A novel self-assembled gold nanoparticles-molecularly imprinted modified carbon ionic liquid electrode with high sensitivity and selectivity for the rapid determination of bisphenol A leached from plastic containers

2021 ◽  
pp. 105513
Author(s):  
Rahil Jalilian ◽  
Elham Ezzatzadeh ◽  
Alireza Taheri
Keyword(s):  
Gold Nanoparticles ◽  
Ionic Liquid ◽  
Bisphenol A ◽  
Rapid Determination ◽  
High Sensitivity ◽  
Carbon Ionic Liquid Electrode ◽  
Molecularly Imprinted ◽  
Sensitivity And Selectivity ◽  
Plastic Containers

Electrochemical Sensor Based on Molecularly Imprinted Carbon Nanotubes for Selective Determination of Bisphenol A

2013 ◽  
Vol 303-306 ◽  
pp. 170-179
Author(s):  
Hui Min Zhao ◽  
Ya Qiong Chen ◽  
Hong Bo Cheng ◽  
Fang Yuan ◽  
Xie Quan
Keyword(s):  
Carbon Nanotubes ◽  
Bisphenol A ◽  
Electrochemical Sensor ◽  
High Sensitivity ◽  
Molecularly Imprinted ◽  
Multi Wall Carbon Nanotubes ◽  
Selective Determination ◽  
Sensitivity And Selectivity ◽  
Modified Sensor

Based on the unique electronic properties and high adsorption capacity of carbon nanotubes, as well as the specific recognition ability of molecularly imprinted polymers, a novel molecularly imprinted carbon nanotubes electrochemical sensor with high sensitivity and selectivity was developed for bisphenol A (BPA) determination in water. The sensor was fabricated by directly thermalpolymerising molecularly imprinted film on a multi-wall carbon nanotubes (MWNTs) modified glassy carbon electrode (GCE). The linear sweep voltammogram of BPA on this sensor exhibited a well defined anodic peak. Under optimum conditions, the oxidation peak currents were linear to the concentration of BPA in the range of 0.1 mg/L-10.0 mg/L with a correlation coefficient of 0.9987 and a detection limit of 24.2 μg/L (S/N = 3). The proposed electrode exhibited good sensitivity and selectivity, and provided operation and store stability for the determination of BPA. The experiment results indicated a good potential application of the modified sensor in the detection of BPA.

scholarly journals Highly Selective Electrochemiluminescence Sensor Based on Molecularly Imprinted-quantum Dots for the Sensitive Detection of Cyfluthrin

Sensors ◽  
2020 ◽  
Vol 20 (3) ◽  
pp. 884 ◽  
Author(s):  
Jinjin Xu ◽  
Rongrong Zhang ◽  
Chenxi Liu ◽  
Aili Sun ◽  
Jiong Chen ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Rapid Determination ◽  
High Sensitivity ◽  
Multiwall Carbon Nanotube ◽  
Molecularly Imprinted ◽  
Grafting Technique ◽  
Seawater Samples ◽  
Multiwall Carbon ◽  
High Sensitivity Detection

A highly selective and sensitive molecularly imprinted electrochemiluminescence (MIECL) sensor was developed based on the multiwall carbon nanotube (MWCNT)-enhanced molecularly imprinted quantum dots (MIP-QDs) for the rapid determination of cyfluthrin (CYF). The MIP-QDs fabricated by surface grafting technique exhibited excellent selective recognition to CYF, resulting in a specific decrease of ECL signal at the MWCNT/MIP-QD modified electrode. Under optimal conditions, the MIECL signal was proportional to the logarithm of the CYF concentration in the range of 0.2 µg/L to 1.0 × 103 µg/L with a determination coefficient of 0.9983. The detection limit of CYF was 0.05 µg/L, and good recoveries ranging from 86.0% to 98.6% were obtained in practical samples. The proposed MIECL sensor provides a novel, rapid, high sensitivity detection strategy for successfully analyzing CYF in fish and seawater samples.

Molecularly imprinted polymers for the selective determination of trace bisphenol A in river water by electrochemiluminescence

2013 ◽  
Vol 91 (8) ◽  
pp. 656-661 ◽  
Author(s):  
Xiaohua Jiang ◽  
Wengjie Ding ◽  
Chonglin Luan
Keyword(s):  
Bisphenol A ◽  
River Water ◽  
Limit Of Detection ◽  
Solid Phase ◽  
High Sensitivity ◽  
Selective Extraction ◽  
Molecularly Imprinted ◽  
Selective Determination ◽  
Extraction And Purification

The detection of bisphenol A (BPA) is very important for public health and environmental monitoring. In this work, BPA was found to be able to significantly quench the electrochemiluminescence (ECL) of the Ru(bpy)32+/2-(dibutylamino)ethanol (DBAE) system. Molecularly imprinted polymer was synthesized as solid-phase extraction sorbents, which were used for the selective extraction and purification of BPA. Under optimal conditions, the inhibited ECL intensity versus the logarithm of the concentration of BPA was in good linear relationship over a concentration range from 2.2 × 10−10 to 1.1 × 10−7 mol/L. The limit of detection was 4.5 × 10−11 mol/L (S/N = 3). The developed method was successfully applied for determination of BPA in river water with high sensitivity and reliability. Further, a possible mechanism for the quenching effects of the Ru(bpy)32+/DBAE system by BPA was also proposed.

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