Revealing the doping mechanism of barium in sulfoaluminate cement clinker phases

2021 ◽  
Vol 295 ◽  
pp. 126405
Author(s):  
Jianping Zhu ◽  
Yang Chen ◽  
Li Zhang ◽  
Benkai Guo ◽  
Guangxin Fan ◽  
...  
Author(s):  
Arezki Tagnit-Hamou ◽  
Shondeep L. Sarkar

All the desired properties of cement primarily depend on the physicochemical characteristics of clinker from which the cement is produced. The mineralogical composition of the clinker forms the most important parameter influencing these properties.Optical microscopy provides reasonably accurate information pertaining to the thermal history of the clinker, while XRDA still remains the proven method of phase identification, and bulk chemical composition of the clinker can be readily obtained from XRFA. Nevertheless, all these microanalytical techniques are somewhat limited in their applications, and SEM/EDXA combination fills this gap uniquely by virtue of its high resolution imaging capability and possibility of instantaneous chemical analysis of individual phases.Inhomogeneities and impurities in the raw meal, influence of kiln conditions such as sintering and cooling rate being directly related to the microstructure can be effectively determined by SEM/EDXA. In addition, several physical characteristics of cement, such as rhcology, grindability and hydraulicity also depend on the clinker microstructure.


2020 ◽  
Vol 10 (1) ◽  
pp. 49
Author(s):  
Suharto Suharto ◽  
Muhammad Amin ◽  
Muhammad Al Muttaqii ◽  
Syafriadi Syafriadi ◽  
Kiki Nurwanti

Experimental study on the use of basalt stone originated from Lampung has been conducted to evaluate its potential for a partial substitute of raw material in production of cement clinker. The basalt stone contains minerals of anorthite, augite, and albite phases that are required for clinker formation. In this study, the main raw materials were 80% limestone, 10% silica sand, 9% clay and 1% iron sand. The raw material in these experiments were mixtures 90% or 80% of the main raw material and 10% or 20% of basalt stone. The effect of adding coal to raw materials was also studied to see the possibility of an increase in clinkerization temperature inside the raw material mixture, and at the same time to see the effect of coal ash on clinker composition. Clinker obtained from heating of raw materials at a temperature of 1100oC had LSF of 94.1% and 95.1% (heating time of 1 and 3 hours). If heating is carried out at 1200oC, the clinker had LSF of 97.7% and 98.0% (heating time of 2 and 3 hours, respectively). Depending on the temperature and duration of heating, the clinker mostly had SM in the range of 2.18-2.40% , and AM in the range of 0,78-1.80%. Characterization using XRD showed that the clinker consisted of larnite and gehlenite phases, and dominated by CaO.Batu basalt Lampung telah diuji potensinya sebagai pengganti sebagian bahan baku utama pembuatan klinker semen. Batu basalt tersebut memiliki mineral-mineral dalam fase anorthite, augite, dan albite yang diperlukan pada pembentukan klinker. Pada penelitian ini, bahan baku utama adalah batu kapur 80%, pasir silika 10%, tanah liat 9% dan pasir besi 1%. Campuran bahan baku klinker adalah 90% atau 80% bahan baku utama dan 10% atau 20% batu basalt. Efek penambahan batubara ke dalam bahan baku klinker juga dipelajari untuk melihat kemungkinan kenaikan temperatur klinkerisasi di dalam campuran bahan baku, dan sekaligus untuk melihat efek abu batubara terhadap komposisi klinker. Klinker hasil pemanasan bahan baku pada temperatur 1100oC memiliki LSF 94,1% dan 95,1% (lama pemanasan 1 dan 3 jam). Jika pemanasan dilakukan pada 1200oC, klinker memilik LSF 97,7% dan 98,00% (lama pemanasan 2 dan 3 jam). Tergantung pada temperatur dan lama pemanasan, klinker hasil percobaan ini umumnya memiliki SM 2,18-2,40%, dan AM antara 0,78-1,80%. Karakterisasi dengan XRD menunjukkan bahwa klinker terdiri dari fase larnite dan gehlenite, dan didominasi CaO.


2021 ◽  
Author(s):  
Jiaoling Zheng ◽  
Shuaifei Wei ◽  
Qianqian Wang ◽  
Xiaodong Li ◽  
Suhua Ma
Keyword(s):  

Author(s):  
Ilaria Bargigia ◽  
Lisa R. Savagian ◽  
Anna M. Österholm ◽  
John R. Reynolds ◽  
Carlos Silva

Nature ◽  
1964 ◽  
Vol 203 (4941) ◽  
pp. 138-139 ◽  
Author(s):  
A. K. CHATTERJI ◽  
T. C. PHATAK

2020 ◽  
Vol 30 (1) ◽  
pp. 54-63
Author(s):  
Willy Mbasha ◽  
Rainer Haldenwang ◽  
Irina Masalova

AbstractNatural gypsum can degenerate into hemihydrate during cement clinker grinding which changes the physical and chemical properties of cement hydration, affecting therefore the fresh and hardened properties of cement based materials. Cement systems containing a constant total amount of calcium sulfate (4%) with relative proportions of hemihydrate and natural gypsum were considered. Rheological measurements were executed on an Anton Paar MCR51 rheometer to evaluate the flow properties of cement pastes. Results show that, the yield stress and the plastic viscosity of cement pastes were affected when the degeneration of natural gypsum exceeded 50%. Above this concentration, the yield stress remarkably increased and a variation in plastic viscosity of about 50% was observed. Using TG-DSC techniques, it was shown that, the amount of formed ettringite could not explain these rheological changes. However, centrifugational packing and SEM-SE measurements confirmed that, more than the amount of ettringite precipitated, ettringite morphology plays a major role in controlling the yield stress and plastic viscosity of fresh cement pastes.


1989 ◽  
Vol 178 ◽  
Author(s):  
Kirsten G. Jeppesen

AbstractSpray dried absorption products (SDA) having special characteristics are used as substitutes for cement in the preparation of mortars; the qualities of the resulting mixed mortars are described. Conditions are described for mortar mixes, data for which were presented at the MRS Fall Meeting 1987.The influence of the composition of the SDA on water requirement and setting time has been studied. A full scale project involving 3 precast, reinforced concrete front-elements containing 20 and 30 wt.% SDA is described. Strength development, mineralogical composition and corrosion were monitored for two years.A non-standard freeze-thaw experiment was performed which compares mortars containing SDA and fly ash (FA) and also shows the effect of superplasticizer.The possibility of improving the SDA by grinding has been tested and a limited improvement has been found. The strength of the mixed mortars seems slightly influenced by the grain size of SDAGypsum (CaSO4·2H2O), synthetic calcium-sulphite (CaSO3·½H2O) and 2 SDAs have been used as retarders for cement clinker. Mortar test prisms have been cast and comparative strengths after curing for 3 years are reported


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