-valp)4 (I), of valproic acid, a branched short-chain fatty acid, and bipyridine ligands, two new mixed-ligand coordination compounds, namely, bis(2,2′-bipyridine)di-μ3-hydroxido-hexakis(μ-2-propylpentanoato)bis(2-propylpentanoato)pentazinc(II), [Zn5(C8H15O2)8(OH)2(C10H8N2)2] (II), and poly[[bis(μ-4,4′-bipyridine)di-μ3-hydroxido-octakis(μ-2-propylpentanoato)bis(2-propylpentanoato)hexazinc(II)] dimethylformamide disolvate], {[Zn6(C8H15O2)10(OH)2(C10H8N2)2]·2C3H7NO} n (III), were synthesized. Compound II is a core-shell-type zero-dimensional discrete Zn5(μ3-OH)2 metal–organic cluster with Zn ions in double-triangle arrangements that share one Zn ion coincident with an inversion centre. The cluster contains three crystallographically non-equivalent Zn ions exhibiting three different coordination geometries (tetrahedral, square pyramidal and octahedral). The cluster cores are well separated and embedded in a protective shell of the aliphatic branched short chains of valproate. As a result, there is no specific interaction between the discrete clusters. Conversely, compound III, a 2D layered coordination network with a secondary building unit (SBU), is formed by Zn6(μ3-OH)2 clusters exhibiting a chair-like hexagonal arrangement. This SBU is formed from two Zn3(μ3-OH) trimers related by inversion symmetry and connected by two syn–anti bridging carboxylate groups. Each SBU is connected by four 4,4′-bipyridine ligands producing a 63-hcb net topology. 2D coordination layers are sandwiched within layers of dimethylformamide molecules that do not interact strongly with the network due to the hydrophobic protection provided by the valproate ligands.

Fabrication of Subretinal 3D Microelectrodes with Hexagonal Arrangement

This study presents the fabrication of three-dimensional (3D) microelectrodes for subretinal stimulation, to accommodate adjacent return electrodes surrounding a stimulating electrode. For retinal prosthetic devices, the arrangement of return electrodes, the electrode size and spacing should be considered together, to reduce the undesired dissipation of electric currents. Here, we applied the hexagonal arrangement to the microelectrode array for the localized activation of retinal cells and better visual acuity. To provide stimuli more efficiently to non-spiking neurons, a 3D structure was created through a customized pressing process, utilizing the elastic property of the materials used in the fabrication processes. The diameter and pitch of the Pt-coated electrodes were 150 μm and 350 μm, respectively, and the height of the protruded electrodes was around 20 μm. The array consisted of 98 hexagonally arranged electrodes, supported by a flexible and transparent polydimethylsiloxane (PDMS) base, with a thickness of 140 μm. Also, the array was coated with 2 μm-thick parylene-C, except the active electrode sites, for more focused stimulation. Finally, the electrochemical properties of the fabricated microelectrodes were characterized, resulting in the mean impedance of 384.87 kΩ at 1 kHz and the charge storage capacity (CSC) of 2.83 mC·cm−2. The fabricated microelectrodes are to be combined with an integrated circuit (IC) for additional in vitro and in vivo experiments.